Froneman, M.’s team published research in Phosphorus, Sulfur and Silicon and the Related Elements in 47 | CAS: 866-23-9

Phosphorus, Sulfur and Silicon and the Related Elements published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Recommanded Product: Diethyltrichloromethylphosphonate.

Froneman, M. published the artcileDialkylamino group transfer from titanium(IV) to a phosphoryl center. Structure-reactivity studies, Recommanded Product: Diethyltrichloromethylphosphonate, the publication is Phosphorus, Sulfur and Silicon and the Related Elements (1990), 47(3-4), 273-81, database is CAplus.

Reaction between phosphoryl substrates (EtO)2P(O)R (R = H, Me, OEt) and Ti(NR2)nCl4-n (R1 = Me, Et, n = 2, 3, 4) and Mn(NEt2)2 leads to the exchange of one or both EtO groups for the NR2 substituent. The reactivity of the system depends on electronic as well as steric effects of both substrates, and approx. correlates with Lewis acid-base interactions between the substrates.

Phosphorus, Sulfur and Silicon and the Related Elements published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Recommanded Product: Diethyltrichloromethylphosphonate.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics