Cuyegkeng, Maria Assunta published the artcileChromatographic separation of enantiomers and barriers to enantiomerization of axially chiral aromatic carboxamides, Synthetic Route of 36335-47-4, the publication is Chemische Berichte (1987), 120(5), 803-9, database is CAplus.
The enantiomers (M) and (P) of a series of similar aromatic carboxamides were for the first time examined anal. and enriched preparatively by liquid chromatog. on triacetylcellulose. Enantiomeric purities (7-99%), sp. rotations, and barriers to rotation about the C(sp2)-C(sp2) bond (87-120 kJ/mol) were determined These energies were discussed in terms of the size of ortho substituents and of the buttressing effects by meta substituents.
Chemische Berichte published new progress about 36335-47-4. 36335-47-4 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Carboxylic acid,Benzene,Ether, name is 3-Chloro-2,6-dimethoxybenzoic acid, and the molecular formula is C9H9ClO4, Synthetic Route of 36335-47-4.
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https://en.wikipedia.org/wiki/Chloride,
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