Karrenbrock, Friedhelm’s team published research in Tetrahedron Letters in | CAS: 866-23-9

Tetrahedron Letters published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, COA of Formula: C5H10Cl3O3P.

Karrenbrock, Friedhelm published the artcileCathodic formation of olefins from phosphonates, COA of Formula: C5H10Cl3O3P, the publication is Tetrahedron Letters (1979), 2915-16, database is CAplus.

Cathodic reduction of Cl3CP(O)(OEt)2 in the presence of RR1CO [R = 4-MeOC6H4, CH2:CMe, Me(CH2)4, R1 = H; R = Et, R1 = Me; R = R1 = Bu; RR1 = (CH2)4] gave 24-52% RCR1:CCl2. Similar reduction of (EtO)2P(O)CCl2CO2Et in the presence of PhCHO or cyclohexanone gave 55% of a 40:60 mixture of E– and Z-PhCH:CClCO2Et and 43% Et chlorocyclohexylideneacetate, resp.

Tetrahedron Letters published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, COA of Formula: C5H10Cl3O3P.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics