Jagadeesh, Rajenahally V. published the artcileNanoscale Fe2O3-Based Catalysts for Selective Hydrogenation of Nitroarenes to Anilines, Product Details of C6H3ClFNO2, the publication is Science (Washington, DC, United States) (2013), 342(6162), 1073-1076, database is CAplus and MEDLINE.
Production of anilines-key intermediates for the fine chem., agrochem., and pharmaceutical industries relies on precious metal catalysts that selectively hydrogenate aryl nitro groups in the presence of other easily reducible functionalities. Herein, we report convenient and stable iron oxide (Fe2O3)-based catalysts as a more earth-abundant alternative for this transformation. Pyrolysis of iron-phenanthroline complexes on carbon furnishes a unique structure in which the active Fe2O3 particles are surrounded by a nitrogen-doped carbon layer. Highly selective hydrogenation of numerous structurally diverse nitroarenes (more than 80 examples) proceeded in good to excellent yield under industrially viable conditions.
Science (Washington, DC, United States) published new progress about 350-30-1. 350-30-1 belongs to chlorides-buliding-blocks, auxiliary class Fluoride,Chloride,Nitro Compound,Benzene, name is 3-Chloro-4-fluoronitrobenzene, and the molecular formula is C6H3ClFNO2, Product Details of C6H3ClFNO2.
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