Computed Properties of C7H7Cl. I found the field of Chemistry very interesting. Saw the article Silylation of Aryl Chlorides by Bimetallic Catalysis of Palladium and Gold on Alloy Nanoparticles published in 2020.0, Reprint Addresses Miura, H; Shishido, T (corresponding author), Tokyo Metropolitan Univ, Grad Sch Urban Environm Sci, Dept Appl Chem Environm, 1-1 Minami Osawa, Hachioji, Tokyo 1920397, Japan.; Miura, H; Shishido, T (corresponding author), Tokyo Metropolitan Univ, Res Ctr Hydrogen Energy Based Soc, 1-1 Minami Osawa, Hachioji, Tokyo 1920397, Japan.; Shishido, T (corresponding author), Tokyo Metropolitan Univ, Res Ctr Gold Chem, 1-1 Minami Osawa, Hachioji, Tokyo 1920397, Japan.; Miura, H; Shishido, T (corresponding author), Kyoto Univ, Elements Strategy Initiat Catalysts & Batteries, Nishikyo Ku, Kyoto 6158520, Japan.. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene.
Supported palladium-gold alloy-catalyzed cross-coupling of aryl chlorides and hydrosilanes enabled the selective formation of aryl-silicon bonds. Whereas a monometallic palladium catalyst predominantly promoted the hydrodechlorination of aryl chlorides and gold nanoparticles showed no catalytic activity, gold-rich palladium-gold alloy nanoparticles efficiently catalyzed the title reaction to give arylsilanes with high selectivity. A wide array of aryl chlorides and hydrosilanes participated in the heterogeneously-catalyzed reaction to furnish the corresponding arylsilanes in 34-80% yields. A detailed mechanistic investigation revealed that palladium and gold atoms on the surface of alloy nanoparticles independently functioned as active sites for the formation of aryl nucleophiles and silyl electrophiles, respectively, which indicates that palladium and gold atoms on alloy nanoparticles work together to enable the selective formation of aryl-silicon bonds.
Welcome to talk about 95-49-8, If you have any questions, you can contact Miura, H; Masaki, Y; Fukuta, Y; Shishido, T or send Email.. Computed Properties of C7H7Cl
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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