Recommanded Product: Diiodo(1,5-cyclooctadiene)platinum(II). Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about Synthesis, Structures, and Emissive Properties of Platinum(II) Complexes with a Cyclometalating Aryldiamine Ligand. Author is Jude, Hershel; Bauer, Jeanette A. Krause; Connick, William B..
A new series of square planar Pt(II) complexes with the mer-coordinating tridentate ligand, pip2NCN- (pip2NCNH = 1,3-bis(piperdylmethyl)benzene), has been prepared: Pt(pip2NCN)Cl (2), Pt(pip2NCN)Br (3), Pt(pip2NCN)I (4), and [Pt(pip2NCN)(CH3N:C(CH3)2)][CF3SO3] (5). The complexes have been fully characterized by 1H NMR spectroscopy, elemental anal., and UV-vis spectroscopy. The x-ray crystal structures of pip2NCNBr (1), 2, and 5 are reported. Compound 1: triclinic, P1̅, a = 10.081(1) Å, b = 10.153(2) Å, c = 10.390(1) Å, α = 66.05(1)°, β = 79.07(1)°, γ = 64.51(1)°, V = 877.1(2) Å3, Z = 2. Complex 2: triclinic, P1̅, a = 9.897(2) Å, b = 10.191(2) Å, c = 19.174(4) Å, α = 75.09(3)°, β = 76.14(3)°, γ = 71.00(3)°, V = 1741.2(6) Å3, Z = 4. Complex 5: triclinic, P1̅, a = 10.709(2) Å, b = 11.2321(10) Å, c = 12.447(2) Å, α = 110.509(8)°, β = 112.417(10)°, γ = 91.066(9)°, V = 1276.1(3) Å3, Z = 2. In 77 K 3:1 EtOH/MeOH glassy solution, these colorless complexes exhibit weak red-orange to red emissions originating from a lowest spin-forbidden ligand field excited state.
From this literature《Synthesis, Structures, and Emissive Properties of Platinum(II) Complexes with a Cyclometalating Aryldiamine Ligand》,we know some information about this compound(12266-72-7)Recommanded Product: Diiodo(1,5-cyclooctadiene)platinum(II), but this is not all information, there are many literatures related to this compound(12266-72-7).
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