The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: N,N’-(trans-Cyclohexane-1,2-diyl)dipicolinamide(SMILESS: O=C(N[C@H]1[C@H](NC(C2=NC=CC=C2)=O)CCCC1)C3=NC=CC=C3,cas:218290-24-5) is researched.Related Products of 16400-32-1. The article 《Ruthenium(II) carbonyl complexes containing pyridine carboxamide ligands and PPh3/AsPh3/Py coligands: Synthesis, spectral characterization, catalytic and antioxidant studies》 in relation to this compound, is published in Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy. Let’s take a look at the latest research on this compound (cas:218290-24-5).
New Ru(II) carbonyl complexes bearing pyridine, carboxamide and PPh3/triphenylarsine/pyridine were prepared by direct reaction of Ru(II) precursors with some pyridine carboxamide ligands, N,N-bis(2-pyridinecarboxamide)-1,2-ethane (H2L1), N,N-bis(2-pyridinecarboxamide)-1,2-benzene (H2L2) and N,N-bis(2-pyridinecarboxamide)-trans-1,2-cyclohexane (H2L3). The organic ligands offering two Namide and two Npyridine donor sites to the metal center. They were characterized by elemental analyses, FTIR, UV-Visible, NMR (1H, 13C and 31P) and ESI-MS techniques. Based on the above data, an octahedral structure was assigned for all the complexes. The catalytic efficiency of the complexes in transfer hydrogenation of ketones in the presence of iPrOH/KOH and N-alkylation of amine in the presence of tBuOK was examined Also, the antioxidant activity of the ligands and its Ru(II) complexes were determined by DPPH radical, nitric oxide radical, hydroxyl radical and H2O2 scavenging methods, which indicates that the Ru(II) complexes exhibit more effective antioxidant activity than the ligands alone.
This literature about this compound(218290-24-5)Synthetic Route of C18H20N4O2has given us a lot of inspiration, and I hope that the research on this compound(N,N’-(trans-Cyclohexane-1,2-diyl)dipicolinamide) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics