Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 12266-72-7, is researched, Molecular C8H12I2Pt, about Preparation and reaction of platinum(II) complexes of N,N-bis(dicyclohexylphosphinomethyl)aminomethane. Crystal structures of (Cy2PCH2)2NMe (Cy = cyclohexyl) and [PtX2{(Cy2PCH2)2NMe}], (X = Cl and I), the main research direction is crystal structure dicyclohexyl bishydroxymethyl phosphonium chloride platinum iodide chloride; mol structure dicyclohexyl bishydroxymethyl phosphonium chloride platinum iodide chloride; phosphonium chloride platinum halide preparation structure substitution reaction; aminomethylphosphine chelating phosphine platinum complex preparation.Application In Synthesis of Diiodo(1,5-cyclooctadiene)platinum(II).
Treatment of [Cy2P(CH2OH)2]Cl with MeNH2 in the presence of Et3N affords a high yield of the phosphine (Cy2PCH2)2NMe (1) (dcpam) which was characterized by a single crystal x-ray structure. Treatment of [PtX2(COD)], (COD = cycloocta-1,5-diene, X = Cl or I) with 1 affords the Pt complexes [PtX2{(Cy2PCH2)2NMe}] (2). The chloride complex, (2a), reacts with t-BuNC to afford [PtCl(t-BuNC){(Cy2PCH2)2NMe}]Cl (3) and treatment of 2a with 2-mercapto-1-methylimidazole affords [Pt{SCN(Me)CHCHN(Me)}{(Cy2PCH2)2NMe}]Cl (5). The reaction of 2a with 2-acetamidoacrylic acid in the presence of Ag(I) oxide affords the C bonded isomer (8a) only whereas a similar reaction using [PtCl2{Ph2P(CH2)3PPh2}] affords a mixture of the azaallyl complex (7) and the C bonded isomer (8b) which can be separated by fractional crystallization The crystal structures of PtX2{(Cy2PCH2)2NMe} are also reported.
As far as I know, this compound(12266-72-7)Application In Synthesis of Diiodo(1,5-cyclooctadiene)platinum(II) can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics