Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: 2-((1R,5S)-6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethanol, is researched, Molecular C11H18O, CAS is 35836-73-8, about Carbon-13 nuclear magnetic resonance studies. Camphene racemization. III. endo-Methyl migration problem.Category: chlorides-buliding-blocks.
By means of 13C labeling at the 8 position of camphene, it was possible to effect simultaneous analysis by NMR for the amount of the isotope label at each of the possible positions (8,9, and 10) after partial racemization. With these data, it is possible to make full use of integrated rate equations developed earlier and thus obtain a more precise and significant value for the extent of endo-Me migration during racemization. It is also possible to provide reasonably exact rate constants for all of the various processes contributing to racemization, including tricyclene formation. The endo-Me migration appears to be very small: certainly less than 5% (as compared with the previously reported 22%) but very likely not actually zero.
Although many compounds look similar to this compound(35836-73-8)Category: chlorides-buliding-blocks, numerous studies have shown that this compound(SMILES:CC1(C)[C@@]2([H])CC=C(CCO)[C@]1([H])C2), has unique advantages. If you want to know more about similar compounds, you can read my other articles.
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics