Dashan, Irem; Balta, Demet Karaca; Temel, Binnur Aydogan; Temel, Gokhan published the artcile< Preparation of Single Chain Nanoparticles via Photoinduced Double Collapse Process>, Application In Synthesis of 1592-20-7, the main research area is chain nanoparticle photoinduced collapse.
A straightforward method is described to achieve polymeric nanoparticles by double folding of single linear chains. The side chain functional polystyrene with controlled mol. weight is converted to pendant azide and benzophenone motifs via postmodification reactions. Resulting functionalized chains undergo intramol. crosslinking upon UV illumination using simultaneous and subsequent pathways at a dilute concentration Particle size of nanoparticles can be tuned by changing the degree of crosslinking using a second folding process. Obtained single and double collapsed chains indicate higher glass transition temperatures and lower hydrodynamic radii compared to their intermediates. To our knowledge, the combination of photoinduced azide crosslinking and radical coupling processes is the first attempt to prepare double folding single polymer chains.
Macromolecular Chemistry and Physics published new progress about Crosslinking, intramolecular. 1592-20-7 belongs to class chlorides-buliding-blocks, and the molecular formula is C9H9Cl, Application In Synthesis of 1592-20-7.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics