Category: 10007-84-8

Name: Sodium 2,6-dichlorobenzoateOn May 31, 1989, Dekoninck, J. M.; Legras, R.; Mercier, J. P. published an article in Polymer. The article was 《Nucleation of poly(ethylene terephthalate) by sodium compounds: a unique mechanism》. The article mentions the following:

The high nucleation efficiency of Na salts in PET is not due to additives but to reaction products. Ester linkages of PET are broken and Na carboxylate chain ends are created. The ionic chain ends are the effective nucleating species. After reading the article, we found that the author used Sodium 2,6-dichlorobenzoate(cas: 10007-84-8Name: Sodium 2,6-dichlorobenzoate)

Sodium 2,6-dichlorobenzoate(cas: 10007-84-8) belongs to organochlorine compounds. The wide structural variety and divergent chemical properties of organochlorides lead to a broad range of names, applications, and properties. Organochlorine compounds have wide use in many applications, though some are of profound environmental concern, with TCDD being one of the most notorious.Name: Sodium 2,6-dichlorobenzoate

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Razak, Norazizah A.; Khan, M. Niyaz published their research in Rheologica Acta on December 31 ,2013. The article was titled 《Determination of flow activation energy at viscosity maximum for spherical and wormlike micelles of different lengths and flexibility》.Safety of Sodium 2,6-dichlorobenzoate The article contains the following contents:

Steady shear rheol. measurements were carried out on aqueous solutions containing 15 mM cetyltrimethylammonium bromide (CTABr) and a constant value of [MX] and temperature for MX = 2,3-; 2,4-; 2,5-; 2,6-; 3,4-; and 3,5-Cl2BzNa with Bz-representing C6H3CO-2. Plots of zero shear viscosity (η0) vs. [MX] at 35 °C and 15 mM CTABr show the presence of single maximum and double maxima for MX = 2,3- and 3,5-Cl2BzNa, resp. Turbidity data (absorbance at 600 nm vs. [MX]) coupled with η0vs. [MX] data at 35 °C reveal indirectly the presence of vesicles along with wormlike micelles (WM) at[MX]/[CTABr] > 0. 7 for MX = 3,5-Cl2BzNa. Temperature dependence of η0in the vicinity of the viscosity maximum shows nonlinear and linear Arrhenius behavior, within the temperature range of 20-55 °C, for MX = 2,3-; 2,4-; 2,5-; 3,4-; and 3,5-Cl2BzNa, resp. The values of η0, γ̇cr (critical shear rate), and flow activation energy correlate with CTABr micellar binding constants of counterions. After reading the article, we found that the author used Sodium 2,6-dichlorobenzoate(cas: 10007-84-8Safety of Sodium 2,6-dichlorobenzoate)

Sodium 2,6-dichlorobenzoate(cas: 10007-84-8) belongs to organochlorine compounds. The wide structural variety and divergent chemical properties of organochlorides lead to a broad range of names, applications, and properties. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Safety of Sodium 2,6-dichlorobenzoate

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Safety of Sodium 2,6-dichlorobenzoateOn May 1, 2013 ,《Quantitative correlation between counterion (X) affinity to cationic micelles and X-induced micellar growth for X = 2,4-; 2,5-; 2,6- and 3,4-dichlorobenzoate ions》 appeared in Journal of Oleo Science. The author of the article were Yusof, Nor Saadah M.; Razak, Norazizah A.; Khan, M. Niyaz. The article conveys some information:

A semi empirical kinetic (SEK) method has been used to determine the ratio of cetyltrimethylammonium bromide (CTABr) micellar binding constants of counterion X- and Br- (a reference counterion), i.e. KX/KBr (=RXBr). The values of KX and KBr have been derived from the kinetic parameters obtained in the presence spherical/non-spherical and spherical micelles, resp. This rather new method gives the resp. mean values of RXBr as 45 ± 2, 25 ± 3, 4.7 ± 0.6 and 119 ± 10 for X = 2,4-, 2,5-, 2,6- and 3,4-Cl2C6H3CO2- (Cl2Bz’Na). Literature lacks the report on the values of RXBr for all X except for X = 2,6-Cl2C6H3CO2- (2,6-Cl2Bz’-) for which the reported value is 5.0. Rheol. properties, such as shear thinning behavior, reveal indirectly the presence of wormlike micelles (WM) in the CTABr micellar solutions containing MX for all X except X = 2,6-Cl2Bz’-. The micelles remain spherical within [2,6-Cl2Bz’-] range 0.01 – 0.34 M at 0.015 M CTABr. The maxima of the plots of zero shear viscosity, η0, (obtained from the initial plateau region of flow curves, i.e. η vs. γ̇ curve) vs. [MX] (MX = 2,4-, 2,5- and 3,4-Cl2Bz’Na) at 0.015 M CTABr also support indirectly the presence of linear, entangled and branched WM. After reading the article, we found that the author used Sodium 2,6-dichlorobenzoate(cas: 10007-84-8Safety of Sodium 2,6-dichlorobenzoate)

Sodium 2,6-dichlorobenzoate(cas: 10007-84-8) belongs to organochlorine compounds. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Safety of Sodium 2,6-dichlorobenzoate

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Magid, L. J.; Han, Z.; Li, Z.; Butler, P. D. published an article in Journal of Physical Chemistry B. The title of the article was 《Tuning the Contour Lengths and Persistence Lengths of Cationic Micelles: The Role of Electrostatics and Specific Ion Binding》.Formula: C7H3Cl2NaO2 The author mentioned the following in the article:

Small-angle scattering was used to obtain detailed information on micellar contour lengths and persistence lengths, a measure of micellar flexibility, for mixed micelles of cetyltrimethylammonium 2,6-dichlorobenzoate and cetyltrimethylammonium chloride in H2O as a function of surfactant and salt concentrations and the relative amounts of the 2 counterions (the counterion inventory) at the micellar surface. Increasing amounts at the surface of the penetrating counterion of the pair, 2,6-dichlorobenzoate, lowers the 1-dimensional bending modulus of the micelles, making them more flexible. Micellar contour lengths exhibit a maximum with increasing amounts of 2,6-dichlorobenzoate at the micellar surface. This is understood in terms of decreases in the micellar end-cap energies, Ec, at high concentrations of penetrating counterion. By decreasing the effective micellar surface charge d., penetrating counterions also cause decreased contributions from electrostatic repulsion, Ee, which retard micellar growth. At low ionic strengths, this results in more extensive micellar growth upon addition of Na 2,6-dichlorobenzoate rather than NaCl. In the experiment, the researchers used Sodium 2,6-dichlorobenzoate(cas: 10007-84-8Formula: C7H3Cl2NaO2)

Sodium 2,6-dichlorobenzoate(cas: 10007-84-8) belongs to organochlorine compounds. The wide structural variety and divergent chemical properties of organochlorides lead to a broad range of names, applications, and properties.Formula: C7H3Cl2NaO2 Organochlorine compounds have wide use in many applications, though some are of profound environmental concern, with TCDD being one of the most notorious.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Application of 10007-84-8On September 1, 2013 ,《A semi-empirical spectrophotometric (SESp) method for the indirect determination of the ratio of cationic micellar binding constants of counterions X- and Br- (KX/KBr)》 was published in Journal of Oleo Science. The article was written by Khan, Mohammad Niyaz; Yusof, Nor Saadah Mohd.; Abdul Razak, Norazizah. The article contains the following contents:

The semi-empirical spectrophotometric (SESp) method, for the indirect determination of ion exchange constants (KXBr) of ion exchange processes occurring between counterions (X- and Br-) at the cationic micellar surface, is described in this article. The method uses an anionic spectrophotometric probe mol., N-(2-methoxyphenyl)phthalamate ion (1-), which measures the effects of varying concentrations of inert inorganic or organic salt (NavX, v = 1, 2) on absorbance, (Aob) at 310 nm, of samples containing constant concentrations of 1-, NaOH and cationic micelles. The observed data fit satisfactorily to an empirical equation which gives the values of two empirical constants These empirical constants lead to the determination of KXBr (= KX/KBr with KX and KBr representing cationic micellar binding constants of counterions X and Br-). This method gives values of KXBr for both moderately hydrophobic and hydrophilic X-. The values of KXBr, obtained by using this method, are comparable with the corresponding values of KXBr, obtained by the use of semi-empirical kinetic (SEK) method, for different moderately hydrophobic X. The values of KXBr for X = Cl- and 2,6-Cl2C6H3CO2-, obtained by the use of SESp and SEK methods, are similar to those obtained by the use of other different conventional methods.Sodium 2,6-dichlorobenzoate(cas: 10007-84-8Application of 10007-84-8) was used in this study.

Sodium 2,6-dichlorobenzoate(cas: 10007-84-8) belongs to organochlorine compounds. The wide structural variety and divergent chemical properties of organochlorides lead to a broad range of names, applications, and properties.Application of 10007-84-8 Organochlorine compounds have wide use in many applications, though some are of profound environmental concern, with TCDD being one of the most notorious.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Application In Synthesis of Sodium 2,6-dichlorobenzoateOn May 31, 1986, Menkisoglou-Spyroudi, Ourania; Varvoglis, Anastasios published an article in Journal of the Chemical Society. The article was 《[Bis[(aryloxy)acetoxy]iodo]benzenes》. The article mentions the following:

The title compounds were prepared and their chem. properties studied. With iodine they gave ROCH2CO2CH2OR (I, R = aryl) via (aryloxy)acetyl hypoiodites and α-iodoanisoles. The former were unstable but were trapped with pyridine to give N-iodopyridinium (aryloxy)acetates, whereas the latter were stable and reacted independently with the title compounds to give I. The thermolysis of the title compounds was studied and, besides I, aryl (aryloxy)acetates were formed. The mechanism of the thermolysis was briefly discussed. Thus, 4-BrC6H4OCH2CO2Na in MeCN treated with (CF3CO2)2IPh gave 95% (4-BrC6H4OCH2CO2)2IPh (II). Treatment of II with iodine gave 37% 4-BrC6H4OCH2CO2CH2OC6H4Br-4 (III). Heating II at 200° for 30 min, gave 65% 4-BrC6H4OCH2CO2C6H4Br-4 and 49% III. The experimental part of the paper was very detailed, including the reaction process of Sodium 2,6-dichlorobenzoate(cas: 10007-84-8Application In Synthesis of Sodium 2,6-dichlorobenzoate)

Sodium 2,6-dichlorobenzoate(cas: 10007-84-8) belongs to organochlorine compounds. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Application In Synthesis of Sodium 2,6-dichlorobenzoate

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

SDS of cas: 10007-84-8On May 31, 2015, Solyanikova, Inna P.; Emelyanova, Elena V.; Shumkova, Ekaterina S.; Egorova, Darya O.; Korsakova, Ekaterina S.; Plotnikova, Elena G.; Golovleva, Ludmila A. published an article in International Biodeterioration & Biodegradation. The article was 《Peculiarities of degradation of benzoate and its chloro- and hydroxy-substituted analogs by actinobacteria》. The article mentions the following:

This work investigates the ability of representatives of four actinobacterial genera (Arthrobacter, Microbacterium, Rhodococcus, Gordonia) to degrade benzoic acid and its hydroxylated or chlorinated analogs. Benzoate, 3-chlorobenzoate and 4-hydroxybenzoate were shown to support growth of most strains. We determined the maximal specific growth rates and doubling times for bacteria grown on these substrates. We examined the substrate specificities of actinobacterial benzoate dioxygenases towards 16 aromatic chems. The specificities varied among species, they were narrow for Rhodococcus opacus 1CP and Gordonia polyisoprenivorans 135 and broad for Rhodococcus ruber P25 and Microbacterium sp. B51. The genes encoding the benzoate dioxygenase α-subunit from R. opacus 1CP, R. opacus 6a, R. ruber P25, Rhodococcus wratislaviensis P1 and R. wratislaviensis G10 which were isolated at distant sites exhibited between 88 and 97% homol. with the homologous gene of Rhodococcus jostii RHA1. This indicates a common origin of these genes. Notably, in some strains, catechol 1,2-dioxygenase and gentisate dioxygenase were induced simultaneously during growth on benzoate. In the part of experimental materials, we found many familiar compounds, such as Sodium 2,6-dichlorobenzoate(cas: 10007-84-8SDS of cas: 10007-84-8)

Sodium 2,6-dichlorobenzoate(cas: 10007-84-8) belongs to organochlorine compounds. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.SDS of cas: 10007-84-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics