Category: 12083-92-0

Synthesis and characterization of a novel polyorganosiloxane having a bigger sized tubular structure and its supramolecular clathrate was written by Liu, Chunqing;Liu, Zhihua;Xie, Ping;Dai, Daorong;Zhang, Rongben;Zhu, Chuanfeng;Wang, Chen;He, Chaobin;Chung, Neal Tai-Shung. And the article was included in Polymers for Advanced Technologies in 2002.Recommanded Product: Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) This article mentions the following:

A novel polyorganosiloxane having a bigger sized tubular structure, tubular polymer (TP) was synthesized successfully by hydrosilylation reaction of reactive cis-isotactic ladder-like polyallylsilsesquioxane (Allyl-T) with coupling agent p-bis(dimethylhydrogensilyl)oxydiphenylene (M) in the presence of dicyclopentadienylplatinum(II) chloride (Cp₂PtCl₂) catalyst. A novel supramol. TP clathrate (TP/LC) was prepared by in situ encapsulating rod-like liquid crystalline mol. within the pore of TP. The Allyl-T was prepared by stepwise coupling polymerization Various characterization methods including solubility test, FT-IR, ¹H-NMR, differential scanning calorimetry (DSC), gel permeation chromatog. (GPC), vapor pressure osmometer (VPO), X-ray diffraction (XRD), at. force microscopy (AFM), polarized optical microscopy (POM) and mol. simulation were used and the results not only proved the existence of nano-scale tubular structures in the TP, but also demonstrated that a novel soluble supramol. clathrate had been formed. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Recommanded Product: Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)).

Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Recommanded Product: Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Nucleophilic Attack of Carbonyl-Stabilized Phosphorus Ylides on Neutral and Cationic Alkene Platinum(II) Complexes was written by Vicente, Jose;Chicote, Maria Teresa;MacBeath, Calum;Jones, Peter G.. And the article was included in Organometallics in 2003.Application In Synthesis of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) This article mentions the following:

The carbonyl-stabilized phosphorus ylides Ph₃P:CHCO₂R (R = Me, Et) react with the platinum complexes [PtCl(畏²-CH₂:CH₂)(N,N,N’,N’-tetramethylethylenediamine)]ClO₄ and [PtCl₂(畏⁴-diene)] (diene = 1,5-hexadiene (C₆H₁₀), dicyclopentadiene (C₁₀H₁₂), 4-vinylcyclohex-1-ene (C₈H₁₂), norbornadiene (C₇H₈)) to give complexes resulting from nucleophilic attack of the ylide at one of the olefinic carbons. The crystal structures of [PtCl₂{畏³-C₆H₁₀CH(PPh₃)CO₂Et}], [PtCl₂{畏³-C₁₀H₁₂CH(PPh₃)CO₂Me}]路0.5CH₂Cl₂, and [PtCl₂{畏³-C₈H₁₂CH(PPh₃)CO₂Me}]路2CHCl₃ are reported and indicate an exo attack in the case of the dicyclopentadiene complex and anti-Markovnikov addition (attack at the CH₂ group) in the other two complexes. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Application In Synthesis of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)).

Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Application In Synthesis of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Unusual iron-platinum bonding in the cluster (diironhexacarbonyl)[(蟺-dicyclopentadiene)platinum] disulfide was written by Pasynskii, A. A.;Semenova, N. I.;Torubaev, Yu. V.;Lysenko, K. A.. And the article was included in Zhurnal Neorganicheskoi Khimii in 2001.Recommanded Product: 12083-92-0 This article mentions the following:

Transmetalation of (渭₃-S)₂Fe₃(CO)₉ with C₁₀H₁₂PtCl₂ (C₁₀H₁₂ = dicyclopentadiene) in THF gave 55% title cluster C₁₀H₁₂Pt(渭₃-S)₂Fe₂(CO)₆, the structure of which was determined by x-ray crystallog. The Pt atom is 蟺-coordinated with double bonds of the dicyclopentadiene mol. and with 2 渭₃-bridging S atoms and is in a square planar environment. The Fe(CO)₃ moieties show an Fe-Fe bond length of 2.515 脜. One of the Fe atoms forms an Fe-Pt bond of 3.03 脜 length with the Pt atom, and tilts the planarity of the Pt atom ligand environment toward itself. The role of the steric effects of interligand repulsion on Fe-Pt interaction is discussed. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Recommanded Product: 12083-92-0).

Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Recommanded Product: 12083-92-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Comparison of Different Polymer- and Silica-Supported 9-Amino-9-deoxy-epi-quinines as Recyclable Organocatalysts was written by Porta, Riccardo;Coccia, Francesca;Annunziata, Rita;Puglisi, Alessandra. And the article was included in ChemCatChem in 2015.Safety of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) This article mentions the following:

9-Amino-9-deoxy-epi-quinine, properly modified by suitable linkers, was anchored on highly cross-linked polystyrene, poly(ethylene glycol), and silica. The resulting species were characterized by NMR spectroscopy and tested as supported organocatalysts in the reaction between isobutyric aldehyde and trans-尾-nitrostyrene. Polystyrene- and poly(ethylene glycol)-supported catalysts outperformed their nonsupported counterpart affording the desired product in high yield and ee (>90 % ee). Silica-supported catalysts proved to be less efficient in terms of both chem. yield and enantioselectivity. Polystyrene- and poly(ethylene glycol)-supported 9-amino-9-deoxy-epi-quinine were then used in the same reaction with different substrates, leading to the desired products in high yield and ee, as well as in three other reactions operating with different mechanism. An investigation of the recyclability of the polystyrene- and poly(ethylene glycol)-supported systems showed that these could be recovered and recycled with no loss of stereochem. activity but with a marked erosion of chem. efficiency occurring at the fifth reaction cycle. This was ascribed to chem. degradation of the alkaloid occurring during the reaction. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Safety of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)).

Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Safety of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Synthesis and properties of high-temperature mesomorphic polysiloxane (MEPSIL) solvents: biphenyl- and terphenyl-based nematic systems was written by Apfel, M. A.;Finkelmann, H.;Janini, G. M.;Laub, R. J.;Luehmann, B. H.;Price, A.;Roberts, W. L.;Shaw, T. J.;Smith, C. A.. And the article was included in Analytical Chemistry in 1985.Recommanded Product: Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) This article mentions the following:

Mesomorphic (liquid-crystalline) side-chain siloxanes were prepared for evaluation as stationary phases in gas chromatog. by hydrosilylation of 4-(allyloxy)benzoate esters by Me hydrogen siloxanes in the presence of a dicyclopentadienylplatinum (II)chloride聽聽[12083-92-0] catalyst. The products were characterized by IR, NMR, gas chromatog., DSC, elemental anal., and hot-stage, polarized optical microscopy. Their selectivity was substantially different from that of other common gas chromatog. solvents. The one best suited for use in gas chromatog. had m.p. 139掳, nematic-isotropic transition temperature 319掳, and practical operating limits of 150 to >300掳. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Recommanded Product: Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)).

Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Recommanded Product: Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Preparation and ligand displacement reactions of diene(polyfluorophenyl)platinum(II) complexes was written by Deacon, G. B.;Nelson-Reed, K. T.. And the article was included in Journal of Organometallic Chemistry in 1987.HPLC of Formula: 12083-92-0 This article mentions the following:

The complexes PtR₂(diene) [R = C₆F₅ or p-HC₆F₄; diene = cis,cis-cycloocta-1,5-diene (cod), dicyclopentadiene (dcy), norbornadiene (nbd), hexa-1,5-diene (hex)] have been prepared by the organolithium route. Reaction of PtCl₂(cod) with an equimolar amount of TlO₂CR (R = C₆F₅, p-HC₆F₄) in pyridine yields Pt(R)Cl(cod), which have been converted into Pt(R)X(cod) (X = Br or iodo) by halogen exchange reactions. Other decarboxylations result in diene displacement giving cis-Pt(C₆F₅)Cl(py)₂ and cis– and trans-Pt(C₆F₅)₂(py)₂. The complexes, cis-Pt(C₆F₅)₂L₂ (L = py or Ph₃P) and cis-Pt(p-HC₆F₄)₂(PPh₃)₂ are formed by ligand replacement reactions of PtR₂(cod), but Pt(C₆F₅)₂ (cod) does not react with N,N,N‘,N‘-tetramethylethylenediamine (tmed) nor Pt(C₆F₅)₂(nbd or dcy) with ethylenediamine (en). Diene displacement occurs more readily from PtR₂(hex) giving Pt(C₆F₅)₂L₂ [L₂ = cis-(NH₃)₂, en, tmed, 1,10-phenanthroline) and cis-Pt(p-HC₆F₄)₂(PPh₃)₂. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0HPLC of Formula: 12083-92-0).

Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.HPLC of Formula: 12083-92-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Hydrosilylation conditions applied on alkenyl benzylated xyloses: selective reduction and isomerization was written by Hadad, Caroline;Bouquillon, Sandrine;Harakat, Dominique;Muzart, Jacques. And the article was included in Applied Organometallic Chemistry in 2009.Category: chlorides-buliding-blocks This article mentions the following:

In the presence of triethylsilane and different transition metal catalysts, the main reactive pathways observed from benzylated xyloses bearing an unsaturated tether were the reduction and the isomerization of the double bond without debenzylation of the sugar moiety. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Category: chlorides-buliding-blocks).

Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Iron-Platinum interaction in (hexacarbonyldiiron)-[(π-diene)platinum] dichalcogenide clusters was written by Pasynskii, A. A.;Semenova, N. I.;Torubaev, Yu. V.;Lysenko, K. A.. And the article was included in Zhurnal Neorganicheskoi Khimii in 2003.Safety of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) This article mentions the following:

Trinuclear diiron-platinum cluster [(diene)Pt(μ₃-Se)₂Fe₂(CO)₆] (2, diene = dicyclopentadiene) was prepared by transmetalation of [(μ₃-Se)₂Fe₃(CO)₉] by [(diene)PtCl₂]. Crystal structure of 2 was determined by single-crystal x-ray crystallog. Platinum atom in 2 has a square-planar coordination geometry and is η²-bound to double bonds of the dicyclopentadiene ligand and coordinated by μ₃-Se atoms. The Fe(CO)₃ fragments are bound by two selenium bridges and by Fe-Fe bond (2.545 Å). Besides that, one of the Fe atoms has close contact with platinum (Fe-Pt 3.169 Å), declining the Pt coordination plane from the mirror plane of the two Fe(CO)₃ fragments. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Safety of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)).

Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Safety of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Fluoropolymers with low dielectric constants: triallyl ether-hydrosiloxane resins was written by Hu, Henry S. W.;Griffith, James R.;Buckley, Leonard J.;Snow, Arthur W.. And the article was included in ACS Symposium Series in 1995.Safety of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) This article mentions the following:

The preparation of a class of processable heavily fluorinated triallyl ether homo- and co-polymers is carried out to elucidate the structure-property relations in comparison with the acrylic analogs. The triallyl ether monomer was prepared in good yield through the condensation of the triol, 1,3,5-tris(2-hydroxy-hexafluoro-2-propyl)benzene, in dry acetone with allyl bromide in the presence of potassium carbonate. Homopolymers were obtained and cured through a slow free radical polymerization, while copolymers were obtained through a fast hydrosilylation with catalyst. The dielec. constant of the copolymer of the triallyl ether and an equivalence of polymethylhydrosiloxane (PMHS) catalyzed by a trace of dicyclopentadienylplatinum(II) chloride is 2.33 at 13.2 GHZ with a dissipation factor of 0.004. The factors which affect the dielec. constant and thermal stability are the fluorine content, the polymer type and the mol. architecture. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Safety of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)).

Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Safety of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Synthesis and characterization of substituted poly(ferrocenylsilanes) and magnetic properties of their doped products was written by Liu, Yunyang;Tang, Hongding;Su, Xu;Chen, Xingguo;Li, Jun;Qin, Jingui;Zhang, Xixiang. And the article was included in Synthetic Metals in 2003.Related Products of 12083-92-0 This article mentions the following:

A series of substituted poly(ferrocenyl-silane)s were synthesized through transition-metal catalyzed ring-opening polymerization (ROP) of the corresponding [1]silaferrocenophanes. The structure of the polymers was studied using ¹H-NMR, FTIR, gel permeation chromatog. (GPC), and differential scanning calorimetry (DSC). The polymers formed ferromagnetic charge transfer complexes with tetracyanoethylene (TCNE). The the complexes showed paramagnetism below 110 K, as measured using SQUID. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Related Products of 12083-92-0).

Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Related Products of 12083-92-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics