Category: 12083-92-0

Stereospecific addition of carbon and nitrogen nucleophiles to dicyclopentadieneplatinum and -palladium complexes was written by Stille, John K.;Fox, Dale B.. And the article was included in Journal of the American Chemical Society in 1970.Computed Properties of C10H10Cl2Pt This article mentions the following:

The nucleophilic additions of acetylacetone, Et acetoacetate, diethyl malonate, or PhCH2NH2 to the double bond of dichloro(endo-dicyclopentadiene)platinum(II) and of thallous acetylacetone to dichloro(endo-dicyclopentadiene)palladium(II) produced platinum- and palladium-carbon σ-bonded complexes. The trans additions take place at the 5,6-double bond without skeletal rearrangement of the dicyclopentadiene moiety; the nucleophile is attached exo with the metal endo and coordinated to the 2,3-double bond. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Computed Properties of C10H10Cl2Pt).

Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Computed Properties of C10H10Cl2Pt

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Solid Supported Chiral N-Picolylimidazolidinones: Recyclable Catalysts for the Enantioselective, Metal- and Hydrogen-Free Reduction of Imines in Batch and in Flow Mode was written by Porta, Riccardo;Benaglia, Maurizio;Annunziata, Rita;Puglisi, Alessandra;Celentano, Giuseppe. And the article was included in Advanced Synthesis & Catalysis in 2017.Reference of 12083-92-0 This article mentions the following:

A new class of solid supported chiral imidazolidinone organocatalysts for the catalytic reduction of imines with trichlorosilane was developed. Polystyrene proved to be a more effective support than SiO₂ in terms of both chem. and stereochem. efficiency. Even with a loading ≥1 mol% the best performing supported catalyst showed a remarkable activity and stereocontrol ability, promoting the reduction with stereoselectivities reaching 98% ee and in most cases ranging between 90-95% ee The general scope of the methodol. and the good recyclability of the immobilized catalyst were demonstrated. The polystyrene-anchored chiral catalyst was also used to prepare packed bed reactors for the continuous flow synthesis of chiral amines, that were obtained in excellent yields and enantioselectivities. By exploiting the chiral organocatalytic reactor, the in-flow stereoselective synthesis of a common, immediate precursor of rivastigmine, of the calciomimetic (R)-NPS 568 and of Acrylamide (S)-A, currently under study for the treatment of neuropathic pain, was successfully accomplished. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Reference of 12083-92-0).

Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Reference of 12083-92-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics