Category: 12266-72-7

Recommanded Product: 12266-72-7. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about Heteropolytopic Arsanylarylthiolato Ligands: Cis-Trans Isomerism of Nickel(II), Palladium(II), and Platinum(II) Complexes of 1-AsPh2-2-SHC6H4.

Heteropolytopic arsinoarylthiolato ligands 1-AsPh2-2-SHC6H4 (AsSH), PhAs(2-SHC6H4)2 (AsS2H2), and As(2-SHC6H4)3 (AsS3H3) have been prepared by lithiation-electrophilic substitution procedures. The 2:1 reaction of AsSH with NiCl2·6H2O, Na2[PdCl4], and [PtI2(cod)] (cod = 1,5-cyclooctadiene) in the presence of NEt3 afforded the square-planar complexes trans-[Ni{(AsS)-κ2S,As}2] (1), cis-[Pd{(AsS)-κ2S,As}2] (2), trans-[Pd{(AsS)-κ2S,As}2] (3), and cis-[Pt{(AsS)-κ2S,As}2] (4). In the cases of nickel and platinum, only one isomer was isolated. With palladium, initially the cis isomer 2 is formed and undergoes slow isomerization to the trans isomer 3 in solution Small amounts of the trinuclear complex [{PtI(1-AsPh2-μ-2-S-C6H4-κ2S,As)}3] (5) are also formed besides the mononuclear platinum bis-chelate complex 4. D. functional theory calculations support a dissociative mechanism for the isomerization of the palladium(II) complexes.

《Heteropolytopic Arsanylarylthiolato Ligands: Cis-Trans Isomerism of Nickel(II), Palladium(II), and Platinum(II) Complexes of 1-AsPh2-2-SHC6H4》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(Diiodo(1,5-cyclooctadiene)platinum(II))Recommanded Product: 12266-72-7.

Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Product Details of 12266-72-7. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about Comparison of the bonding in zero- and divalent platinum-olefin and -acetylene complexes from carbon-13 nuclear magnetic resonance parameters. XXII. Author is Chisholm, M. H.; Clark, H. C.; Manzer, L. E.; Stothers, J. B..

13C NMR parameters for simple olefin and acetylene complexes of Pt(0) and Pt(II) support the concept of a continuum of metal-olefin/acetylene bonding. The coupling constant 1J(195Pt-13C) for olefinic C depends on the trans influence of the trans ligand and thus reflects the Pt “”6s”” orbital contribution to the olefin-π to metal σ-bond.

《Comparison of the bonding in zero- and divalent platinum-olefin and -acetylene complexes from carbon-13 nuclear magnetic resonance parameters. XXII》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(Diiodo(1,5-cyclooctadiene)platinum(II))Product Details of 12266-72-7.

Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 12266-72-7, is researched, Molecular C8H12I2Pt, about Organometallic palladium and platinum complexes with strongly donating alkyl coligands – Synthesis, structures, chemical and cytotoxic properties, the main research direction is organometallic palladium platinum complex preparation crystal mol structure antitumor; cyclooctadiene palladium platinum methyl neopentyl neosilyl trimethylsilylmethyl alkynyl complex; crystal mol structure cyclooctadiene palladium platinum benzyl neopentyl neosilyl; antitumor activity cyclooctadiene platinum methyl benzyl neosilyl alkynyl halide.Computed Properties of C8H12I2Pt.

The synthesis, spectroscopy, and structures of organometallic complexes [(COD)M(R)X] and [(COD)M(R)(R’)] (COD = 1,5-cyclooctadiene, M = Pd or Pt; R = Me, neopentyl (2,2-dimethylpropyl), neosilyl (trimethylsilylmethyl), or benzyl; X = Cl, Br, or I; R’ = 2-phenyl-ethynyl, p-fluoro-2-phenyl-ethynyl, p-methyl-2-phenyl-ethynyl or p-nitro-2-phenyl-ethynyl) has been explored. Selected samples of organo-platinum complexes show strikingly high cytotoxicity when tested against HT-29 and MCF-7 tumor cells.

《Organometallic palladium and platinum complexes with strongly donating alkyl coligands – Synthesis, structures, chemical and cytotoxic properties》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(Diiodo(1,5-cyclooctadiene)platinum(II))Computed Properties of C8H12I2Pt.

Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Diiodo(1,5-cyclooctadiene)platinum(II)(SMILESS: I[Pt]I.C1=CCC/C=CCC/1,cas:12266-72-7) is researched.Recommanded Product: 3,3′-Diindolylmethane. The article 《Classics Meet Classics: Theoretical and Experimental Studies of Halogen Bonding in Adducts of Platinum(II) 1,5-Cyclooctadiene Halide Complexes with Diiodine, Iodoform, and 1,4-Diiodotetrafluorobenzene》 in relation to this compound, is published in Crystal Growth & Design. Let’s take a look at the latest research on this compound (cas:12266-72-7).

Complexes of PtX2COD (X = Cl, Br, I; COD = 1,5-cyclooctadiene) were cocrystd. with classical halogen-bond donors (CHI3, I2, and 1,4-diiodotetrafluorobenzene (FIB)), resulting in noncovalently bound supramol. aggregates of various lengths-from heterotrimers to polymers. The influence of halides in the complexes on the geometry and strength of the halogen bond (XB) was studied both exptl. by single-crystal XRD and theor. by quantum chem. methods such as noncovalent interaction plots (NCI-plot), electrostatic potential (ESP) surface anal., and a combination of electron localization function (ELF) and quantum theory of atoms in mols. (QTAIM) analyses. It was shown that strength of XB interactions in the adducts increases in the order CHI3 > FIB > I2. Although halogen bonding was found to be the main preorganizing force in the structures, in the case of FIB adducts a rare Pt···I interaction was involved in addnl. stabilization of the structure. Hence, fine-tuning of halogen bonding can influence the length of the polymer, as well as the strength and directionality of interactions in the adduct. Since Hassel’s already classical work on charge-transfer interactions, halogen bonding has attracted a great deal of attention as a potentially useful instrument to organize mols. Due to the tunability, relative strength, and directionality, halogen bonding has been used as a self-assembly tool in crystal engineering. In this study classics meet classics: classical halogen bond donors XBD (such as mol. iodine, iodoform, and FIB) and classical synthons PtX2COD were used to create metallopolymeric adducts. In the obtained systems the XBD influenced the geometry (1D or 2D) and the length (heterotrimer or polymer) of the adduct. To understand differences among the obtained systems, they were further studied with computational methods, and addnl. stabilizing weak interactions were discovered. Caution: COD is hazardous to health and should be handled with care.

Different reactions of this compound(Diiodo(1,5-cyclooctadiene)platinum(II))COA of Formula: C8H12I2Pt require different conditions, so the reaction conditions are very important.

Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Diiodo(1,5-cyclooctadiene)platinum(II)(SMILESS: I[Pt]I.C1=CCC/C=CCC/1,cas:12266-72-7) is researched.SDS of cas: 86404-63-9. The article 《Solid-state 13C NMR and quantum chemical investigation of metal diene complexes》 in relation to this compound, is published in Magnetic Resonance in Chemistry. Let’s take a look at the latest research on this compound (cas:12266-72-7).

This paper presents novel measurements and calculations of the olefinic 13C chem. shift tensor principal values in several metal diene complexes. The exptl. values and the calculations show shifts as large as 70 ppm with respect to the values in the parent olefinic compounds These shifts are highly anisotropic, with the largest ones observed in the less shielded principal components and the smallest ones in the most shielded principal components of the tensor. The orientations of the principal components of the tensors remain, within 10°, at their directions in ethylene and other olefinic compounds The calculations, performed using the GIAO method and the LanDZ pseudopotential basis set, show good agreement with the experiments, and were used to establish definite evidence for the existence of a Cl-bridge structure in the bicyclo[2.2.1]hepta-2,5-diene (BCHD)dichlororuthenium(II) polymer.

Different reactions of this compound(Diiodo(1,5-cyclooctadiene)platinum(II))Computed Properties of C8H12I2Pt require different conditions, so the reaction conditions are very important.

Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Electric Literature of C8H12I2Pt. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about Synthesis and structural characterization of a tetranuclear platinum(II) metallamacrocycle containing 1,3-diisocyanoarene ligands.

A new tetranuclear platinum(II) metallamacrocycle, including four 1,3-diisocyanoarene ligands, was synthesized and characterized. The reaction of PtI2(cod) with an equimolar amount of the 1,3-diisocyanoarene ligand in dichloromethane under diluted conditions gave the metallamacrocycle [(PtI2)4(1,3-diisocyanoarene)4]. X-ray crystallog. anal. showed that the complex adopted a square ring structure with trans arrangement of coordinated isocyanides around the Pt atoms. GPC, ESI-MS, IR, and NMR anal. of the metallamacrocycle showed that the tetranuclear macrocyclic scaffold was maintained in solution The shape and dimensions of the interior cavity was estimated by force field simulations.

Different reactions of this compound(Diiodo(1,5-cyclooctadiene)platinum(II))Electric Literature of C8H12I2Pt require different conditions, so the reaction conditions are very important.

Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Diiodo(1,5-cyclooctadiene)platinum(II)(SMILESS: I[Pt]I.C1=CCC/C=CCC/1,cas:12266-72-7) is researched.SDS of cas: 86404-63-9. The article 《Solid-state 13C NMR and quantum chemical investigation of metal diene complexes》 in relation to this compound, is published in Magnetic Resonance in Chemistry. Let’s take a look at the latest research on this compound (cas:12266-72-7).

This paper presents novel measurements and calculations of the olefinic 13C chem. shift tensor principal values in several metal diene complexes. The exptl. values and the calculations show shifts as large as 70 ppm with respect to the values in the parent olefinic compounds These shifts are highly anisotropic, with the largest ones observed in the less shielded principal components and the smallest ones in the most shielded principal components of the tensor. The orientations of the principal components of the tensors remain, within 10°, at their directions in ethylene and other olefinic compounds The calculations, performed using the GIAO method and the LanDZ pseudopotential basis set, show good agreement with the experiments, and were used to establish definite evidence for the existence of a Cl-bridge structure in the bicyclo[2.2.1]hepta-2,5-diene (BCHD)dichlororuthenium(II) polymer.

Different reactions of this compound(Diiodo(1,5-cyclooctadiene)platinum(II))Computed Properties of C8H12I2Pt require different conditions, so the reaction conditions are very important.

Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Electric Literature of C8H12I2Pt. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about Synthesis and structural characterization of a tetranuclear platinum(II) metallamacrocycle containing 1,3-diisocyanoarene ligands.

A new tetranuclear platinum(II) metallamacrocycle, including four 1,3-diisocyanoarene ligands, was synthesized and characterized. The reaction of PtI2(cod) with an equimolar amount of the 1,3-diisocyanoarene ligand in dichloromethane under diluted conditions gave the metallamacrocycle [(PtI2)4(1,3-diisocyanoarene)4]. X-ray crystallog. anal. showed that the complex adopted a square ring structure with trans arrangement of coordinated isocyanides around the Pt atoms. GPC, ESI-MS, IR, and NMR anal. of the metallamacrocycle showed that the tetranuclear macrocyclic scaffold was maintained in solution The shape and dimensions of the interior cavity was estimated by force field simulations.

Different reactions of this compound(Diiodo(1,5-cyclooctadiene)platinum(II))Electric Literature of C8H12I2Pt require different conditions, so the reaction conditions are very important.

Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about Synthesis, X-ray, spectroscopic and a preliminary Suzuki coupling screening studies of a complete series of dppfMX2 (M = Pt, Pd; X = Cl, Br, I).Related Products of 12266-72-7.

A complete series of dppfMX2 (M = Pt, Pd; X = Cl, Br, I) compounds were synthesized using different routes, and characterized fully. The synthesis of dppfPdI2 was achieved by reacting Pd(COD)Cl2 with dppf in the presence of NaI. X-ray structures of dppfPdBr2 and dppfPdI2 also are reported for the 1st time. A preliminary Suzuki coupling screening study reveals that dppfPdX2 compounds are superior to the conventional Ph3P-based catalysts and bidentate phosphine-based ligands. Reactions carried out under in situ conditions also gave a similar trend, but their resp. activities were much lower than that of the fully formed catalysts.

The article 《Synthesis, X-ray, spectroscopic and a preliminary Suzuki coupling screening studies of a complete series of dppfMX2 (M = Pt, Pd; X = Cl, Br, I)》 also mentions many details about this compound(12266-72-7)Related Products of 12266-72-7, you can pay attention to it, because details determine success or failure

Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Journal of Cluster Science called Platinum(II)-silver(I) polymers bearing platinum(II) clusters containing chelated P,P- and bridged P,N-2-pyridylphosphine ligands, Author is Jones, Nathan D.; Rettig, Steven J.; James, Brian R., which mentions a compound: 12266-72-7, SMILESS is I[Pt]I.C1=CCC/C=CCC/1, Molecular C8H12I2Pt, HPLC of Formula: 12266-72-7.

Reactions of PtI2L [L = P,P-bonded 1,2-bis((2-pyridyl)phosphino)ethane, d(py)pe, or 1,2-bis((2-pyridyl)phosphino)cyclopentane, d(py)pcp] with excess AgNO3 in acetic acid/ethanol afford the polymers {[Pt2(d(py)pe)2Ag4(NO3)8]·2H2O}n (1) and [Pt2(d(py)pcp)2Ag6(NO3)10]n (2), resp., which contain (Pt2L2)4+ cores with each L ligand now P,N-bridging two Pt-atoms; these Pt2 cores are connected via bridging AgNO3 clusters, the Ag being bound to the pyridyl-N or nitrate-O atoms. X-ray crystallog. data reveal Pt-Pt contacts of ∼2.76 Å indicative of bonding.

The article 《Platinum(II)-silver(I) polymers bearing platinum(II) clusters containing chelated P,P- and bridged P,N-2-pyridylphosphine ligands》 also mentions many details about this compound(12266-72-7)HPLC of Formula: 12266-72-7, you can pay attention to it, because details determine success or failure

Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics