Category: 13820-53-6

Single palladium atoms stabilized by β-FeOOH nanorod with superior performance for selective hydrogenation of cinnamaldehyde was written by Li, Zhijun;Leng, Leipeng;Lu, Xiaowen;Zhang, Mingyang;Xu, Qian;Horton, J. Hugh;Zhu, Junfa. And the article was included in Nano Research in 2022.Name: Sodium tetrachloropalladate(II) The following contents are mentioned in the article:

Atomically dispersed single atom catalysts represent an ideal means of converting less valuable organics into value-added chems. of interest with high efficiency. Herein, we describe a facile synthetic approach to create defect-containing β-FeOOH doped with isolated palladium atoms that bond covalently to the nearby oxygen and iron atoms. The presence of singly dispersed palladium atoms is confirmed by spherical aberration correction electron microscopy and extended X-ray absorption fine structure measurements. This single palladium atom catalyst manifests outstanding catalytic efficiency (conversion: 99%; selectivity 99%; turnover frequency: 2,440 h-1) in the selective hydrogenation of cinnamaldehyde to afford hydrocinnamaldehyde. Exptl. measurements and d. functional theory (DFT) calculations elucidate the high catalytic activity and the strong metal-support interaction stem from the unique coordination environment of the isolated palladium atoms. These findings may pave the way for the facile construction of single atom catalysts in a defect-mediated strategy for efficient organic transformations in heterogeneous catalysis. [graphic not available: see fulltext]. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Name: Sodium tetrachloropalladate(II)).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Name: Sodium tetrachloropalladate(II)

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Nitrogen doped carbon-distributed and nitrogen-stabilized ultrafine FeM (M = Pd, Pt, Au) nanoclusters for doxorubicin detoxification was written by Fu, Haoyang;Li, Meirong;Xu, Qianyu;Chen, Guoliang;Zou, Yunjie;Zhang, Weixian;Li, Shuzhou;Ling, Lan. And the article was included in Applied Catalysis, B: Environmental in 2022.Electric Literature of Cl4Na2Pd The following contents are mentioned in the article:

Downsizing supported metal of Fe⁰-based materials in dealing with ever-growing pharmaceutical contamination issues are highly desired but still challenging. Herein, we develop a modular design protocol to synthesize a family of ultrafine alloy nanoclusters embedded in a nitrogen-enriched carbon framework (NEC@FeM (M=Pd, Pt, Au)). Engineering the fine structure of nitrogen-enriched carbon and interfacial interaction with bimetallic nanoclusters largely suppresses bimetallic overgrowth, eventually producing supported ultrafine (< 4 nm), highly dispersed, well-alloyed nanoclusters. The alloying Fe0 with M for ultrafine nanoclusters optimize the electron flow, chem. stability, and catalytic property, resulting in the obtained NEC@FeM exhibiting excellent doxorubicin (DOX) degradation performance. D. functional theory calculation combined with exptl. results attribute the outstanding DOX degradation ability of NEC@FePd originally to the synergistic effect of enhanced DOX affinity and efficient electrons transfer from Fe to DOX. This work provides a paradigm for the design of ultrafine Fe⁰-based nanocluster with application in pollution control. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Electric Literature of Cl4Na2Pd).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Electric Literature of Cl4Na2Pd

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Glutamine Antagonist Synergizes with Electrodynamic Therapy to Induce Tumor Regression and Systemic Antitumor Immunity was written by Chen, Gui;Xu, Qing;Feng, Zhenzhen;Xu, Qinqin;Zhang, Xuhui;Yang, Yuanyuan;Zhang, Yuxuan;Liang, Xing-Jie;Yu, Zhiqiang;Yu, Meng. And the article was included in ACS Nano in 2022.Name: Sodium tetrachloropalladate(II) The following contents are mentioned in the article:

Electrodynamic therapy (EDT) combining nanotechnol. with electronic current was used in this study to generate highly cytotoxic oxidative hydroxyl radicals (·OH) for tumor destruction. However, increasing evidence suggests that EDT treatment alone for one time still faces great challenges in achieving long-term tumor suppression in an immunosuppressive environment, which would raise the risk of later tumor recurrence. Benefitting from the marvelous potential of reactive oxygen species (ROS)-mediated dynamic therapies in tumor immunocombination therapy due to their immunogenic cell death (ICD) effect, a glutamine antagonist 6-diazo-5-oxo-L-norleucine (DON)-loaded nanocarrier (Pt-Pd@DON) was designed for combination therapy (EDT and immunotherapy) against tumor recurrence and metastasis. The protective immune response was motivated in highly immunosuppressive tumors by the joint functions of ICD and CD8⁺ T cell infiltration promoted by DON. A great therapeutic efficacy has been demonstrated in primary and metastatic tumor models, resp. This study has provided an effective thought way for clin. highly immunosuppressive tumor treatment. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Name: Sodium tetrachloropalladate(II)).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Name: Sodium tetrachloropalladate(II)

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Electrochemical Degradation of 4-Fluorophenol in a Moveable Pd-Polypyrrole Catalyst-Mediated Reactor was written by Yang, Yadan;Wei, Xuefeng;Miao, Juan;Zhang, Ruichang;Xu, Hang;Liu, Junhui;Zhu, Shufa. And the article was included in Electrocatalysis in 2022.Reference of 13820-53-6 The following contents are mentioned in the article:

Electrochem. redox is an effective method to degrade halogenated organic pollutants (HOPs). Herein, highly dispersed Pd-polypyrrole (Pd-PPy) catalysts were synthesized by a facile one-step polymerization method. The morphol. and phase structure of the catalysts were characterized by SEM (SEM), X-ray diffraction (XRD), transmission electron microscopy (TEM), and XPS. The electrochem. redox of 4-fluorophenol (4-FP) was conducted in a single-chamber reactor with Pd-PPy as a moveable catalyst. The effects of the initial solution pH, constant current, and supporting electrolyte on the degradation of 4-FP were investigated. The removal efficiency of 4-FP was 84.6% after 2 h under an initial solution pH of 2.5 and an applied c.d. of 2.0 mA/cm². The mechanism of 4-FP degradation was inferred, including the defluorination of 4-FP on the cathode and oxidation of 4-FP and phenol on the anode. The degradation of 4-FP in the Pd-PPy-mediated reactor showed lower energy consumption and higher removal efficiency. The degradation efficiency of 4-FP had almost no change after 20 cycles of experiments, which indicates the good durability of the prepared Pd-PPy catalysts. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Reference of 13820-53-6).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Reference of 13820-53-6

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Low-temperature control over deposition of ultrafine Pd nanoparticles on porous carbon nanosheets for highly efficient dehydrogenation of ammonia borane was written by Zhao, Xue;Hu, Hanyue;Li, Guo;Cai, Jiaqi;Wang, Yi;Fan, Guangyin. And the article was included in Journal of Alloys and Compounds in 2022.Formula: Cl4Na2Pd The following contents are mentioned in the article:

The search for simply synthetic strategies of small-size metal nanoparticles is of significant relevance but still faces challenges. In this paper, a method of lowtemperature regulation (LTR) of ultrafine palladium nanoparticles deposited on porous carbon nanosheets is proposed for efficient dehydrogenation of ammonia borane. The LTR method might relieve the sintering of metal particles, thereby resulting in ultrafine Pd nanoparticles of 1.7 nm and their high dispersion on porous carbon. As suggested by the catalytic experiments hereby, Pd/NPC-LTR contributes to higher turnover frequencies of ammonia borane hydrolysis relative to most Pd-based catalysts reported previously. Furthermore, the catalytic performance could be further enhanced by the addition of NaOH under the same reaction conditions, with the hydrolysis completion time shortened by 2.5 times. Moreover, the recycle tests reveal that Pd/NPC-LTR catalyst has good stability and reusability in the hydrolysis of ammonia borane, preserving 70% of its initial catalytic activity even after 10 recycles. The insights reported here can be easily extended to slick preparation and rational design of Pd-catalysts for practical applications. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Formula: Cl4Na2Pd).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Formula: Cl4Na2Pd

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Titanium carbide MXene ornamented with palladium nanoparticles for electrochemical carbon monoxide oxidation was written by Salah, Belal;Eid, Kamel;Abdelgwad, Ahmed M.;Ibrahim, Yasmeen;Abdullah, Aboubakr M.;Hassan, Mohammad K.;Ozoemena, Kenneth I.. And the article was included in Electroanalysis in 2022.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

Titanium carbide (Ti₃C₂T_x) MXene possesses various unique physicochem. and catalytic properties. However, the electrochem. CO oxidation performance is not yet addressed exptl. Herein, Ti₃C₂T_x (TX=OH, O, and F) ordered and exfoliated two-dimensional nanosheets ornamented with semi-spherical pallidum nanoparticles (2.5 Weight %) with an average diameter of (10±1 nm) (denoted as Pd/Ti₃C₂T_x) is rationally designed for the electrochem. CO oxidation The fabrication process is based on the selective chem. etching of Ti₃AlC₂ and delamination under sonication to form Ti3C2Tx nanosheets that are used as a substrate and reducing agent for supporting in situ growth of Pd nanoparticles via impregnation with Pd salt. Interestingly, Pd-free Ti₃C₂T_x displayed inferior CO oxidation activity, while Pd/Ti₃C₂T_x enhanced the CO oxidation activity substantially. This is attributed to the combination of outstanding physicochem. properties of Ti₃C₂T_x and the catalytic merits of Pd nanoparticles. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Category: chlorides-buliding-blocks).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Simultaneous Successive Twinning Captured by Atomic Electron Tomography was written by Pelz, Philipp M.;Groschner, Catherine;Bruefach, Alexandra;Satariano, Adam;Ophus, Colin;Scott, Mary C.. And the article was included in ACS Nano in 2022.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

Shape-controlled synthesis of multiply twinned nanostructures is heavily emphasized in nanoscience, in large part due to the desire to control the size, shape, and terminating facets of metal nanoparticles for applications in catalysis. Direct control of the size and shape of solution-grown nanoparticles relies on an understanding of how synthetic parameters alter nanoparticle structures during synthesis. However, while outcome populations can be effectively studied with standard electron microscopy methods, transient structures that appear during some synthetic routes are difficult to study using conventional high resolution imaging methods due to the high complexity of the 3D nanostructures. Here, we have studied the prevalence of transient structures during growth of multiply twinned particles and employed at. electron tomog. to reveal the at.-scale three-dimensional structure of a Pd nanoparticle undergoing a shape transition. By identifying over 20 000 atoms within the structure and classifying them according to their local crystallog. environment, we observe a multiply twinned structure consistent with a simultaneous successive twinning from a decahedral to icosahedral structure. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Category: chlorides-buliding-blocks).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Bromide-Mediated Reduction Kinetics and Oxidative Etching for Manipulating the Twin Structure and Facet of Pd Nanocrystals for Catalysis was written by Hsieh, Chia-Jui;Liu, Yi-Hong;Tsao, Chi-Yen;Lin, Jui-Tai;Chi, Chong-Chi;Chang, Chun-Wei;Hsiao, Yueh-Chun;Wu, Cheng-Yu;Yang, Tung-Han. And the article was included in Advanced Materials Interfaces in 2022.Synthetic Route of Cl4Na2Pd The following contents are mentioned in the article:

With Pd as an example, a set of quant. analyses is designed to shed light on the bromide-mediated reduction kinetics and oxidative etching in determining the twin structure and facet of Pd nanocrystals. The success of this work relies on the kinetic measurements of Pd(II) precursor reduction and the close examinations of resultant Pd seeds and nanocrystals at different stages of synthesis. We observe there is a clear trend where low, moderate, and high initial Pd(II) reduction rates regulated by Br- ions correspond to the formation of Pd seeds with singly-twinned, multiply-twinned, and single-crystal structures in the nucleation stage, resp. Our quant. analyses also suggest the oxidative etching induced by oxygen/Br- pair can selectively remove the multiply-twinned Pd seeds from the products in the growth stage while leaving behind singly-twinned or single-crystal Pd seeds for the evolution into Pd nanocrystals with well-defined facets in high purity. The mechanistic insights obtained in this work can be extended to the synthesis of Pd@Pd-Pt core-shell nanocubes with high-index facets, which can be used as excellent electrocatalysts and photocatalysts for hydrogen generation. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Synthetic Route of Cl4Na2Pd).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Synthetic Route of Cl4Na2Pd

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Advanced Plasmon-driven ethylene glycol oxidation over 3D ultrathin Lotus-like PdCu nanosheets was written by Zhang, Kewang;Wang, Cheng;You, Huaming;Zou, Bin;Guo, Siyu;Li, Shujin;Du, Yukou. And the article was included in Chemical Engineering Journal (Amsterdam, Netherlands) in 2022.SDS of cas: 13820-53-6 The following contents are mentioned in the article:

Coupling the unique surface plasmon resonance (SPR) of plasma metals with electrocatalysis is of huge challenge but great significance to advance alc. oxidation Herein, we demonstrate the commendable SPR effect of Cu harvesting solar energy to boost the electrocatalytic efficiency of ethylene glycol oxidation reaction (EGOR) over 3D ultrathin lotus-like PdCu nanosheets (NSs). Notably, the well-defined PdCu-2 NSs exhibit the highest mass activity (7547 mA mg^-1) to EGOR under visible light illumination, which is 1.3 times enhanced vs. in dark, as well as outclassing the Pd-homemade NSs and com. Pd/C catalyst. Meanwhile, the PdCu-2 NSs also show excellent stability in long-term durable tests. Investigations of the correlative mechanism reveal that the enhanced EGOR is mainly attributed to the SPR of Cu promoting the electron transfer from Cu to Pd, modifying the electronic structure of Pd, and facilitating the charge transport in electrochem. reactions, thus strengthening the electrocatalytic ability of Pd. This work sheds light on the SPR of plasma Cu-assisted photoelectrocatalysis to EGOR and provides new avenues to develop novel and high-efficiency photoelectrocatalysts for liquid fuel cells. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6SDS of cas: 13820-53-6).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.SDS of cas: 13820-53-6

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Biaxial strained dual-phase palladium-copper bimetal boosts formic acid electrooxidation was written by Geng, Jiarun;Zhu, Zhuo;Ni, Youxuan;Li, Haixia;Cheng, Fangyi;Li, Fujun;Chen, Jun. And the article was included in Nano Research in 2022.Synthetic Route of Cl4Na2Pd The following contents are mentioned in the article:

Surface strain engineering is considered as an effective strategy to promote the electrocatalytic properties of noble metal nanocrystals. Herein, we construct a dual-phase palladium-copper (DP-PdCu) bimetallic electrocatalyst with remarkable biaxial strain via a one-pot wet-chem. approach for formic acid oxidation The biaxial strain originates from the lattice mismatch between the disordered face-centered cubic (FCC) phase and ordered body-centered cubic (BCC) phase in each of DP-PdCu nanoparticles. The proportion of FCC and BCC phases and size of PdCu nanoparticles are dependent on the addition amount of capping agent, cetyltrimethylammonium bromide (CTAB). D. functional theory calculations reveal the downshift of d-band center of Pd atoms due to the interfacial strain, which weakens the adsorption strength of undesired intermediates. These merit the DP-PdCu catalyst with superior mass activity of 0.55 A.mg_Pd^-1 and specific activity of 1.91 mA.cm_Pd^-2 toward formic acid oxidation, outperforming the single FCC/BCC PdCu and com. Pd/C catalysts. This will provide new insights into the structure design of high-performance electrocatalysts via strain engineering. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Synthetic Route of Cl4Na2Pd).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Synthetic Route of Cl4Na2Pd

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics