Category: 13820-53-6

Ultrasound assisted synthesis of attapulgite-PdO nanocomposite using palladium complex for hydrogen storage: Kinetic studies was written by Allawi, Aumaih H.;Alheety, Mustafa A.;Mohammed, Modher Y.. And the article was included in Inorganic Chemistry Communications in 2022.Electric Literature of Cl4Na2Pd The following contents are mentioned in the article:

This research included the synthesis and characterization of new complex by in-situ method using two mole equivalent from 3,4,5-trimethoxybenzoic acid (TMB) and triphenylphosphine (PPh₃) in the presence of triethylamine (NEt₃). This complex was characterized using FTIR, ¹H NMR, ³¹P NMR, CHN, molar conductivity The results prove that TMB ligand behave as monodentate through the protonated oxygen atom of the carboxylic. This complex was used as a precursor for the synthesis of PdO@attapulgite nanocomposite which was characterized using TEM and XRD. The measurement proved that the palladium oxide nanoparticles had a pos. effect in reducing the diameter of the attapulgite channels from 160 nm to the range 90-95 nm. This nanocomposite was used as a potential material for hydrogen storage. The results of hydrogen storage showed that the composite has the ability to store hydrogen even at low pressures, as the composite had the ability to store âˆ?% at 30 bar and reached 3.81% at 90 bar. The kinetic studies prove that the storage fit to the pseudo-second order with coefficient factor equal to 0.9278 and the hydrogen storage was reached the maximum (3.81%) after only 200 s. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Electric Literature of Cl4Na2Pd).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Electric Literature of Cl4Na2Pd

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Achieving Z-scheme charge transfer through constructing Bi₄Ti₃O₁₂/Pd@Au/Ag₂S heterostructure for photoelectrochemical aptasensor of Hg²⁺ detection was written by Luo, Jing;Shao, Xinrong;Gong, Zhengxing;Sun, Xu;Ma, Hongmin;Wu, Dan;Fan, Dawei;Li, Yuyang;Wei, Qin;Ju, Huangxian. And the article was included in Sensors and Actuators, B: Chemical in 2022.Electric Literature of Cl4Na2Pd The following contents are mentioned in the article:

An ultrasensitive photoelectrochem. (PEC) aptasensor based on Bi₄Ti₃O₁₂/Pd@Au/Ag₂S was proposed for the detection of Hg²⁺. The indium tin oxide (ITO) electrode was first decorated with the nested hollow bismuth titanate (Bi₄Ti₃O₁₂) that functioned with Pd@Au as an electron mediator to accelerate the photocurrent conversion, and then silver sulfide (Ag₂S) nanoparticles were grown in-situ to enhance the PEC response. The band gap of Ag₂S is so narrow that photogenerated electrons are easily generated under illumination. Pd@Au acts as an electron medium to facilitate electron transfer from the conduction band of Ag₂S to the valence band of Bi₄Ti₃O₁₂. The quant. detection of Hg²⁺ was achieved based on the thymidine-Hg²⁺-thymidine (T-Hg²⁺-T) specific interaction. The results showed that the PEC aptasensor showed a wide linear range (1 mM-0.1 pM) and a low detection limit (19 fM). In addition, the aptasensor has excellent selectivity, reproducibility and stability, providing a feasible method for the detection of Hg²⁺. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Electric Literature of Cl4Na2Pd).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Electric Literature of Cl4Na2Pd

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Kinetics-controlled synthesis of gold-palladium alloy nano-corolla using a syringe pump and their applications for ethanol oxidation reaction was written by Zhang, Haifeng;Zhang, Gongguo;Zheng, Yiqun;Zhao, Na;Ma, Yanyun;Liu, Feng;Liu, Maochang. And the article was included in Journal of Nanoparticle Research in 2022.Related Products of 13820-53-6 The following contents are mentioned in the article:

Gold-palladium (AuPd) alloy nano-corolla are successfully prepared in high purity, followed by exploration as electrocatalysts for electroxidn. of ethanol (EOR) in alk. medium. Applying kinetics control on the one-pot formation process using a syringe pump is emphasized, where the Au/Pd precursor solution is dropwise titrated into the reaction mixture containing capping agent and reductant at an elevated temperature We perform systematical investigation towards the morphol. evolution pathway and effects of several key parameters. After loading on carbon black, the current AuPd alloy nano-corolla exhibit superb specific activity, reaction kinetics, and operation stability for EOR, showing morphol. and structural merit. The present study provides insight into fabrication of bimetallic alloy nanocrystals with open structure, which could find important use in crystal engineering for multimetallic nanocrystals and rational design of fuel cell electrocatalyst. Graphical abstract: Gold-palladium (AuPd) alloy nanocrystals in the form of corolla are successfully prepared via kinetic-controlled synthesis in high purity, exhibit improved activity and stability as EOR electrocatalysts in KOH solution [graphic not available: see fulltext]. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Related Products of 13820-53-6).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Related Products of 13820-53-6

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Dichlorido(4-methylaniline-ΚN)[N-(4-methylphenyl)-1-(thiophen-2-yl)methanimine-ΚN]palladium(II) was written by Butcher, Ray J.;Singh, Puspendra;Shabbani, Gulam. And the article was included in Acta Crystallographica in 2022.COA of Formula: Cl4Na2Pd The following contents are mentioned in the article:

The structure of a mono-amine Pd^II complex, [PdCl₂(C₇H₉N)(C₁₂H₁₁NS)], which crystallizes in the triclinic space group, P1, is reported. The primary geometry around the Pd^II atom closely resembles square planar (τ4â€?= 0.069). In the (E)-1-(thiophen-2-yl)-N-(p-tolyl)methanimine ligand, the Ph and thiophene rings are not coplanar, subtending a dihedral angle of 38.5 (1)° because of steric effects. The PdCl₂N₂ coordination plane is almost perpendicular to the planes of the coordinated o-toluidine and the NC₂ fragment [dihedral angles of 84.7 (1) and 72.50 (4)°, resp.]. The Pd-NH₂ length of 2.040 (2) Å is slightly shorter than the observed mean value for other complexes involving a Pd atom attached to the nitrogen of an aniline derivative The mols. display an interesting supramol. synthon based on reciprocal intermol. N-H···Cl hydrogen-bonding interactions of the p-toluidine amine fragment, which results in centrosym. dimeric units. These units are further linked by C-H···Cl interactions, resulting in chains in the c-axis direction where the mean-planes of the repeating fragment are oriented in the (110) plane. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6COA of Formula: Cl4Na2Pd).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.COA of Formula: Cl4Na2Pd

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Synergetic effect between Pd²⁺ and Ir⁴⁺ species promoting direct ethane dehydrogenation into ethylene over bimetallic PdIr/AC catalysts was written by Zhang, Ling;Sun, Jikai;Jiang, Shuchao;He, Huijie;Ren, Guoqing;Zhai, Dong;Tu, Rui;Zhai, Shengliang;Yu, Tie. And the article was included in Catalysis Science & Technology in 2022.Electric Literature of Cl4Na2Pd The following contents are mentioned in the article:

This work reported an efficient PdIr/activated carbon (PdIr/AC) catalyst and its application during direct ethane dehydrogenation (EDH) into ethane. The XRD and HADDF-STEM results revealed Pd/Ir nano-particles and atomically dispersed Pd²⁺ and Ir⁴⁺ species simultaneously. The activity tests demonstrated that Ir species showed higher C₂H₄ selectivity than Pd species and the co-presence of Pd/Ir could further improve the catalytic stability and inhibit carbon deposition over the bimetallic Pd/Ir catalyst. Nevertheless, raising the reaction temperature from 500°C to 600°C boosted coking including carbon nanotubes (CNTs) and carbon particles. XPS results of Pd7Ir2/AC-B after Ar or H₂ pretreatment proved that the active sites are Pd²⁺/Ir⁴⁺ species. The simulation results exposed the reaction pathway over Ir⁴⁺/Pd²⁺ species, and ethane dehydrogenation was the rate-determining step over the PdIr/AC sample; meanwhile, the synergetic effect between Pd²⁺ and Ir⁴⁺ increased their TOF (C₂H₄). Finally, a deactivation mechanism was also proposed to examine the coking over various metal species. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Electric Literature of Cl4Na2Pd).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Electric Literature of Cl4Na2Pd

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

2-Pyridyl-benzimidazole-Pd(II)/Pd(0) Supported on Magnetic Mesoporous Silica: Aerobic Oxidation of Benzyl Alcohols/Benzaldehydes and Reduction of Nitroarenes was written by Sajedi, Mohammad;Mansoori, Yagoub;Nuri, Ayat;Fekri, Somayeh;Esquivel, Dolores;Navarro, Ma Angeles. And the article was included in Catalysis Surveys from Asia in 2022.Name: Sodium tetrachloropalladate(II) The following contents are mentioned in the article:

2-(2-Pyridyl)benzimidazole (PyBzIm) was supported onto magnetic mesoporous silica, Fe₃O₄@SiO₂@SBA-15 via the click chem. The supported ligand was treated with Na₂PdCl₄ in methanol to afford Fe₃O₄@SiO₂@SBA-PyBzIm-Pd(II) as a magnetically retrievable supported catalyst. The catalyst was fully characterized by conventional methods. XPS studies confirmed some C = N nitrogen atoms interact with palladium in the + 2 oxidation state. The prepared catalyst was found to catalyze the aerobic oxidation of benzyl alcs. and benzaldehydes to the corresponding benzoic acids, and excellent conversions were obtained. The magnetic catalyst showed a very low metal leaching (3.9%) in the first run. Fe₃O₄@SiO₂@SBA-PyBzIm-Pd(II) was then treated with aqueous NaBH₄ to give Fe₃O₄@SBA-PyBzIm-Pd(0). The obtained catalyst was found to catalyze the transfer hydrogenation of nitroarenes to the corresponding anilines in the presence of hydrazine, and excellent yields were obtained. The prepared catalysts present an excellent recycling efficiency over seven consecutive runs without significant loss of catalyst reactivity. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Name: Sodium tetrachloropalladate(II)).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Name: Sodium tetrachloropalladate(II)

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Rapid and efficient reduction of chromate by novel Pd/Fe@biomass derived from Enterococcus faecalis was written by Wei, Xiaorong;Zhu, Nengwu;Huang, Junlin;Kang, Naixin;Li, Fei;Wu, Pingxiao;Dang, Zhi. And the article was included in Environmental Research in 2022.Name: Sodium tetrachloropalladate(II) The following contents are mentioned in the article:

Efficient reduction of chromate is highly desirable for its detoxification and remediation of the contaminated environment. This study described a fusion of the concepts of precious metal biorecovery and fabrication of Pd/Fe@biomass derived from simulated wastewater. The effectiveness of Pd/Fe@biomass during reduction process of Cr(VI) was evaluated by comparing with pure nZVI, E. faecalis and Pd@biomass. Results showed that Pd(II) could be recovered by E. faecalis with Fe(II) as the electron donor, and precipitation could yield nZVI anchored onto Pd-loaded E. faecalis. The nano particles (NPs) on Pd/Fe@biomass were well-dispersed, which provided 2.70 folds sp. surface area comparing with nZVI. Efficient Cr(VI) reduction could be achieved at a higher catalyst dosage, the most appropriated Pd/Fe molar ratio of 2% and a wide pH range. Typically, 0.5 mM Cr(VI) could be completely reduced in 5 min driven by Pd/Fe@biomass under the conditions of dosage of 1.0 g/L and pH 3. Moreover, the mechanisms of Cr(VI) reduction by Pd/Fe@biomass were proposed, which intimately related to nZVI electron donating capacities, Pd catalysis for hydrogenation and galvanic cell effects between Fe and Pd. Therefore, Pd/Fe@biomass could be an alternative for rapid and complete reduction of Cr(VI). This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Name: Sodium tetrachloropalladate(II)).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Name: Sodium tetrachloropalladate(II)

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Controlled Growth of Single-Crystal Pd Quantum Dots on 2D Carbon for Large Current Density Hydrogen Evolution was written by Zhang, Danyan;Zheng, Xuchen;Qi, Lu;Xue, Yurui;He, Feng;Li, Yuliang. And the article was included in Advanced Functional Materials in 2022.COA of Formula: Cl4Na2Pd The following contents are mentioned in the article:

The key issue for industrial large-scale hydrogen production by water electrolysis is developing environment-friendly electrocatalysts that can work well at large current densities and low overpotentials. Thanks to the superior advantages of 2D graphdiyne (GDY) on chem. structure and the alkyne bond strong reductivity, the highly selective, in situ growth of the single-crystal Pd (111) quantum dots is achieved. The metal dots distribute uniformly and densely on the GDY surface (GDY-Pd1) in a controllable way at low temperatures without adding addnl. reductive agents. Exptl. and theor. results show that the 2D GDY affords an ideal platform to construct highly selective and active electrocatalysts with accurate structures, defined valence states, facilitated charge transfer ability, and enhanced elec. conductivity for hydrogen evolution reaction. Remarkably, the electrocatalyst can reach 500 and 1000 mA cm^-2 at small overpotentials of only 201 and 261 mV, with high long-term stability, which are better than most of the reported ones. The results demonstrate that 2D DGY is an excellent support in the controllable synthesis of metal quantum dots with well-defined surface and structure and the potential to achieve large-scale preparation This study takes a critical step toward industrial hydrogen production This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6COA of Formula: Cl4Na2Pd).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.COA of Formula: Cl4Na2Pd

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Biocompatible pericarpium citri reticulatae polysaccharide templated Pd nanoparticles for effectively colorimetric detection of glutathione was written by Li, Shukai;Zhao, Yu;Ji, Fangqin;Zheng, Ruixue;Ji, Xianbing;Liu, Zhiwei;Wang, Longgang. And the article was included in Colloids and Surfaces, A: Physicochemical and Engineering Aspects in 2022.Application In Synthesis of Sodium tetrachloropalladate(II) The following contents are mentioned in the article:

Glutathione as a natural antioxidant can protect the human body from free radicals produced by oxidative stress. Therefore, it’s quite necessary to measure the concentration of glutathione to ensure our health. Herein, we prepared biocompatible pericarpium citri reticulatae polysaccharide templated palladium nanoparticles (Pdn-PCRP NPs, n = 150, 225, 300) by a green and facile synthetic method. The sizes of Pd150-PCRP NPs, Pd225-PCRP NPs, and Pd300-PCRP NPs were 2.10 ± 0.62 nm, 2.48 ± 0.62 nm, and 2.63 ± 0.62 nm, resp. Pd150-PCRP NPs exhibited excellent biocompatibility based on the MTT assay. Moreover, Pd150-PCRP NPs oxidized the colorless peroxidase substrates 3,3′,5,5′ -tetramethylbenzidine (TMB) to its corresponding blue product in the presence of hydrogen peroxide. More importantly, Pd150-PCRP NPs were used in the colorimetric detection of glutathione. The detection range of colorimetric detection with Pd150-PCRP NPs reached 2-300μM and the detection limit was 1.65μM. The recovery rate of glutathione in serum samples was as high as 103.60%. Overall, these results demonstrated that Pd150-PCRP NPs had good biocompatibility, peroxidase-like activity and ability of glutathione detection. Pd150-PCRP NPs could serve as a safe and promising agent for sensitive detection of glutathione in future applications. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Application In Synthesis of Sodium tetrachloropalladate(II)).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Application In Synthesis of Sodium tetrachloropalladate(II)

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Photoinduction of palladium single atoms supported on defect-containing γ-AlOOH nanoleaf for efficient trans-stilbene epoxidation was written by Li, Zhijun;Li, Honghong;Yuan, Dundong;Leng, Leipeng;Zhang, Mingyang;Di, Minghui;Horton, J. Hugh;Wang, Jun;Sun, Litao;Sun, Weiwei. And the article was included in Chemical Engineering Journal (Amsterdam, Netherlands) in 2022.Formula: Cl4Na2Pd The following contents are mentioned in the article:

Exploring the interaction between metal and support is of great importance in enhancing the catalytic performance and deepening the mechanistic understanding of single atom catalysis. Here we describe a photoinduction method to construct atomically dispersed palladium atoms supported over defect-containing boehmite (γ-AlOOH) nanoleaf with a palladium loading of 0.32 wt%. The existence of singly dispersed palladium atoms is confirmed by spherical aberration correction electron microscopy, extended X-ray absorption fine structure measurement, and CO-absorbed diffuse reflectance IR Fourier transform spectroscopy. This catalyst shows excellent catalytic efficiency in trans-stilbene epoxidation to yield trans-stilbene oxide (TOF: 416 h^-1; conversion: 84 %; selectivity: 99 %), along with excellent recyclability and scalability. In addition, various aromatic olefins were successfully transformed into the corresponding epoxides with high selectivity and excellent yield. DFT study further reveals that the high catalytic activity originates from under-coordinated single palladium atoms in the defect-containing γ-AlOOH in a unique coordination environment. This lays the foundation for the facile creation of single atom catalysts and sheds light on the possibility for scale-up production This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Formula: Cl4Na2Pd).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Formula: Cl4Na2Pd

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics