Category: 14070-51-0

N-chlorosaccharin oxidation of propan-2-ol: a kinetic study was written by Singh, Sanjay K.;Arora, Monika;Kaur, Gurpreet;Kaur, Raman Deep;Gujral, Harjeet. And the article was included in Archives of Applied Science Research in 2010.Category: chlorides-buliding-blocks This article mentions the following:

Oxidation of propan-2-ol by N-chlorosaccharin (NCSA) in aqueous acetic acid medium has been carried out. The reactions exhibit first-order in oxidant and fractional order with substrate. The rate of oxidation increases with increase of acetic acid in medium while retarding by the addition of saccharin. This oxidation is acid catalyzed. The effect of temperature on reaction rate has also been studied. The thermodn. parameters have been calculated Based on all the kinetic data a possible operative mechanism has been proposed and a suitable rate law has been derived. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0Category: chlorides-buliding-blocks).

2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

N-chloro amides, lactams, carbamates, and imides. New classes of initiators for the metal-catalyzed living radical polymerization of methacrylates was written by Percec, Virgil;Grigoras, Cristian. And the article was included in Journal of Polymer Science, Part A: Polymer Chemistry in 2005.Safety of 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide This article mentions the following:

Metal-catalyzed living radical polymerization of Me methacrylate initiated with N-chloro amides (N-chloro N-Et propionamide, N-chloro benzanilide, N-chloro methylbenzamide, and N-chloro acetanilide), lactams (N-chloro caprolactam and N-chloro 2-pyrrolidinone), carbamates or urethanes (N-chloro ethylcarbamate or N-chlorourethane), imides (N-chloro phthalimide, N-chloro succinimide, trichloroisocyanuric acid, and N-chloro saccharin) and catalyzed with the self-regulated catalytic system Cu₂S/2,2′-bipyridine is reported. The initiation efficiency of these initiators is determined by their structure. Regardless of the initiator efficiency, in all cases, poly(Me methacrylate) with narrow mol. weight distribution and functionalized chain-ends was obtained. These new classes of initiators open new strategies for the functionalization of polymer chain-ends and for the synthesis of complex architectures by graft copolymerization initiated from N-chloro proteins, aliphatic, aromatic and semiarom. polyamides, and polyurethanes. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0Safety of 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide).

2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Safety of 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Selective Silylation of Alcohols, Phenols and Oximes Using N-Chlorosaccharin as an Efficient Catalyst under Mild and Solvent-Free Conditions was written by Aghapour, Ghasem;Kazemi Moghaddam, Ali;Nadali, Samaneh. And the article was included in Journal of the Chinese Chemical Society (Weinheim, Germany) in 2015.Application In Synthesis of 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide This article mentions the following:

Efficient silylation of OH group in alcs., phenols and oximes using a catalytic amount of N-chlorosaccharin and hexamethyldisilazane (HMDS) under mild and solvent-free conditions is described. This silylation reaction can be carried out with excellent and interesting selectivities. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0Application In Synthesis of 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide).

2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Application In Synthesis of 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

NX···Y halogen bonds. Comparison with NH···Y H-bonds and CX···Y halogen bonds was written by Nepal, Binod;Scheiner, Steve. And the article was included in Physical Chemistry Chemical Physics in 2016.SDS of cas: 14070-51-0 This article mentions the following:

Quantum calculations examine how the NH···Y H-bond compares to the equivalent NX···Y halogen bond, as well as to comparable CH/CX donors. Succinimide and saccharin, and their corresponding halogen-substituted derivatives, are chosen as the prototype NH/NX donors, paired with a wide range of electron donor mols. The NH···Y H-bond is weakened if the bridging H is replaced by Cl, and strengthened by I; a Br halogen bond is roughly comparable to a H-bond. The lone pairs of the partner mol. are stronger electron donors than are π-systems. Whereas Coulombic forces represent the largest fraction of the attractive force in the H-bonds, induction energy is magnified in the halogen bonds, surpassing electrostatics in several cases. Mutation of NH/NX to CH/CX weakens the binding energy to roughly half its original value, while also lengthening the intermol. distances by 0.3-0.8 Å. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0SDS of cas: 14070-51-0).

2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.SDS of cas: 14070-51-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Preparation of several active N-chloro compounds from trichloroisocyanuric acid was written by Shiri, Azam;Khoramabadi-zad, Ahmad. And the article was included in Synthesis in 2009.Name: 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide This article mentions the following:

A very simple method for the preparation of several active N-chloro compounds that have extensive applications in organic synthesis, industry, and medicine was developed. Tetrachloroglycolurils, chloramine-T, N-chlorosaccharin, N-chlorosuccinimide, N-chlorophthalimide, N,N’-dichlorophenobarbital, and N,N’-dichlorobarbital were synthesized by chlorination with trichloroisocyanuric acid under mild reaction conditions at room temperature This method is clean, fast, and efficient; the yields are also good to excellent. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0Name: 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide).

2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Name: 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics