Category: 1451391-17-5

Pearce-Higgins, Robert published the artcileAn Enantioselective Suzuki-Miyaura Coupling To Form Axially Chiral Biphenols, Related Products of chlorides-buliding-blocks, the publication is Journal of the American Chemical Society (2022), 144(33), 15026-15032, database is CAplus and MEDLINE.

The use of enantiopure, sulfonated SPhos (sSPhos), an existing ligand that has until now been used only in racemic form and that derived its chirality from an atropisomeric axis that was introduced through sulfonation. The attractive noncovalent interactions involving the ligand sulfonate group was responsible for the high levels of asym. induction that we obtain in the 2,2′-biphenol products of Suzuki-Miyaura coupling, and a highly practical resolution of sSPhos via diastereomeric salt recrystallization was developed.

Journal of the American Chemical Society published new progress about 1451391-17-5. 1451391-17-5 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Boronic acid and ester,Benzene,Phenol,Boronate Esters,Boronic Acids,Boronic acid and ester,, name is 3-Chloro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol, and the molecular formula is C12H16BClO3, Related Products of chlorides-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Homma, Yuki published the artcileRuthenium-catalyzed regio- and site-selective ortho C-H borylation of phenol derivatives, Recommanded Product: 3-Chloro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol, the publication is Chemical Communications (Cambridge, United Kingdom) (2020), 56(73), 10710-10713, database is CAplus and MEDLINE.

Efficient synthesis of o-borylphenols, e.g. I, is achieved through the Ru-catalyzed regio- and site-selective sp² C-H borylation of aryl diphenylphosphinites followed by removal of the phosphorus directing group. A successful application to aryl phosphites enables practical one-pot borylation of phenols, demonstrating high synthetic utility of this protocol.

Chemical Communications (Cambridge, United Kingdom) published new progress about 1451391-17-5. 1451391-17-5 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Boronic acid and ester,Benzene,Phenol,Boronate Esters,Boronic Acids,Boronic acid and ester,, name is 3-Chloro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol, and the molecular formula is C12H16BClO3, Recommanded Product: 3-Chloro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics