Platonov, Dmitry N. published the artcileIonic Cyclopropenium-Derived Triplatinum Cluster Complex [(Ph3C3)2Pt3(MeCN)4]2+(BF4–)2: Synthesis, Structure, and Perspectives for Use as a Catalyst for Hydrosilylation Reactions, Formula: C9H20Cl2Si, the publication is Organometallics (2021), 40(23), 3876-3885, database is CAplus.
This study presents a methodol. for the synthesis of the ionic cyclopropenium-derived triplatinum cluster complex [(Ph3C3)2Pt3(MeCN)4]2+(BF4–)2 and its analog with the replacement of one of the BF4– anions with a Cl– anion, which represents a chain coordination polymer in crystalline form. The structures of the complexes were studied by several physicochem. methods, primarily x-ray diffraction using synchrotron radiation and 195Pt NMR spectroscopy in solution with measurement and anal. of the 195Pt-195Pt and 13C-195Pt spin-spin coupling constants A high catalytic activity of the synthesized Pt3 complex was observed in hydrosilylation reactions. The catalytic efficiency of the complex is comparable to that of Karstedt’s catalyst and in some cases even higher.
Organometallics published new progress about 14799-93-0. 14799-93-0 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(methyl)(octyl)silane, and the molecular formula is C9H20Cl2Si, Formula: C9H20Cl2Si.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics