Category: 22519-64-8

Yang, Yang; Ohnoutek, Lukas; Ajmal, Saira; Zheng, Xiuzhen; Feng, Yiqing; Li, Kejian; Wang, Tao; Deng, Yue; Liu, Yangyang; Xu, Dong; Valev, Ventsislav K.; Zhang, Liwu published the artcile< ""Hot edges"" in an inverse opal structure enable efficient CO2 electrochemical reduction and sensitive in situ Raman characterization>, COA of Formula: Cl3H8InO4, the main research area is carbon dioxide electrochem reduction sensitivity inverse opal structure.

Conversion of CO2 into fuels and chems. via electroreduction has attracted significant interest. Via mesostructure design to tune the elec. field distribution in the electrode, it is demonstrated that the Cu-In alloy with an inverse opal (CI-1-IO) structure provides efficient electrochem. CO2 reduction and allows for sensitive detection of the CO2 reduction intermediates via surface-enhanced Raman scattering. The significant enhancement of Raman signals of the intermediates on the CI-1-IO surface can be attributed to elec. field enhancement on the “”hot edges”” of the inverse opal structure. Addnl., a highest CO2 reduction faradaic efficiency (FE) of 92% (sum of formate and CO) is achieved at -0.6 V vs. RHE on the CI-1-IO electrode. The diffuse reflectance IR Fourier transform spectroscopy (DRIFTS) results show that the Cu-In alloy with an inverse opal structure has faster adsorption kinetics and higher adsorption capacity for CO2. The “”hot edges”” of the bowl-like structure concentrate elec. fields, due to the high curvature, and also concentrate K+ on the active sites, which can lower the energy barrier of the CO2 reduction reaction. This research provides new insight into the design of materials for efficient CO2 conversion and the detection of intermediates during the CO2 reduction process.

Journal of Materials Chemistry A: Materials for Energy and Sustainability published new progress about Current density. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, COA of Formula: Cl3H8InO4.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Yi, Xiaofeng; Wang, Di; Li, Fan; Zhang, Jian; Zhang, Lei published the artcile< Molecular bixbyite-like In12-oxo clusters with tunable functionalization sites for lithography patterning applications>, Recommanded Product: Indium(III) chloride tetrahydrate, the main research area is indium oxo cluster mol bixbyite lithog patterning application.

Indium oxides have been widely applied in many technol. areas, but their utilization in lithog. has not been developed. Herein, we illustrated a family of unprecedented In12-oxo clusters with a general formula [In12(Μ4-O)4(Μ2-OH)2(OCH2CH2NHCH2CH2O)2(OR)4X4]X2 (where X = Cl or Br; R = CH3, C6H4NO2 or C6H4F), which not only present the largest size record in the family of indium-oxo clusters (InOCs), but also feature the first mol. model of bixbyite-type In2O3. Moreover, through the labile coordination sites of the robust diethanolamine-stabilized In12-oxo core, these InOCs can be accurately functionalized with different halides and alc. or phenol derivatives, producing tunable solubility Based on the high solution stability as confirmed by ESI-MS anal., homogeneous films can be fabricated using these In12-oxo clusters by the spin-coating method, which can be further used for electron beam lithog. (EBL) patterning studies. Accordingly, the above structural regulations have significantly influenced their corresponding film quality and patterning performance, with bromide or p-nitrophenol functionalized In12-oxo clusters displaying better performance of sub-50 nm lines. Thus, the here developed bixbyite-type In12-oxo cluster starts the research on indium-based patterning materials and provides a new platform for future lithog. radiation mechanism studies.

Chemical Science published new progress about Atomic force spectroscopy. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, Recommanded Product: Indium(III) chloride tetrahydrate.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Liu, Lin; Liu, Jiaqing; Yang, Weijie; Wan, Jun; Fu, Feng; Wang, Danjun published the artcile< Constructing a Z-scheme ZnIn2S4-S/CNTs/RP nanocomposite with modulated energy band alignment for enhanced photocatalytic hydrogen evolution>, Application of Cl3H8InO4, the main research area is zinc indium sulfide carbon red phosphorus photocatalytic hydrogen evolution; Energy band alignment; Nanocomposite; Photocatalytic hydrogen evolution; Red phosphorus; Sulfur vacancies.

Energy band structures greatly determine the charge separation and transfer properties in heterojunction photocatalysts and consequently their photocatalytic activities. Herein, a well-designed Z-scheme ZnIn2S4-S/CNTs/RP (ZIS-S/CNTs/RP) nanocomposite was fabricated according to an energy band alignment steering strategy to realize superior photocatalytic H2 evolution performance. The ZIS-S/CNTs/RP nanocomposite shows an efficient photocatalytic H2 evolution rate of 1639.9μmol g-1h-1, which is noticeably higher than that of pristine red phosphorus (RP) and CNTs/RP and ZIS-S/RP composites, as well as those of the compared heterojunctions using bulk RP or ZnIn2S4. Owing to the modification of nanosized RP and the introduction of sulfur vacancies in ZnIn2S2, a tailored energy band alignment of the heterojunction with a higher reduction potential and larger Fermi level p.d. was achieved, which resulted in significantly increased photogenerated electron-hole separation efficiency and a more efficient Z-scheme charge transfer mechanism, thus promoting the photocatalytic activity of ZIS-S/CNTs/RP. This work aims to provide a novel effective strategy for the construction of high-performance heterojunction photocatalysts by energy band engineering.

Journal of Colloid and Interface Science published new progress about Band structure. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, Application of Cl3H8InO4.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Su, Hang; Lou, Hongming; Zhao, Zhipeng; Zhou, Lan; Pang, Yuxia; Xie, Haijiao; Rao, Cheng; Yang, Dongjie; Qiu, Xueqing published the artcile< In-situ Mo doped ZnIn2S4 wrapped MoO3 S-scheme heterojunction via Mo-S bonds to enhance photocatalytic HER>, Computed Properties of 22519-64-8, the main research area is molybdenum doped indium zinc sulfide hydrogen evolution reaction photocatalyst.

The construction of ZnIn2S4 based heterogeneous structure combined with in-situ relatively metal doping remains a great challenge. A direct Step-scheme (S-scheme) of in-situ Mo doped ZnIn2S4 wrapped MoO3 (MoO3@Mo-ZIS) was prepared in this work based on the thermal solubility properties of MoO3. The optimized photocatalyst of MoO3@Mo-ZIS exhibits superior H2 evolution rate of 5.5 mmol/g/h without co-catalysts, which is the 6.5 and 1.3 times of ZIS and 40 Mo doped ZIS (40 Mo-ZIS), resp. The excellent photocatalytic activity was attributed to the Mo doping and formation of Mo-S species. The d. functional theory (DFT) calculations demonstrate that the Mo-S species would form a new hybridized state near the Fermi level, reducing the ΔGH* to enhance photocatalytic hydrogen evolution reaction (HER). Furthermore, the direct S-scheme heterojunction of MoO3@Mo-ZIS confirmed by ESR (EPR) and Kelvin probe force microscopy (KPFM) promotes photogenerated carrier separation, thus enhancing the performance of photocatalytic HER.

Chemical Engineering Journal (Amsterdam, Netherlands) published new progress about Density functional theory. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, Computed Properties of 22519-64-8.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Pan, Jingwen; Guan, Zhongjie; Yang, Jianjun; Li, Qiuye published the artcile< Facile fabrication of ZnIn2S4/SnS2 3D heterostructure for efficient visible-light photocatalytic reduction of Cr(VI)>, Product Details of Cl3H8InO4, the main research area is tin zinc indium sulfide chromium heterostructure light photocatalytic reduction.

Photocatalytic method has been intensively explored for Cr(VI) reduction owing to its efficient and environmentally friendly natures. In order to obtain a high efficiency in practical application, efficient photocatalysts need to be developed. Here, ZnIn2S4/SnS2 with a three-dimensional (3D) heterostructure was prepared by a hydrothermal method and its photocatalytic performance in Cr(VI) reduction was investigated. When the mass ratio of SnS2 to ZnIn2S4 is 1:10, the ZnIn2S4/SnS2 composite exhibits the highest photocatalytic activity with 100% efficiency for Cr(VI) (50 mg/L) reduction within 70 min under visible-light irradiation, which is much higher than those of pure ZnIn2S4 and SnS2. The enhanced charge separation and the light absorption have been confirmed from the photoluminescence and UV-vis absorption spectra to be the two reasons for the increased activity towards photocatalytic Cr(VI) reduction In addition after three cycles of testing, no obvious degradation is observed with the 3D heterostructured ZnIn2S4/SnS2, which maintains a good photocatalytic stability.

Chinese Journal of Catalysis published new progress about Absorption. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, Product Details of Cl3H8InO4.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Zeng, Chao; Hu, Yingmo published the artcile< Hydrothermal synthesis of a CoIn2S4/g-C3N4 heterojunctional photocatalyst with enhanced photocatalytic H2 evolution activity under visible light illumination>, Category: chlorides-buliding-blocks, the main research area is cobalt indium sulfide carbon nitride hydrogen heterojunction photocatalyst; hydrogen hydrothermal treatment photocatalytic activity.

CoIn2S4, a black semiconducting material, possesses an outstanding visible light response and is employed to modify g-C3N4. A series of CoIn2S4/g-C3N4 heterojunctional photocatalysts are synthesized via a hydrothermal method, whereby cubic CoIn2S4 nanosheets are in situ immobilized on the surfaces of porou g-C3N4 nanosheets. Compared with the pristine g-C3N4 and CoIn2S4, under visible light (λ> 420 nm) irradiation, the CoIn2S4/g-C3N4 composite samples show markedly enhanced photocatalytic activity in hydrogen evolution. Among all of the samples, the 30% CoIn2S4/g-C3N4 sample shows the maximum H2 evolution rates, 5.2 and 23.9 times higher than those of g-C3N4 and CoIn2S4, resp. The efficient photocatalytic activity of CoIn2S4/g-C3N4 composite photocatalysts is attributed to the formation of an intimate heterostructure, which not only significantly facilitates charge migration, but also enhances visible light absorption. Moreover, a plausible photocatalytic mechanism for the composite photocatalyst has been elucidated. This research provides a novel hint for fabricating visible-light-responsive heterojunction photocatalysts with high performance for energy production

Nanotechnology published new progress about Absorption. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, Category: chlorides-buliding-blocks.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Hameurlaine, Edhawya; Guezzoul, M’hamed; Bouslama, M’HAMMED; Ouerdane, Abdellah; Derri, Amira; Bedrouni, Mahmoud; Bensassi, Kadda Benmohktar; Baizid, Abdelhak; Abdelkrim, Mahfoud; Kharoubi, Bachir published the artcile< IMPACT OF INDIUM DOPING ON ZnO THIN FILM SUBJECTED TO APPROPRIATE UHV TREATMENT CHARACTERIZED BY XPS, XRD, AND PL TECHNIQUES>, Recommanded Product: Indium(III) chloride tetrahydrate, the main research area is indium doping zinc oxide thin film UHV treatment; photoluminescence X ray diffraction photoelectron spectroscopy.

The chem. composition, crystalline structure and optical properties of un-doped ZnO (UZO) and indium (6%)-doped ZnO (IZO) thin films grown on Si substrate were studied using XPS, X-ray diffraction (XRD) and photoluminescence (PL) techniques. The results are complementary and confirm each other. The surface is cleaned using checked ultra-high vacuum (UHV) treatment (argon ion sputtering followed by successive heating). For IZO, the XPS anal. displays that the indium incorporates in the ZnO matrix to form the In-O-Zn-type chem. bonds. The PL of UZO reveals structural defects, including oxygen interstitial (Oi), oxygen vacancies (VO), zinc vacancies (VZn) and interstitial zinc (Zni), and they decrease with the In doping and UHV treatment. For IZO, the PL measurements show the great interest of UHV treatment to stimulate the incorporation of indium into the ZnO matrix. There is an increase in the UV emission intensity and improvement of its phys. structure. The In (6%) doping of ZnO is convenient to compensate the zinc vacancies (VZn), eliminate Zni and VO, and ensure the structural homogeneity of IZO film. All the detected peaks of the XRD patterns are matched to the wurtzite crystalline structure for both UZO and IZO thin films grown mainly along the (002) orientation plane.

Surface Review and Letters published new progress about Binding energy. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, Recommanded Product: Indium(III) chloride tetrahydrate.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Qiu, Jianhao; Li, Ming; Xu, Jie; Zhang, Xiong-Fei; Yao, Jianfeng published the artcile< Bismuth sulfide bridged hierarchical Bi2S3/BiOCl@ZnIn2S4 for efficient photocatalytic Cr(VI) reduction>, Product Details of Cl3H8InO4, the main research area is epitaxial heterostructure photocatalyst photocatalytic reduction wastewater treatment; Bi(2)S(3)/BiOCl@ZnIn(2)S(4); Epitaxial heterostructure; Intimate junction; Photocatalysis.

Delicate construction based on 2D epitaxial heterostructure can be an effective route to adequately excavate and utilize its superiorities. Here, a core-shell Bi2S3/BiOCl@ZnIn2S4 hierarchical heterostructure is rationally designed and built by Bi2S3 epitaxial growth on two-dimensional template-like BiOCl and ZnIn2S4 nanosheets in-situ growth. The epitaxial growth of Bi2S3 on BiOCl endows the tight contact between them. More importantly, Bi2S3 as the interlayer could offer an extra intimate junction to ZnIn2S4 due to the chem. interaction of S2- between Bi2S3 and ZnIn2S4. Such a Bi2S3/BiOCl@ZnIn2S4 composite was explored for visible-light-driven reduction of Cr(VI), and much satisfactory performance was achieved, which is about 3.3 and 24.1-fold increase compared to that of ZnIn2S4 and Bi2S3/BiOCl resp. Efficient generation, separation and transfer of photo-generated charge carriers inherited from this ternary hierarchical composite made significant contributions to the highly elevated photocatalytic activity. This work may stimulate the construction of multiple hierarchical composites based on 2D epitaxial heterostructure material for efficient photocatalysis or other optoelectronics.

Journal of Hazardous Materials published new progress about Photocatalysts. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, Product Details of Cl3H8InO4.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Liu, Xiaojing; Sun, Xiaoli; Duan, Xinping; Zhang, Chong; Zhao, Kunrong; Xu, Xijin published the artcile< Core-shell Ag@In2O3 hollow hetero-nanostructures for selective ethanol detection in air>, Synthetic Route of 22519-64-8, the main research area is silver indium oxide hetero nanostructure air ethanol detection.

By applying the Ag@carbon nanospheres as self-sacrificial templates, Ag@In2O3 core-shell nanospheres (Ag@In2O3 CSNs) have been successfully prepared via the aging and subsequent annealing process. The formation and sensing performances of this Ag@In2O3 CSNs based sensor are systematically evaluated and analyzed in detail. Compared to pristine In2O3 nanospheres with solid and hollow inner structures, the as-prepared Ag@In2O3 CSNs exhibit the best response (∼72.56 to 50 ppm), especially in terms of the outstanding reusability as well as the excellent anti-interference to other biomarkers in human breath. Such virtues are owing to the unique structure (porous shell and internal voids) and the catalytic effect of encapsulated Ag nanoparticles, which provides considerable active centers and diffusion channels for ethanol. The investigation in this research may shed light on the fabrication of a novel In2O3-based nanocomposite for ethanol gas sensor detection.

Sensors and Actuators, B: Chemical published new progress about Annealing. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, Synthetic Route of 22519-64-8.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Zhang, Haikun; Xie, Shunji; Hu, Jinyuan; Wu, Xuejiao; Zhang, Qinghong; Cheng, Jun; Wang, Ye published the artcile< C-H activations of methanol and ethanol and C-C couplings into diols by zinc-indium-sulfide under visible light>, HPLC of Formula: 22519-64-8, the main research area is cobalt phosphide indium zinc sulfide catalyst dehydrogenative coupling ethanol; methanol ethylene glycol cobalt phosphide indium zinc sulfide catalyst.

An environmentally friendly CoP/Zn2In2S5 catalyst is reported as a visible-light photocatalyst for the selective activation of the α-C-H bond of methanol to generate ethylene glycol with a selectivity of as high as 90%. The catalytic system also illustrates the first example of visible-light-driven dehydrogenative coupling of ethanol to 2,3-butanediol.

Chemical Communications (Cambridge, United Kingdom) published new progress about Band gap. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, HPLC of Formula: 22519-64-8.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics