Category: 22519-64-8

Han, Guang; Gu, Qinfen; Yang, Lei; Chen, Zhi-Gang; Zou, Jin published the artcile< A new indium selenide phase: controllable synthesis, phase transformation and photoluminescence properties>, Application of Cl3H8InO4, the main research area is indium selenide synthesis phase transformation photoluminescence.

A new indium selenide phase, close to the composition of In2.45Se4, is controllably synthesized by an EDTA-mediated solvothermal method. Through detailed structural and chem. characterization using transmission electron microscopy and synchrotron powder X-ray diffraction, it is determined that In2.45Se4 crystallizes in a rhombohedral structure with lattice parameters of a = 6.9632(1) Å and c = 38.1612(1) Å. Systematic investigations show that the synthesis parameters, including the reaction temperature, EDTA/InCl3 molar ratio, solvent composition, and reaction duration, play crucial roles in the formation of this new indium selenide phase. Naturally, such a new-phase In2.45Se4 easily forms flowerlike nano/micro-structures, while In2.45Se4 hexagonal nanoplates can also be selectively synthesized by tuning the precursor concentration In situ high-temperature synchrotron powder X-ray diffraction anal. demonstrates that In2.45Se4, with a hexagonal nanoplate morphol., is stable ≤400°, while a phase transformation from In2.45Se4 to γ-In2Se3 takes place when the annealing temperature reaches 500°. The photoluminescence property measurements show that the In2.45Se4 hexagonal nanoplates have a near IR emission at ∼815 nm, indicating their potential applications in optoelectronics.

Journal of Materials Chemistry C: Materials for Optical and Electronic Devices published new progress about Annealing. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, Application of Cl3H8InO4.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Zhou, Min; Xie, Xialin; Liu, Qianyan; Zhang, Meilin; Peng, Cheng; Li, Fangqin; Liu, Qizhen; Song, Yubao; Wu, Jiang; Qiao, Zhanwei published the artcile< Spherical In2S3 anchored on g-C3N4 nanosheets for efficient elemental mercury removal in the wide temperature range>, Recommanded Product: Indium(III) chloride tetrahydrate, the main research area is spherical indium sulfide anchored carbon nitride nanosheet; efficient elemental mercury removal.

Mercury emission from coal-fired power plants has posed a great threat to the environment and human, and reducing and controlling mercury emissions has become a global environmental issue. In this work, the In2S3/g-C3N4 adsorbent was prepared by simple hydrothermal method to achieve efficient removal of Hg0 from coal-fired flue gas. When the loading value of In2S3 was 40%, the effect of removing Hg0 by as-synthesized IC-40 was the best. IC-40 showed excellent Hg0 adsorption performance in a temperature range of 80-240°. Under the condition of 120° and N2 atmosphere, the Hg0 adsorption capacity of the synthesized IC-40 reached 14.78 mg/g. The study on the impacts of flue gas components demonstrate that IC-40 has good resistance to nitric oxide, and has a slight inhibitory effect by SO2 and water vapor. According to the results of XPS and Hg-TPD, the formed main mercury compound is extremely stable HgS. In addition, DFT was conducted to calculate the adsorption energy of Hg0 on In2S3 (1 1 0) surface, which further illustrated the sulfur site served as stable adsorption site to convert Hg0 into HgS. From the above anal., IC-40 as an efficient and scientific adsorbent to remove Hg0 from coal-fired power plants is a promising tech. method.

Chemical Engineering Journal (Amsterdam, Netherlands) published new progress about Adsorbents. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, Recommanded Product: Indium(III) chloride tetrahydrate.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Zhu, Taotao; Ye, Xiangju; Zhang, Qiaoqiao; Hui, Zhenzhen; Wang, Xuchun; Chen, Shifu published the artcile< Efficient utilization of photogenerated electrons and holes for photocatalytic redox reactions using visible light-driven Au/ZnIn2S4 hybrid>, HPLC of Formula: 22519-64-8, the main research area is gold zinc indium sulfide photocatalyst aromatic oxidation wastewater; Aromatic alcohol; Aromatic aldehyde; Au/ZnIn(2)S(4); Hydrogen evolution; Photocatalysis.

In this study, a new photocatalytic reaction system for simultaneous selective oxidation of aromatic alcs. to corresponding aldehydes and reduction of protons to H2 has been developed. The results reveal that compared with pure ZnIn2S4, the ZnIn2S4 photocatalysts modified with noble metal gold (Au/ZnIn2S4) significantly promote the photocatalytic performance. Among them, the 0.5% Au/ZnIn2S4 nanosheets shows the highest photocatalytic activity for selective oxidation of benzyl alc. to benzaldehyde and hydrogen production, and the yields of H2 and benzaldehyde are 326.68 and 352.04 μmol under visible light irradiation for 4 h, resp. Those are about 4.4 and 3.6 times higher than those of pure ZnIn2S4 sample (74.0 μmol H2 and 98.04 μmol benzaldehyde), resp. The utilization ratio of photogenerated electrons to holes can achieve 92.8%. Addnl., the control experiments demonstrate that the photogenerated electrons and holes play significant roles during the reaction process. It is hoped that the current work can offer an avenue to utilize the photogenerated carriers more efficiently and to develop other photocatalytic reaction systems, such as nitrogen fixation and reduction of carbon dioxide.

Journal of Hazardous Materials published new progress about Adsorption. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, HPLC of Formula: 22519-64-8.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Mohamed, R. M.; Mkhalid, I. A.; Shawky, Ahmed published the artcile< Facile synthesis of Pt-In2O3/BiVO4 nanospheres with improved visible-light photocatalytic activity>, COA of Formula: Cl3H8InO4, the main research area is facile synthesis platinum In2O3 BiVO4 nanospheres photocatalyst.

We present a simple synthesis of BiVO4 nanospheres co-doped with Pt and In2O3 by a hydrothermal approach. The obtained samples exhibited monoclinic phase with homogeneously dispersed Pt and In2O3 on BiVO4 dopants as indicated by XRD, TEM, and XPS, resp. The Pt-In2O3/BiVO4 photocatalyst exhibited highest surface area, lowest band gap, and much less charge recombination compared to pure, Pt or In2O3-doped BiVO4. The 1.2 gL-1 dose of Pt-In2O3/BiVO4 displayed a complete photodegradation of malachite green as an industrial model dye within 40 min with great reusability. A proposed mechanism is suggested based on the presented results.

Journal of Alloys and Compounds published new progress about Hydrothermal reaction. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, COA of Formula: Cl3H8InO4.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Wu, Kai; Jiang, Renqian; Zhao, Yulong; Mao, Liang; Gu, Xiuquan; Cai, Xiaoyan; Zhu, Mingshan published the artcile< Hierarchical NiCo2S4/ZnIn2S4 heterostructured prisms: High-efficient photocatalysts for hydrogen production under visible-light>, Product Details of Cl3H8InO4, the main research area is nickel cobalt zinc indium sulfide heterostructured prisms; zinc indium sulfide hydrogen production photocatalysts visible light; Charge separation; Co-catalyst; Hollow structure; Hydrogen; Photocatalyst.

Exploring low-cost co-catalyst to ameliorate the photocatalytic activity of semiconductors sets a clear direction for solving energy crisis and achieving efficient solar-chem. energy conversion. In this work, a unique hierarchical hollow heterojunction was constructed by in-situ growing ZnIn2S4 nanosheets on the porous NiCo2S4 hollow prisms through a low temperature solvothermal method, in which NiCo2S4 with semi-metal property acted as non-noble metal co-catalyst. NiCo2S4 co-catalyst was innovatively encapsulated in ZnIn2S4, which not only relieved the light shielding effect caused by the large loading amount of co-catalyst, but also supplied abundant active sites for H2 evolution. The hierarchical hollow heterostructure of NiCo2S4 /ZnIn2S4 provided a highly efficient channel for charge transfer. Combining these advantages, NiCo2S4 /ZnIn2S4 composite demonstrated excellent photocatalytic activity. In the absence of sacrificial agent, the NiCo2S4/ZnIn2S4 photocatalyst achieved a remarkable improved H2 yield of 0.77 mmol g-1h-1 under visible light irradiation (λ > 400 nm), which is 6.6 times greater than that of ZnIn2S4. Besides, NiCo2S4 even exhibited better performance on the H2 evolution improvement of ZnIn2S4 than precious metal Pt. This work will offer novel insights into the reasonable design of non-noble metal photocatalysts with respectable activity for water splitting.

Journal of Colloid and Interface Science published new progress about Centrifugation. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, Product Details of Cl3H8InO4.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Gao, Wa; Wang, Lu; Gao, Chao; Liu, Jinqiu; Yang, Yong; Yang, Liuqing; Shen, Qing; Wu, Congping; Zhou, Yong; Zou, Zhigang published the artcile< Exquisite design of porous carbon microtubule-scaffolding hierarchical In2O3-ZnIn2S4 heterostructures toward efficient photocatalytic conversion of CO2 into CO>, Product Details of Cl3H8InO4, the main research area is carbon dioxide indium oxide zinc sulfur semiconductor heterostructure.

Porous carbon microtubule (PCMT)-scaffolding semiconductor heterostructures were exquisitely designed through the in situ growth of ZnIn2S4 (ZIS) ultrathin nanosheets onto In2O3 nanoparticle layers generated on the surface PCMT (abbreviated as PCMT@In2O3/ZIS) toward the efficient photocatalytic conversion of CO2 into CO. The pronounced photocatalytic performance for CO2 photoreduction into CO is attributed to a synergistic effect of the following factors: (1) the multistage hopping of the charge carriers among In2O3, ZIS, and PCMT greatly reduces the charge recombination in In2O3 and ZIS. An (2) The mesoporous feature of the PCMT renders the large surface area and abundant active sites to accumulate the local concentration of CO2 in the heterostructures. An (3) The existence of a large amount of carbon defects in PCMT promotes the activity of the absorbed CO2 mols. An (4) The tubular structures with two open ends of PCMT may favor the fast diffusion of the reactants and products, and the optical absorption can also be increased by multi-light scattering/reflection in the interior void. An (5) The unique fabrication route leads to an intimate and tight contact among PCMT, In2O3, and ZIS, which is also favorable for the charge migration. This work makes a contribution to the development of a complex hollow photocatalysis system for artificial photosynthesis.

Nanoscale published new progress about Band gap. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, Product Details of Cl3H8InO4.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Huang, X.; Chen, X. L.; Zheng, Z. W.; Ji, H. M.; Ma, Y. L. published the artcile< Dense chalcopyrite CuInSe2 thin films prepared with ethanol-based In2Se3-Cu+ ink>, Computed Properties of 22519-64-8, the main research area is chalcopyrite copper indium diselenide thin film ethanol ink.

Here, we show a novel ink containing ethanol, In2Se3 nanosheets and Cu+ that can be used as the sol for filming by dip coating method. And pure chalcopyrite (CH) CuInSe2 (CIS) thin films were obtained when In2Se3 nanosheets with poor crystallinity as a component of the ink. We described the formation of the CH CIS films that exhibit (112)-orientation and dense structure without interspace. Hall measurement shows that the CIS film sintered at 550°C has an elec. resistivity of 3.19 Ω·cm and carrier concentration of 2.63×1017 cm-3, which meet the requirements of high performance solar cell absorption layer.

Chalcogenide Letters published new progress about Absorption. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, Computed Properties of 22519-64-8.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Li, Yi; Yu, Shan; Doronkin, Dmitry E.; Wei, Shiqian; Dan, Meng; Wu, Fan; Ye, Liqun; Grunwaldt, Jan-Dierk; Zhou, Ying published the artcile< Highly dispersed PdS preferably anchored on In2S3 of MnS/In2S3 composite for effective and stable hydrogen production from H2S>, Product Details of Cl3H8InO4, the main research area is manganese indium palladium sulfide photocatalytic hydrogen evolution.

As an important byproduct during natural gas exploitation, green utilization of hydrogen sulfide (H2S) by photocatalysis has offered us the possibility for production of clean hydrogen (H2) from H2S with low energy consumption. In this work, we have successfully introduced well-dispersed palladium sulfide (PdS) which is preferably loaded on In2S3 of MnS/In2S3 composite for improved photocatalytic hydrogen evolution from H2S aqueous solution In contrast to binary MnS/In2S3, ternary MnS/In2S3/PdS has exhibited a remarkable and stable hydrogen production rate of 22.7 mmol g-1 h-1 with an apparent quantum yield of 34% at around 395 nm. A comprehensive structure characterization of the ternary composite including scanning transmission electron microscopy (STEM) and X-ray absorption spectroscopy (XAS) in combination with theor. calculations confirm the good dispersion of PdS in the composite. Moreover, we discovered that PdS preferably interact with In2S3 rather than MnS in the composite through Pd-S-In bond on the interface of the two. Photoluminescence (PL) spectra, surface photovoltage (SPV) spectra together with transient photocurrent and electrochem. impedance spectra (EIS) demonstrate the advantage of PdS for promoting the charge separation This work sheds light on the pos. effect on the enhanced activity of the corresponding system resulting from the preferable anchoring of highly dispersed PdS on In2S3 in the composite by chem. Pd-S-In bond. Not only the high dispersion but also the preferable anchoring of the co-catalyst in the composite could hence inspire people for more rational designs of ternary composite in future.

Journal of Catalysis published new progress about Band structure. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, Product Details of Cl3H8InO4.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Chen, Wei; Chang, Ling; Ren, Shi-Bin; He, Zhi-Cai; Huang, Guo-Bo; Liu, Xiao-Heng published the artcile< Direct Z-scheme 1D/2D WO2.72/ZnIn2S4 hybrid photocatalysts with highly-efficient visible-light-driven photodegradation towards tetracycline hydrochloride removal>, Computed Properties of 22519-64-8, the main research area is preparation property direct Z scheme hybrid photocatalyst; tungsten oxide nanorod zinc indium sulfide nanosheet photocatalyst; visible light driven photocatalytic wastewater treatment tetracycline hydrochloride; Tetracycline hydrochloride; WO(2.72); Z-scheme; ZnIn(2)S(4).

There are increasing environmental concerns of serious pollution from discharge of antibiotic wastewater. A series of direct Z-scheme WO2.72/ZnIn2S4 (WOZIS) hybrid photocatalysts comprised of one-dimensional (1D) WO2.72 (WO) nanorods and two-dimensional (2D) ZnIn2S4 (ZIS) nanosheets were designed and prepared to degrade tetracycline hydrochloride (TCH) without solid-state electron mediators. The crystalline phase, chem. composition, morphol., optical properties, and photocatalytic activity of as-prepared samples were characterized by x-ray diffraction, XPS, SEM, high resolution transmission electron microscopy, BET, UV-vis diffuse reflectance spectroscopy, and PL. All WOZIS hybrid photocatalysts exhibited significantly enhanced photocatalytic activity for TCH degradation WOZIS-1 sample with a 1:1 WO:ZIS molar ratio displayed the highest photocatalytic activity. The significantly enhanced photo-activity of WOZIS hybrid photocatalyst was due to a Z-scheme charge separation mechanism based on tight interfacial contacts between WO nanorods and ZIS nanosheets, thereby driving efficient charge separation The high photocatalytic stability of as-prepared WOZIS-1 hybrid sample was shown with seven successive cycling reactions.

Journal of Hazardous Materials published new progress about Adsorptive wastewater treatment. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, Computed Properties of 22519-64-8.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Wu, Boyuan; Liu, Ning; Lu, Lele; Zhang, Ruizhe; Zhang, Runhao; Shi, Wei; Cheng, Peng published the artcile< A MOF-derived hierarchical CoP@ZnIn2S4 photocatalyst for visible light-driven hydrogen evolution>, HPLC of Formula: 22519-64-8, the main research area is cobalt phosphide indium zinc sulfide photocatalyst metal organic framework.

A hierarchical CoP@ZnIn2S4 photocatalyst was prepared via a MOF-templated strategy. Owing to the unique composition and morphol. that can facilitate the separation of photoexcited carriers, enhance light absorption and provide high surface area, CoP@ZnIn2S4 exhibited a H2 evolution rate of 0.103 mmol h-1 and remained stable over 24 h.

Chemical Communications (Cambridge, United Kingdom) published new progress about Hydrogen evolution reaction. 22519-64-8 belongs to class chlorides-buliding-blocks, and the molecular formula is Cl3H8InO4, HPLC of Formula: 22519-64-8.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics