Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 320-51-4, Name is 4-Chloro-3-(trifluoromethyl)aniline, SMILES is C1=C(C=CC(=C1C(F)(F)F)Cl)N, in an article , author is Banerjee, Amritanshu, once mentioned of 320-51-4, Category: chlorides-buliding-blocks.
Synthesis of chitosan grafted polymethyl methacrylate nanopolymers and its effect on polyvinyl chloride membrane for acetone recovery by pervaporation
In comparison to conventional nanoparticles biopolymer like chitosan based nanoparticles will be of much lower cost, non-toxic and more compatible with polymer membranes. As a cationic polymer surfactant chitosan is able to generate polymer nanoparticles during emulsion polymerization of methyl methacrylate. Accordingly, the organophilicity of polyvinyl chloride (PVC) membrane was significantly improved by incorporating chitosan grafted polymethyl methacrylate (PMMA) nanopolymers(NPs) prepared by emulsion polymerization. The NPs and the PVC-NP blend membranes were characterized. The chitosan: MMA wt. ratio and the wt.% of NP in PVC were optimized by a 5-level factorial design. The membranes prepared from i) PVC, PVC blended with 6.5 wt.% each of ii) chitosan, iii) PMMA and iv) NP showed a pervaporative flux (kg/m(2)/h)/acetone selectivity of 0.439/24.31, 0.477/21.56, 0.461/23.41 and 0.502/27.96, respectively for 5.6 wt.% acetone in feed. The sorption and pervaporation data showed close fitting to ENSIC and six-parameter solution-diffusion model, respectively.
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