Category: 332154-58-2

Masuda, Takeshi published the artcileSugar-induced stereoselectivity in the Fe³⁺-complexation of boronic acid-appended trihydroxamate-type artificial siderophores, Synthetic Route of 332154-58-2, the publication is Supramolecular Chemistry (2000), 11(4), 301-314, database is CAplus.

Two linear- and two tripodal-trihydroxamate siderophore mimics, suspending phenylboronic acid as the sugar-binding site, have been newly prepared These siderophore mimics strongly bind Fe³⁺ ions to give rise to the ligand-Fe³⁺ 1:1 complexes over a wide range of pH 2 to 11. CD spectra of these complexes in the presence of a sugar, D-fructose, exhibit moderately strong bisignate Cotton effects of first neg. and second pos. signs in aqueous alk. media. The sign and extent of the observed CD signals depend largely on the solution pH and the concentration and absolute configuration of the bound sugars, implying that the phenylboronate-sugar covalent interactions are capable of inducing a chirality around the metal center.

Supramolecular Chemistry published new progress about 332154-58-2. 332154-58-2 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Boronic acid and ester,Benzene,acyl chloride,Boronic Acids,Boronic Acids,Boronic acid and ester,, name is (3-(Chlorocarbonyl)phenyl)boronic acid, and the molecular formula is C7H6BClO3, Synthetic Route of 332154-58-2.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Wang, Yun published the artcileSynthesis of a phenylboronic acid-functionalized thermosensitive block copolymer and its application in separation and purification of vicinal-diol-containing compounds, Quality Control of 332154-58-2, the publication is RSC Advances (2016), 6(85), 82309-82320, database is CAplus.

A phenylboronic acid-functionalized amphiphilic thermosensitive block copolymer was prepared by taking PEO₂₀PPO₆₀PEO₂₀ as the template and a detailed study of its performance in downstream separation processes was presented. Alizarin red was used as the model compound to study the feasibility of using an affinity adsorption system and aqueous two-phase flotation system based on the phenylboronic acid-functionalized PEO₂₀PPO₆₀PEO₂₀ for the separation and purification of ortho-hydroxyl compounds The optimized conditions of the affinity adsorption experiment were: 2% phenylboronic acid-functionalized PEO₂₀PPO₆₀PEO₂₀, 0.3 mg alizarin red, 40% K₂HPO₄ and 4 h adsorption time. The affinity adsorption rate of alizarin red reached 98% under such conditions. In addition, a flotation recovery of alizarin red of 97% was obtained under the optimal conditions of aqueous two-phase flotation: 0.3 g of collector, 12 g K₂HPO₄, 0.6 mg alizarin red, 15 mL min^-1 nitrogen flow rate and 40 min flotation time. Both methods are capable of separating alizarin red, suggesting their broad application prospect in downstream separation engineering of vicinal-diol-containing compounds

RSC Advances published new progress about 332154-58-2. 332154-58-2 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Boronic acid and ester,Benzene,acyl chloride,Boronic Acids,Boronic Acids,Boronic acid and ester,, name is (3-(Chlorocarbonyl)phenyl)boronic acid, and the molecular formula is C8H11NO, Quality Control of 332154-58-2.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics