Category: 4569-86-2

On January 5, 2011, Xu, Shumin; Liu, Jianguang; Yang, Xiangkui; Ma, Xuewu; Song, Zhaoxia published a patent.Computed Properties of 4569-86-2 The title of the patent was Method for surface treatment of pink copper foil used for high-grade FR-4 copper-clad laminate. And the patent contained the following:

The title method comprises the steps of: using 12-70μm high-temperature high-ductility copper foil as cathode, running at 25.0±0.1m/min to roughen the copper foil surface and solidify fractal electrodeposited tubercular copper, forming a layer of nanoscale Cu alloy via electrodeposition, then depositing a layer of nanoscale Zn via electrodeposition, deactivating with basic chromate, and coating with a layer of silane coupling agent. An organic additive containing nitrogen heterocyclic ring is used in the electrodeposition of the Cu-N alloy whisker, to improve the appearance and corrosion resistance after treatment. The treated pink copper foil has the advantages of high oxidation resistance at normal temperature and high temperature, high plating layer diffusion resistance, high corrosion resistance, high etching resistance, high stripping resistance, and high high-temperature conversion resistance. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Computed Properties of 4569-86-2

The Article related to laminate pink copper foil surface treatment electrodeposition, Nonferrous Metals and Alloys: Surface Treatment, Metallic and Nonmetallic Coating, Sealing, Cleaning, Polishing, Etching, and Pickling and other aspects.Computed Properties of 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On November 1, 2020, Liu, Ya; Zhao, Yunfeng; Cheng, Wei; Zhang, Tao published an article.Product Details of 4569-86-2 The title of the article was Targeted reclaiming cationic dyes from dyeing wastewater with a dithiocarbamate-functionalized material through selective adsorption and efficient desorption. And the article contained the following:

In this work, we applied a novel dithiocarbamate-grafted star-like polymer for efficient reclamation of cationic dyes. This material is highly selective towards cationic dyes and almost completely rejective to anionic dyes. The adsorption kinetics, isotherms, and thermodn. were systematically investigated to analyze the adsorption behavior of cationic dyes onto the material. As compared with other reported adsorbents, this cheap and facilely-prepared material has exceptional adsorption capacities for industrial cationic dyes, e.g., methylene blue (MB, 2624 mg/g), crystal violet (CV, 2553 mg/g), basic fuchsin (BF, 1729 mg/g), and methylene violet 3RAX (MV, 1239 mg/g), being 5-11 times of that reported in literatures. Based on the effects of pH and ionic strength on adsorption, competitive adsorption of the cationic dyes, and FTIR characterization, mechanisms for the adsorption and desorption of cationic dyes were proposed. The adsorbed dyes can be recovered over 95% just by immersing into diluted HCl solution (0.01 M) for 10 min, thus avoiding organic solvent extraction Over 98% of the adsorption capacity was maintained during consecutive reclamation operation. Due to the high selectivity, high adsorption capacity and the ease of efficient regeneration, this material is potentially applicable for targeted reclamation of cationic dyes from dyeing wastewater. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Product Details of 4569-86-2

The Article related to dithiocarbamate polyacrylamide reclamation cationic dye adsorption desorption wastewater, cationic dyes, dithiocarbamate, dyeing wastewater, reclamation, selective adsorption and other aspects.Product Details of 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On June 26, 2008, Brunner, Heiko; Dahms, Wolfgang; Grieser, Udo published a patent.Safety of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride The title of the patent was Preparation of halogenated or pseudohalogenated monomeric phenazinium compounds useful in acidic baths for electrolytically depositing copper.. And the patent contained the following:

Title compounds [I; R1, R2, R4, R7, R71, R8, R9 = H, halo, amino, aminoalkyl, OH, cyano, SCN, OCN, SH, CO2H, alkyl, (substituted) aryl, heteroaryl, etc.; R5 = alkyl, (substituted) aryl, heteroaryl; X = halo, pseudohalo; A- = acid anion], were prepared Thus, 3,7-diamino-2,8-dimethyl-5-phenylphenazinium chloride in 50% HBF4 at 50-60° was treated with aqueous NaSCN/NaNO2 over 1 h followed by stirring for an addnl. 1 h to give 64.0% 7-amino-2,8-dimethyl-3-thiocyanato-5-phenylphenazinium tetrafluoroborate. The latter in a Cu plating bath gave a brilliant, mirrorlike deposit without burns with invisible brush lines, indicative of an excellent leveling effect. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Safety of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride

The Article related to halogenated pseudohalogenated monomeric phenazinium preparation copper electroplating additive, aminothiocyanatophenazinium tetrafluoroborate preparation copper plating bath additive and other aspects.Safety of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On December 31, 2020, Li, Haolan; Yue, Liangliang; Wu, Ming; Wu, Fengshou published an article.Application of 4569-86-2 The title of the article was Self-assembly of methylene violet-conjugated perylene diimide with photodynamic/photothermal properties for DNA photocleavage and cancer treatment. And the article contained the following:

Near-IR (NIR) light-activated phototherapy, such as photothermal therapy (PTT) and photodynamic therapy (PDT), has gained considerable attention due to the advantages of high efficiency and minimally invasiveness. However, the development of a single component therapeutic agent with clear structure and mol. weight that achieve photodynamic/photothermal synergistic therapy is still challenging. Herein, we design and synthesize a new smart photosensitizer (PRX) by conjugation of perylene diimide (PDI) and methylene violet (RAX). The typical donor-acceptor (D-A) structure of RAX facilitates the red-shift of absorption to the near-IR (NIR) region. The amphiphilic PRX could self-assemble into monodispersed nanoparticles (PRX NPs) with enhanced and broadened absorption. Under a single 808 nm laser irradiation, PRX NPs could generate efficient reactive oxygen species (ROS) and heat simultaneously with the photothermal conversion efficiency as high as 59%. PRX NPs displays strong interaction with DNA and can damage plasmid DNA upon light irradiation The biocompatibility and high phototoxicity of PRX NPs against A549 cells are further confirmed through MTT assay. Therefore, the as-prepared PRX NPs could be served as a promising antitumor nanoagent through photothermal/photodynamic combination manner. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Application of 4569-86-2

The Article related to methylene violet perylene diimide antitumor nanoagent photodynamic photothermal therapy, methylene violet, organic nanoparticles, perylene diimide, photodynamic therapy, photothermal therapy and other aspects.Application of 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On December 1, 2019, Onder, Seda; Biberoglu, Kevser; Tacal, Ozden published an article.Computed Properties of 4569-86-2 The title of the article was The kinetics of inhibition of human acetylcholinesterase and butyrylcholinesterase by methylene violet 3RAX. And the article contained the following:

Phenazines, naturally produced by bacteria and archaeal Methanosarcina species are nitrogen-containing tricyclic mols. with antibiotic, antitumoral, and antiparasitic activities. Phenazines are used as electron acceptors-donors in wide range of fields including environmental biosensors. In this study, the inhibitory effects of a synthetic phenazine dye, methylene violet 3RAX (also known as di-Et safranine) on human erythrocyte AChE and human plasma BChE were tested and also its inhibitory mechanisms for both enzymes were studied in detail. Kinetic anal. showed that methylene violet 3RAX acts as a hyperbolic noncompetitive inhibitor of AChE with Ki value of 1.58 ± 0.36μM; α = 1; β = 0.12 ± 0.0003. On the other hand, it caused linear competitive inhibition of BChE with Ki value of 0.51 ± 0.006μM; α = ∞. In conclusion, methylene violet 3RAX which is a highly effective inhibitor of both human AChE and human BChE with Ki values in low micromolar range may be a promising candidate for the treatment of Alzheimer’s disease. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Computed Properties of 4569-86-2

The Article related to human erythrocyte plasma acetylcholinesterase butyrylcholinesterase methylene violet inhibition kinetics, acetylcholinesterase, butyrylcholinesterase, cholinesterase inhibition, methylene violet 3rax and other aspects.Computed Properties of 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On March 1, 2021, Wang, Xiu Li; Zhang, Jing Yuan; Chang, Zhi Han; Zhang, Zhong; Wang, Xiang; Lin, Hong Yan; Cui, Zi Wei published an article.HPLC of Formula: 4569-86-2 The title of the article was α-γ-Type [Mo8O26]4–Containing Metal-Organic Complex Possessing Efficient Catalytic Activity toward the Oxidation of Thioether Derivatives. And the article contained the following:

In this work, a new α-γ-type [Mo8O26]4- anion was first synthesized and characterized by single-crystal X-ray diffraction anal. and was obtained by introducing molybdate to the synthesis of metal-organic complex (MOC) under hydrothermal conditions. An octamolybdate-based MOC, namely, {[Cu8(H2O)6](dpyh)4(α-γ-Mo8O26) }·(β-Mo8O26)·8.5H2O (1) (H2dpyh = N,N-bis(3-pyrazolamide)-1,2-hexahydrobenzene), was obtained. The α-γ-type [Mo8O26]4- anion was composed of four MoO6 octahedra and four MoO5 trigonal bipyramids by sharing their edges and corners. The title complex exhibited a 1D structure in which an α-γ-type [Mo8O26]4- anion was connected with [Cu4(dpyh)2] units in a staggered manner. Under optimized conditions, complex 1 as the catalyst can achieve a highly efficient conversion (more than 99%) of thioanisole within 30 min and above 99% selectivity toward sulfoxide. Furthermore, efficient catalytic oxidation of thioether derivatives was also performed with 1 as the catalyst. In addition, the stable electrochem. sensing performance and adsorption capacity toward organic dyes were tested. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).HPLC of Formula: 4569-86-2

The Article related to crystal structure redox potential organic dye adsorption polyoxometalate preparation, thioether sulfoxide sulfoxidation catalyst polyoxomolybdate copper pyrazolamide complex, electrochem redox catalysis amperometric sensor octamolybdate metal organic complex and other aspects.HPLC of Formula: 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On March 1, 2021, Wang, Xiu Li; Zhang, Jing Yuan; Chang, Zhi Han; Zhang, Zhong; Wang, Xiang; Lin, Hong Yan; Cui, Zi Wei published an article.HPLC of Formula: 4569-86-2 The title of the article was α-γ-Type [Mo8O26]4–Containing Metal-Organic Complex Possessing Efficient Catalytic Activity toward the Oxidation of Thioether Derivatives. And the article contained the following:

In this work, a new α-γ-type [Mo8O26]4- anion was first synthesized and characterized by single-crystal X-ray diffraction anal. and was obtained by introducing molybdate to the synthesis of metal-organic complex (MOC) under hydrothermal conditions. An octamolybdate-based MOC, namely, {[Cu8(H2O)6](dpyh)4(α-γ-Mo8O26) }·(β-Mo8O26)·8.5H2O (1) (H2dpyh = N,N-bis(3-pyrazolamide)-1,2-hexahydrobenzene), was obtained. The α-γ-type [Mo8O26]4- anion was composed of four MoO6 octahedra and four MoO5 trigonal bipyramids by sharing their edges and corners. The title complex exhibited a 1D structure in which an α-γ-type [Mo8O26]4- anion was connected with [Cu4(dpyh)2] units in a staggered manner. Under optimized conditions, complex 1 as the catalyst can achieve a highly efficient conversion (more than 99%) of thioanisole within 30 min and above 99% selectivity toward sulfoxide. Furthermore, efficient catalytic oxidation of thioether derivatives was also performed with 1 as the catalyst. In addition, the stable electrochem. sensing performance and adsorption capacity toward organic dyes were tested. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).HPLC of Formula: 4569-86-2

The Article related to crystal structure redox potential organic dye adsorption polyoxometalate preparation, thioether sulfoxide sulfoxidation catalyst polyoxomolybdate copper pyrazolamide complex, electrochem redox catalysis amperometric sensor octamolybdate metal organic complex and other aspects.HPLC of Formula: 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics