I found the field of Chemistry very interesting. Saw the article Reversing Reactivity: Stereoselective Desulfurative 1,2-trans-O-Glycosylation of Anomeric Thiosugars with Carboxylic Acids under Copper or Cobalt Catalysis published in 2020. Formula: C7H4Cl2O2, Reprint Addresses Messaoudi, S (corresponding author), Univ Paris Saclay, CNRS, BioCIS, F-92290 Chatenay Malabry, France.. The CAS is 50-84-0. Through research, I have a further understanding and discovery of 2,4-Dichlorobenzoic acid
We have discovered a new mode of reactivity of 1-thiosugars in the presence of Cu(II) or Co(II) for a stereoselective O-glycosylation reaction. The process involves the use of a catalytic amount of Cu(acac)(2) or Co(acac)(2) and Ag2CO3 as an oxidant in alpha,alpha,alpha-trifluorotoluene. Moreover, this protocol turned out to have a broad scope, allowing the preparation of a wide range of complex substituted O-glycoside esters in good to excellent yields with an exclusive 1,2-trans-selectivity. The late-stage modification of pharmaceuticals by this method was also demonstrated. To obtain a closer insight into the reaction mechanism, cyclic voltammetry was performed.
Formula: C7H4Cl2O2. Welcome to talk about 50-84-0, If you have any questions, you can contact Bennai, N; Chabrier, A; Fatthalla, MI; Tran, C; Yen-Pon, E; Belkadi, M; Alami, M; Grimaud, L; Messaoudi, S or send Email.
Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics