Category: 5137-55-3

The physical significance of the Kamlet-Taft π* parameter of ionic liquids was written by Weiss, Nadine;Schmidt, Caroline H.;Thielemann, Gabi;Heid, Esther;Schroeder, Christian;Spange, Stefan. And the article was included in Physical Chemistry Chemical Physics in 2021.Reference of 5137-55-3 The following contents are mentioned in the article:

The Kamlet-Taft dipolarity/polarizability parameters π* for various ionic liquids were determined using 4-tert-butyl-2-(dicyanomethylene)-5-[(4-N,N-diethylamino)-benzylidene]-Δ3-thiazoline and 5-(N,N-dimethylamino)-5′-nitro-2,2′-bithiophene as solvatochromic probes. In contrast to the established π*-probe N,N-diethylnitroaniline, the chromophores presented here show excellent agreement with polarity measurement using the chem. shift of ¹²⁹Xe. They do not suffer from addnl. bathochromic UV/vis shifts caused by hydrogen-bonding resulting in too high π*-values for some ionic liquids In combination with large sets of various ionic liquids, these new chromophores thereby allow for detailed anal. of the phys. significance of π* and the comparison to quantum-mech. methods. We find that π* correlates strongly with the ratio of molar refractivity to molar volume, and thus with the refractive index. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Reference of 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Reference of 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Extractive Separation of Co/Ni Pair With the Deep Eutectic Solvent Aliquat 336/Timol was written by Milevsky, N. A.;Zinovieva, I. V.;Zakhodyaeva, Yu. A.;Voshkin, A. A.. And the article was included in Theoretical Foundations of Chemical Engineering in 2022.HPLC of Formula: 5137-55-3 The following contents are mentioned in the article:

This paper presents the results of a study of the phys. properties of a hydrophobic deep eutectic solvent (HDES) based on Aliquat 336 and thymol. A solid-liquid phase diagram was built based on the glass temperatures of the Aliquat 336/thymol mixture in different molar ratios. For the first time, the temperature dependences of the d., viscosity, and refractive index of the suggested HDES have been studied. A study of the extraction of Co(II) and Ni(II) ions was carried out under various conditions with HDES Aliquat 336/thymol as an extractant: the influence of the concentration of hydrochloric acid, the concentration of ammonium/lithium/sodium chloride, and the volumetric ratio of phases was studied. The mechanism of the extraction of Co(II) ions by the proposed HDES has been established. Based on the obtained exptl. data, it was shown that a Co/Ni pair can be separated from hydrochloric acid solutions with the proposed HDES. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3HPLC of Formula: 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.HPLC of Formula: 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Research on extraction of zinc from spent pickling solution using Aliquat 336 was written by Wang, Yongmi;He, Yuan;Yin, Shaohua;Long, Hailin;Li, Shiwei. And the article was included in Hydrometallurgy in 2020.SDS of cas: 5137-55-3 The following contents are mentioned in the article:

A review. Zinc and iron were separated from the spent pickling solution by extraction with Me trioctyl ammonium chloride (Aliquat 336). The purpose of the extraction experiment is to determine a variety of parameters (e.g. addition of octanol, contact time, phase ratio, [H⁺] concentration and Aliquat 336 concentration). Under optimal extraction conditions, the zinc extraction in one stage was above 92.4% and the separation coefficient β_Zn/Fe could reach 273 with initial zinc concentration 17.6 g/L, iron concentration 141.1 g/L and [H⁺] = 1.4 M. The zinc extraction mechanism was analyzed FT-IR spectroscopy and slope method. Zn(II) after extracting was comparative studied using different stripping agents. Recycling tests were also carried out, indicating that the extractant had a stable extraction performance, retaining 91.2% extraction efficiency of fresh extractant after 5 cycles. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3SDS of cas: 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).SDS of cas: 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Efficient tetracycline adsorptive removal using tricaprylmethylammonium chloride conjugated chitosan hydrogel beads: Mechanism, kinetic, isotherms and thermodynamic study was written by Ranjbari, Sara;Tanhaei, Bahareh;Ayati, Ali;Khadempir, Sara;Sillanpaa, Mika. And the article was included in International Journal of Biological Macromolecules in 2020.Electric Literature of C25H54ClN The following contents are mentioned in the article:

In the present study, novel ionic liquid-impregnated chitosan hydrogel beads (CS-TCMA) were fabricated via the reaction of tricaprylmethylammonium chloride (TCMA, Aliquat-336) with the chitosan’s amino groups. They were used for the fast adsorption of Tetracycline (TC), as a pharmaceutical compound model, from aqueous solution It was found that the impregnation of TCMA greatly improved the adsorption behavior of chitosan toward TC. The optimum adsorbent was determined to be 3 mg/ L in a wide pH range of 5-11. It was a fast process, with a 90% removal efficiency in <45 min. The adsorption kinetic of TC on the CS-TCMA was well described by the pseudo-first-order model and intra-particle diffusion model. The adsorption also obeyed the Langmuir adsorption isotherm model and the maximum adsorption capacity obtained was 22.42 mg/g at 45°C. The thermodn. study also revealed the endothermic nature of the process. The adsorption mechanism was also studied. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Electric Literature of C25H54ClN).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Electric Literature of C25H54ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Isoprene Soya Diels-Alder Adduct and Epoxidation for Photopolymerization was written by Ren, Xiaofeng;Xu, Tong;Thomas, Jomin;Soucek, Mark D.. And the article was included in Macromolecular Chemistry and Physics in 2021.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

A novel cyclohexane derivatized soybean oil (CSO) is synthesized by Diels-Alder cycloaddition of soybean oil with isoprene. Then, the epoxidized cycloaliphatic soybean oil (ECSO) is prepared via epoxidation of CSO. For comparison purpose, norbornylized soybean oil (NSO) and epoxy norbornane soybean oil (ENSO) are synthesized. The CSO, ECSO, NSO, and ENSO are characterized by ¹H NMR, ¹³C NMR, gradient heteronuclear single quantum correlation (gHSQC) 2D NMR, and mass spectroscopy. The epoxidized soybean oil (ESO), ECSO, and ENSO are photopolymerized using UV-light, and the kinetics of the photocuring reactions is evaluated by real-time Fourier transform IR (FT-IR) and photo-differential scanning calorimetry (DSC). Real-time FT-IR and photo-DSC indicate the improved reactivity of ECSO and ENSO compared to ESO. It is found that the curing rate and final conversion of novel developed ECSO is higher than ESO, but lower than ENSO. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Category: chlorides-buliding-blocks).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Recovery of iridium by solvent extraction and direct electrodeposition using phosphonium-based ionic liquids was written by Matsumiya, Masahiko;Kinoshita, Ryoma;Tsuchida, Yusuke;Sasaki, Yuji. And the article was included in Journal of the Electrochemical Society in 2021.SDS of cas: 5137-55-3 The following contents are mentioned in the article:

The extraction behavior of Ir(IV) in a phosphonium-based ionic liquid (IL) system, triethyl-n-pentyl phosphonium bis(trifluoromethyl-sulfonyl)amide ([P2225][NTf2]), was studied using an amine extractant. The electrochem. behavior of the extracted Ir(IV) species in [P2225][NTf2] during electrodeposition was studied. Voltammetry-based electrochem. anal. revealed that the reduction of Ir(IV) proceeded via an intermediate Ir(III) species in two steps, namely, Ir(IV) + e- → Ir(III) and Ir(III) + 3e- → Ir(0). Diffusion coefficients of the extracted Ir(IV) species in the IL were determined at 298-373 K using semi-integral and semi-differential analyses, and values obtained from the two analyses were consistent with each other. Also, consecutive solvent extraction and electrodeposition of Ir metal in the IL bath were performed for 10 cycles. The entire Ir electrodeposit was in the metallic state, as is evident from the 4f7/2 spectrum obtained by XPS. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3SDS of cas: 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).SDS of cas: 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Efficient tetracycline adsorptive removal using tricaprylmethylammonium chloride conjugated chitosan hydrogel beads: Mechanism, kinetic, isotherms and thermodynamic study was written by Ranjbari, Sara;Tanhaei, Bahareh;Ayati, Ali;Khadempir, Sara;Sillanpaa, Mika. And the article was included in International Journal of Biological Macromolecules in 2020.Electric Literature of C25H54ClN The following contents are mentioned in the article:

In the present study, novel ionic liquid-impregnated chitosan hydrogel beads (CS-TCMA) were fabricated via the reaction of tricaprylmethylammonium chloride (TCMA, Aliquat-336) with the chitosan’s amino groups. They were used for the fast adsorption of Tetracycline (TC), as a pharmaceutical compound model, from aqueous solution It was found that the impregnation of TCMA greatly improved the adsorption behavior of chitosan toward TC. The optimum adsorbent was determined to be 3 mg/ L in a wide pH range of 5-11. It was a fast process, with a 90% removal efficiency in <45 min. The adsorption kinetic of TC on the CS-TCMA was well described by the pseudo-first-order model and intra-particle diffusion model. The adsorption also obeyed the Langmuir adsorption isotherm model and the maximum adsorption capacity obtained was 22.42 mg/g at 45°C. The thermodn. study also revealed the endothermic nature of the process. The adsorption mechanism was also studied. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Electric Literature of C25H54ClN).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Electric Literature of C25H54ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Investigation of Electrical Conductivity Properties and Electro Transport of a Novel Multi Walled Carbon Nanotube Electro Membrane under Constant Current was written by Onac, Canan. And the article was included in Electroanalysis in 2020.Reference of 5137-55-3 The following contents are mentioned in the article:

This study used multi-walled C nanotube in electro-membrane extraction studies under direct constant current for the 1st time for the electro transport of cypermethrin (CYP) from aqueous to acceptor phase. A novel and developed membrane exhibits visible and remarkable recovery values (82.76%) for the removal of CYP under 0.3 A constant current at 60 V in 30 min. Regenerating electro membrane by multi-walled C nanotubes (MWCNTs) increased the elec. conductivity, thermal Ea values of a novel membrane (750 meV) and stability, and it resulted in better and higher kinetic results on the transport process. This study presents a potential solution for the limited use of electro-membrane extraction at higher current values. Regenerating of the electro membrane by MWCNTs not only allows the authors to work even at high current values, it prevents the formation of electrolysis up to a certain current value in donor and acceptor phases. TGA of the novel membrane also confirms successful regeneration of the electro membrane by MWCNTs. Electro-membrane extraction studies have gained a new perspective and innovation using MWCNTs in electro-membrane process. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Reference of 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Reference of 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Hydrophobic deep eutectic solvent-based ultrasonic-assisted dispersive liquid-liquid microextraction for preconcentration and determination of trace cadmium and arsenic in wine samples was written by Ji, Yinghe;Zhao, Min;Li, Anwen;Zhao, Longshan. And the article was included in Microchemical Journal in 2021.Computed Properties of C25H54ClN The following contents are mentioned in the article:

In present study, DL-lactic acid/trioctylmethylammonium chloride-based deep eutectic solvent (DES), which was considered as an environmental friendly extraction solvent to replace traditional organic reagent, was firstly presented for monitoring of trace cadmium (Cd) and arsenic (As) in wine samples by ultrasonic-assisted dispersive liquid-liquid microextraction (UA-DLLME) method. Moreover, different extraction conditions, including the type and volume of DES and dispersive solvent, pH of the solution, salt amount, time of vortex and sonication, were systematically evaluated. At the optimized extraction conditions, good linear relationships (0.50-8.0μg·L^-1 for Cd, 2.0-50μg·L^-1 for As) were obtained and limits of detection of Cd and As were 0.080 and 0.30μg·L^-1, resp. In addition, the accuracy (as recoveries %), and intra-/inter-day precision (as relative standard deviation %) were in the ranges of 90.6-103.6% and 2.9-4.5%, resp. Finally, the proposed method was applied to analyze 6 kinds of wine samples, which possessed wide practical application value in monitoring heavy metal residues in wine and even complex food matrixes. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Computed Properties of C25H54ClN).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Computed Properties of C25H54ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Selective Catalytic Synthesis of 1,2- and 8,9-Cyclic Limonene Carbonates as Versatile Building Blocks for Novel Hydroxyurethanes was written by Maltby, Katarzyna A.;Hutchby, Marc;Plucinski, Pawel;Davidson, Matthew G.;Hintermair, Ulrich. And the article was included in Chemistry – A European Journal in 2020.HPLC of Formula: 5137-55-3 The following contents are mentioned in the article:

The selective catalytic synthesis of limonene-derived monofunctional cyclic carbonates and their subsequent functionalization via thiol-ene addition and amine ring-opening is reported. A phosphotungstate polyoxometalate catalyst used for limonene epoxidation in the 1,2-position is shown to also be active in cyclic carbonate synthesis, allowing a two-step, one-pot synthesis without intermittent epoxide isolation. When used in conjunction with a classical halide catalyst, the polyoxometalate increased the rate of carbonation in a synergistic double-activation of both substrates. The cis isomer is shown to be responsible for incomplete conversion and byproduct formation in com. mixtures of 1,2-limonene oxide. Carbonation of 8,9-limonene epoxide furnished the 8,9-limonene carbonate for the first time. Both cyclic carbonates underwent thiol-ene addition reactions to yield linked di-monocarbonates, which can be used in linear non-isocyanate polyurethane synthesis, as shown by their facile ring-opening with N-hexylamine. Thus, the selective catalytic route to monofunctional limonene carbonates gives straightforward access to monomers for novel bio-based polymers. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3HPLC of Formula: 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.HPLC of Formula: 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics