Category: 5137-55-3

Ion-association dispersive liquid-liquid microextraction of trace amount of gold in water samples and ore using Aliquat 336 prior to inductivity coupled plasma atomic emission spectrometry determination was written by Zari, Naeemeh;Hassan, Jalal;Tabar-Heydar, Kourosh;Ahmadi, Seyyed Hamid. And the article was included in Journal of Industrial and Engineering Chemistry in 2020.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

An extraction method employing dispersive liquid-liquid microextraction (DLLME) and ICP-OES has been developed for rapid separation, pre-concentration and determination of ultra-trace amount of Au(III). The extraction of the analyte was performed in the presence of a quaternary ammonium cation, N-Methyl-N, N, N-trioctylammonium chloride, (Aliquat 336) as an extractant based on ion-association extraction system. 1-octanol and acetonitrile were used as extraction and disperser solvents, resp. The variables affecting the extraction conditions were optimized. Calibration curve in the range of 0.3-100 ng mL^-1, the detection limit of 0.09 ng mL^-1, enrichment factor of 150 and extraction recovery of 74% were obtained. The precision (R.S.D. %) of the method was 6% for 5 replicates and recoveries of 10 ng mL^-1 Au(III). The combined DLLME method with ICP-OES can readily determine Au(III) at trace (μg L^-1) level using only 10 mL of sample solution (tap, lake, and mining water) and ore sample without interference by the matrixes. This methodol. is simple, fast, and low cost which can be used in routine anal. laboratories This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Category: chlorides-buliding-blocks).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Separation and adsorption of V(V) from canadium-containing solution by TOMAC-impregnated resins was written by Yu, Chen;Bao, Shenxu;Zhang, Yimin;Chen, Bo. And the article was included in Chemical Engineering Research and Design in 2021.Name: N-Methyl-N,N-dioctyloctan-1-aminium chloride The following contents are mentioned in the article:

Trioctyl Me ammonium chloride-impregnated resins (TOMAC-IRs) were synthesized and utilized to efficiently sep. and recover vanadium from acidic vanadium-containing solution, and the main factors affecting the adsorption properties of V(V) were studied. Under the optimal conditions, i.e., initial pH of 1.8, liquid-solid ratio (L/S) of 200:1 mL/g, impregnation ratio of 18.4%, initial vanadium concentration of 1500 mg/L, and adsorption time of 4 h, the adsorption capacity towards V(V) can reach 78.65 mg/g, and impurity ions (Al and Fe) can be hardly adsorbed. The adsorption of V(V) onto TOMAC-IRs conforms to the Langmuir isotherm adsorption model, indicating that V(V) is adsorbed as a monolayer on TOMAC-IRs. The pseudo-second order kinetic model fits better towards the adsorption processes of V(V), which shows that the adsorption process is dominated by chem. adsorption. The desorption and regeneration of the TOMAC-IRs can be accomplished in just one step using 6 mol/L NaOH; in the meanwhile, the adsorption capacity is 98.01% of the original value after six cycles, demonstrating that the TOMAC-IRs have good stability during the cyclic adsorption of V(V). This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Name: N-Methyl-N,N-dioctyloctan-1-aminium chloride).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Name: N-Methyl-N,N-dioctyloctan-1-aminium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Efficient and environment-friendly vanadium (V) extraction from vanadium shale leachate using tri-n-octylmethylammonium chloride was written by Luo, Dashuang;Huang, Jing;Zhang, Yimin;Liu, Hong;Hu, Pengcheng. And the article was included in Separation and Purification Technology in 2020.Reference of 5137-55-3 The following contents are mentioned in the article:

In this work, an efficient and environmentally friendly method for recovering V (V) from vanadium shale leachate using an ionic liquid, tri-n-octylmethylammonium chloride (TOMAC), was proposed. The main factors affecting the extraction and stripping of vanadium using TOMAC were studied. A significant quantity (93.18%) of vanadium was extracted with almost no impurities under the following conditions: the concentration of TOMAC was 20 vol%; the concentration of 2-octanol as the phase modifier was 15 vol%; the phase ratio (O/A) was 1:10. More than 90% of vanadium in the loaded organic phase could be stripped quant. using a mixed solution of 0.8 mol/L NaOH and 1.2 mol/L NaCl. The stripping and regeneration of the loaded organic phase could be carried out in one step. Meanwhile, the anion exchange mechanism of extraction and stripping was analyzed by Fourier transform IR (FT-IR) spectroscopy. Moreover, the organic phase stripped by the NaOH-NaCl synergistic stripping system maintained a relatively high extraction efficiency (>90%) even across many cycles, which indicated that the developed system is environmentally friendly and efficient for the recovery of vanadium. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Reference of 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Reference of 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Two step activation of Ru-PN³P pincer catalysts for CO₂ hydrogenation was written by Tossaint, Alex S.;Rebreyend, Christophe;Sinha, Vivek;Weber, Manuela;Canossa, Stefano;Pidko, Evgeny A.;Filonenko, Georgy A.. And the article was included in Catalysis Science & Technology in 2022.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

Activation of homogeneous catalysts is an important step in ensuring efficient operation of any catalytic system as a whole. For the majority of pincer catalysts, the activation step leans heavily on the metal ligand cooperative chem. that allows these complexes to react with small mol. substrates and engage in catalytic transformations. While the majority of such catalysts require a single activation event to become cooperative, herein we report an exception to this trend. Specifically, we demonstrate that a Ru-PN³P aminopyridine pincer catalyst, which lacks conventional reactivity with hydrogen upon typical one-fold activation, can exhibit this reactivity when a sequential two-step activation is performed. The resulting anionic complexes readily activate mol. hydrogen and react further with CO₂ showing the previously unknown reactivity that is critical for CO₂ hydrogenation catalysts. While active in CO₂ hydrogenation, Ru-PN³Ps are significantly more efficient in hydrogenation of bicarbonates – a likely consequence of the chem. of these pincers requiring formation of anionic complexes for hydrogen activation. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Category: chlorides-buliding-blocks).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

The surfactant-ionic liquid bi-functionalization of chitosan beads for their adsorption performance improvement toward Tartrazine was written by Ranjbari, Sara;Ayati, Ali;Tanhaei, Bahareh;Al-Othman, Amani;Karimi, Fatemeh. And the article was included in Environmental Research in 2022.Electric Literature of C25H54ClN The following contents are mentioned in the article:

In this study, the ionic liquid (Aliquat-336) and anionic surfactant (cetyltrimethylammonium bromide, CTAB) bi-functionalized chitosan beads were prepared and characterised using different techniques, including FTIR, XRD, SEM, EDS and BET surface area anal. The characteristic anal. confirmed the successful conjugation of chitosan beads with both surfactant and ionic liquid The novel fabricated beads (CS-CTAB-AL) were efficiently employed, as a high-performance adsorbent, for the removal of Tartrazine (TZ), an anionic food dye, from polluted water. The optimum adsorption of TZ onto the CS-CTAB-AL was found at 2 g L-1 of adsorbent in the wide pH range of 4-11, whereas just 45 min was required to reach more than 90% adsorption efficiency in the studied conditions. Also, the adsorption and kinetic studies showed that the exptl. data well fitted the pseudo-first-order kinetic model and the Langmuir isotherm model. The maximum adsorption capacity of prepared beads was found to be 45.95 mg g-1 at 45°C. The adsorption properties of enabling CS-CTAB-AL conjugation introduced a new type of adsorbents, exploited the combination of ionic liquid and surfactant capabilities for wastewater treatment. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Electric Literature of C25H54ClN).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Electric Literature of C25H54ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

The nitrogen-doped carbon supported ultra-small vanadium nitride nanoparticles as a highly efficient oxygen reduction electrocatalyst for the rechargeable Zn-air battery was written by Zhang, Honghui;Wu, Suqin;Deng, Daijie;Wang, Huan;Xun, Suhang;Chen, Feng;Zhang, Jianming;Xu, Li. And the article was included in Inorganic Chemistry Communications in 2022.Reference of 5137-55-3 The following contents are mentioned in the article:

The regulating active sites of vanadium nitride (VN)-based materials is an effective way to improve their oxygen reduction reaction (ORR) performance, which is expected to effectively solve the problem of sluggish kinetics in the cathode of Zn-air batteries. However, traditional synthesis methods cannot uniformly disperse VN, cause inadequate exposure to the active site, resulting in poor ORR performance. Herein, the authors successfully prepared a nitrogen-doped carbon supported ultra-small vanadium nitride nanoparticles (VN/NC) by organic group modification combined with rapid calcination strategies. The size of VN nanoparticles is �-10 nm. The smaller size can ultimately improve the ORR performance of VN/NC by exposing more active sites. Finally, the half-wave potential of the VN/NC is 0.813 V for ORR. More importantly, the Zn-air batteries assembled with the VN/NC catalyst as the air cathode shows a high power d. (115 mW cm^-2) and a large specific capacity (673 mAh g^-1). This approach can successfully synthesize ultra-small size VN nanoparticles, which is of great significance to the development of efficient air cathode materials for the Zn-air battery. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Reference of 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Reference of 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Extraction and recovery of organic compounds from aqueous solution using emulsion liquid membrane process was written by Jusoh, Norela;Othman, Norasikin;Bukhari Rosly, Muhammad. And the article was included in Materials Today: Proceedings in 2021.Electric Literature of C25H54ClN The following contents are mentioned in the article:

The emulsion liquid membrane (ELM) has gained much attention as an advanced separation process for the extraction of organic compounds from aqueous solutions ELM is an important method for separation, concentration, and recovery, as well as in understanding mechanisms of solute transport. In this study, the extraction of several organic compounds such as reactive dyes, lignin, phenol, and succinic acid using ELM have been described. The formulation of ELM including carrier, diluent, surfactant, and stripping agent for each organic compound were summarized. Besides, factors that influence the selectivity and efficiency of the process were also analyzed. It was found the suitable operating condition for ELM process are homogenizer speed (7000-12000 rpm), emulsifying time (3-10 min), surfactant concentration (3%), extraction time (3-10 min), carrier concentration (0-0.7 M), stripping agent concentration (01.-0.3 M), and treat ratio (1:1-1:15). Meanwhile, the extraction, recovery, and enrichment were around 71-95%, 84-98%, and 6.7-13.5, resp. Overall, the ELM formulation and range of operating parameters are found to have great potential for future investigations of the ELM process. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Electric Literature of C25H54ClN).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Electric Literature of C25H54ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Removal of lead ions using OA-Fe₃O₄ magnetic nanoparticles-based pickering emulsion liquid membrane: process optimization using box-behnken response surface methodology was written by Murugan, Perumal;Sarojini, Gopalakrishnan;Saravanane, Raman;Bhuvaneshwari, Soundarajan. And the article was included in Environmental Technology.Recommanded Product: 5137-55-3 The following contents are mentioned in the article:

The purpose of this study is to explore the pickering emulsion liquid membrane (PELM) performance for removing divalent lead ions (Pb II) from aqueous solution In the present work, the membrane phase was prepared by dissolving methyltrioctylammonium chloride (Aliquat 336) with Mahua oil and adding oleic acid coated-ferrosoferric oxide (OA-Fe₃O₄) as magnetic nanoparticles. Exptl. investigation on percentage removal of lead ions was carried out by studying the influencing process parameters such as pH, agitation speed, stripping concentration, initial feed concentration, surfactant concentration, treat ratio, M/S ratio and carrier concentration The optimum condition to remove 98.52% of lead ions from the feed solutions has achieved at a stripping phase concentration of 0.3 M, treat ratio of 3, agitation speed of 300 rpm, initial feed concentration of 10 ppm and stabilizer concentration of 2 wt%. The exptl. results were validated using box-behnken response surface methodol. The extraction ability of OA-Fe₃O₄ magnetic nanoparticles-based PELM has been evaluated using statistical optimization of all the affecting process factors using the design of the experiments This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Recommanded Product: 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Recommanded Product: 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Comparative Studies on the Structure-Performance Relationships of Phenothiazine-Based Organic Dyes for Dye-Sensitized Solar Cells was written by Li, Shengzhong;He, Jingwen;Jiang, Huiyun;Mei, Shu;Hu, Zhenguang;Kong, Xiangfei;Yang, Miao;Wu, Yongzhen;Zhang, Shuhua;Tan, Haijun. And the article was included in ACS Omega in 2021.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

A D-A-π-A dye (PTZ-5) has been synthesized by introducing a benzothiadiazole (BTD) unit as an auxiliary acceptor in a phenothiazine-based D-π-A dye(PTZ-3) to broaden its spectral response range and improve the device performance. Photophys. properties indicate that the inclusion of BTD in the PTZ-5 effectively red-shifted the absorption spectra by reducing the E_gap. However, the device measurements show that the open-circuit voltage (V_oc) of PTZ-5 cell (640 mV) is obviously lower than that of the PTZ-3 cell (710 mV). This results in a poor photoelec. conversion efficiency (PCE) (4.43%) compared to that of PTZ-3 cell (5.53%). Through further comparative anal., we found that the introduction of BTD increases the dihedral angle between the D and A unit, which can reduce the efficiency of intramol. charge transfer (ICT), lead to a less q_CT and lower molar extinction coefficient of PTZ-5. In addition, the ESI test found that the lifetime of the electrons in the PTZ-5 cell is shorter. These are the main factors for the above unexpected result of PCE. Our studies bring new insights into the development of phenothiazine-based highly efficient dye-sensitized solar cells (DSSCs). This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Category: chlorides-buliding-blocks).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Sensitive determination of vincristine in plasma of children with leukaemia using vortex-assisted dispersive liquid-liquid microextraction based on hydrophobic deep eutectic solvent was written by Golpayegani, Mohammad Reza;Akramipour, Reza;Gheini, Simin;Amini, Mazyar Vakili;Fattahi, Farshad;Mohebbi, Ali;Fattahi, Nazir. And the article was included in RSC Advances in 2022.COA of Formula: C25H54ClN The following contents are mentioned in the article:

Vincristine has a wide spectrum of clin. activity and is currently used in the treatment of leukemia. Despite its high therapeutic properties, vincristine has common side effects. Accordingly, it is desirable to determine vincristine in plasma for the use of the drug with strict monitoring. In the present research, for the first time a hydrophobic deep eutectic solvent (DES) composed of methyltrioctylammonium chloride (MTOAC) and n-butanol in a molar ratio of 1 : 3 was used as the extractant in dispersive liquid-liquid microextraction (DLLME) for the extraction and determination of vincristine in the plasma of children with leukemia prior to its anal. by high-performance liquid chromatog.-UV detection (HPLC-UV). Under optimal exptl. conditions, the method showed good linearity with a correlation coefficient (R2) of 0.9986 in the linear range of 0.06-300 μg L^-1, low limit of detection of 0.02 μg L^-1 and acceptable extraction efficiency (EE) of 88.4%. In the final stage of the study, this proposed technique was successfully applied to determine vincristine in real plasma, and the obtained results demonstrated the ability of the synthesized DES to extract drugs from biol. fluids. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3COA of Formula: C25H54ClN).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).COA of Formula: C25H54ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics