Chemistry can be defined as the study of matter and the changes it undergoes. You¡¯ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology. 6092-54-2, Name is Hexyl carbonochloridate, molecular formula is , belongs to chlorides-buliding-blocks compound. In a document, author is Bozkurt, Selahattin, Product Details of 6092-54-2.
A novel turn-on fluorometric reporter-spacer-receptor chemosensor based on calix[4]arene scaffold for detection of cyanate anion
Herein, a novel calix[4]arene compound, which was modified by the 2-(2-aminophenyl)benzothiazole fragment with cyanate recognition function was designed based on the reporter-spacer-receptor sensing system. The construction was done via two-step reaction, and the desired sensor 4 was characterized by FT-IR, H-1-, C-13-NMR, and fluorescence spectroscopy along with HRMS data. The sensor candidate showed distinct fluorometric cyanate detection by means of reporter feature of selected benzothiazole constituent. In the presence of cyanate, the sensor gave a turn-on-type fluorescence at 482 nm with a large stokes’ shift. Furthermore, it was observed that our fluoroionophore 4 is highly selective toward cyanate over remaining anions such as sulfate, phosphate, fluoride, chloride, bromide, iodide, chlorate, and nitrate in 10% aqueous solution of DMSO. The 1:2 stoichiometric ratio of the 4-cyanate complex was given the best fit with Job’s plot based on the titration data. The association constant (K-a) of sensor 4 with cyanate is determined to be 1.64 x 10(5) M-2. The obtained limit of detection (LOD) value for cyanate anion, 312 nM, clearly revealed the remarkable sensitivity of the chemosensor 4. This supramolecular method provides a highly adaptive technique for the detection of cyanate and so cyanide ions by current international standard methods.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 6092-54-2, in my other articles. Product Details of 6092-54-2.