Category: 6294-17-3

MnCl₂-Catalyzed C-H Alkylations with Alkyl Halides was written by Liu, Weiping;Cera, Gianpiero;Oliveira, Joao C. A.;Shen, Zhigao;Ackermann, Lutz. And the article was included in Chemistry – A European Journal in 2017.Formula: C6H12BrCl The following contents are mentioned in the article:

C-H alkylations with challenging β-hydrogen-containing alkyl halides were accomplished with sustainable MnCl₂ as the catalyst under phosphine-ligand-free conditions. The proximity-induced benzamide C-H activation occurred with ample substrate scope through rate-determining C-H metalation, also setting the stage for manganese-catalyzed oxidative C-H methylations. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Formula: C6H12BrCl).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Formula: C6H12BrCl

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Co-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with Alkyl Grignard Reagents was written by Iwasaki, Takanori;Yamashita, Koji;Kuniyasu, Hitoshi;Kambe, Nobuaki. And the article was included in Organic Letters in 2017.Related Products of 6294-17-3 The following contents are mentioned in the article:

The cross-coupling reaction of unactivated alkyl fluorides with alkyl Grignard reagents (alkylmagnesium chlorides) by a CoCl₂/LiI/1,3-pentadiene catalytic system is described. The present reaction smoothly cleaved C-F bonds under mild conditions and achieved alkyl-alkyl cross-coupling even when sterically hindered tertiary alkyl Grignard reagents were employed. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Related Products of 6294-17-3).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Related Products of 6294-17-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

PROTAC-mediated crosstalk between E3 ligases was written by Steinebach, Christian;Kehm, Hannes;Lindner, Stefanie;Vu, Lan Phuong;Koepff, Simon;Lopez Marmol, Alvaro;Weiler, Corinna;Wagner, Karl G.;Reichenzeller, Michaela;Kroenke, Jan;Guetschow, Michael. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2019.Recommanded Product: 1-Bromo-6-chlorohexane The following contents are mentioned in the article:

Small-mol. heterobifunctional degraders can effectively control protein levels and are useful research tools. We assembled proteolysis targeting chimeras (PROTACs) from a cereblon (CRBN) and a von-Hippel-Lindau (VHL) ligase ligand and demonstrated a PROTAC-induced heterodimerization of the two E3 ligases leading to unidirectional and efficient degradation of CRBN. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Recommanded Product: 1-Bromo-6-chlorohexane).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Recommanded Product: 1-Bromo-6-chlorohexane

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Cross-coupling reaction of alkyl halides with alkyl Grignard reagents catalyzed by Cp-iron complexes in the presence of 1,3-butadiene was written by Iwasaki, Takanori;Shimizu, Ryohei;Imanishi, Reiko;Kuniyasu, Hitoshi;Kambe, Nobuaki. And the article was included in Chemistry Letters in 2018.Formula: C6H12BrCl The following contents are mentioned in the article:

Iron-catalyzed cross-coupling reaction of alkyl halides with alkyl Grignard reagents by the combined use of cyclopentadienyl ligand and 1,3-butadiene additive was described. The reaction smoothly proceeded at room temperature using unactivated alkyl bromides and fluorides via non-radical mechanism, which was in sharp contrast with hitherto known Fe-catalyzed cross-coupling reactions of alkyl halides. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Formula: C6H12BrCl).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Formula: C6H12BrCl

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Bis-calix[4]arene-based podants using the bridge position as a constructive mode of subunit connection was written by Fischer, Conrad;Weber, Edwin. And the article was included in Journal of Inclusion Phenomena and Macrocyclic Chemistry in 2014.HPLC of Formula: 6294-17-3 The following contents are mentioned in the article:

A set of bridged calixarenes were synthesized where the bridges were formed by a flexible alkylene chain or a more rigid bistriazole modified connection element of different lengths. NMR measurements as well as MM calculations pointed to rather flexible conjugates showing suitable requirements for a potential formation of inclusion complexes with neutral and anionic guests of appropriate size. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3HPLC of Formula: 6294-17-3).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).HPLC of Formula: 6294-17-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Palladium-catalyzed coupling of α-halo vinylphosphonate and α-phosphonovinyl sulfonate with alkylzincs: straightforward and versatile synthesis of α-alkyl vinylphosphonates was written by Zhang, Li;Fang, Yewen;Jin, Xiaoping;Guo, Ting;Li, Ruifeng;Li, Yan;Li, Xie;Ye, Qilin;Luo, Xiang. And the article was included in Organic Chemistry Frontiers in 2018.Application of 6294-17-3 The following contents are mentioned in the article:

With α-(pseudo)halo vinylphosphonate as the electrophilic coupling partner, a variety of alkyl- and benzylic zinc reagents underwent vinylation reactions to produce α-alkyl vinylphosphonates. This unprecedented Pd-catalyzed Negishi coupling features mild reaction conditions, high functional group tolerance, broad substrate scope, retention of the olefin geometry, and easy gram-scale synthesis. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Application of 6294-17-3).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Application of 6294-17-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Photoinduced Radical Borylation of Alkyl Bromides Catalyzed by 4-Phenylpyridine was written by Zhang, Li;Wu, Zhong-Qian;Jiao, Lei. And the article was included in Angewandte Chemie, International Edition in 2020.Formula: C6H12BrCl The following contents are mentioned in the article:

Utilizing 4-phenylpyridine catalysis, we developed a visible-light-induced transition-metal-free radical borylation reaction of unactivated alkyl bromides that features a broad substrate scope and mild reaction conditions. Mechanistic studies revealed a novel nucleophilic substitution/photoinduced radical formation pathway, which could be utilized to trigger a variety of radical processes. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Formula: C6H12BrCl).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Formula: C6H12BrCl

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Photoswitching Using Visible Light: A New Class of Organic Photochromic Molecules was written by Helmy, Sameh;Leibfarth, Frank A.;Oh, Saemi;Poelma, Justin E.;Hawker, Craig J.;Read de Alaniz, Javier. And the article was included in Journal of the American Chemical Society in 2014.Related Products of 6294-17-3 The following contents are mentioned in the article:

A versatile new class of organic photochromic mols. that offers an unprecedented combination of phys. properties including tunable photoswitching using visible light, excellent fatigue resistance, and large polarity changes is described. These unique features offer significant opportunities in diverse fields ranging from biosensors to targeted delivery systems while also allowing non-experts ready synthetic access to these materials. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Related Products of 6294-17-3).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Related Products of 6294-17-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Palladium and copper-supported on charcoal: A heterogeneous multi-task catalyst for sequential Sonogashira-Click and Click-Heck reactions was written by Rossy, Cybille;Majimel, Jerome;Delapierre, Mona Treguer;Fouquet, Eric;Felpin, Francois-Xavier. And the article was included in Journal of Organometallic Chemistry in 2014.Electric Literature of C6H12BrCl The following contents are mentioned in the article:

This paper describes the development of one-pot sequential Sonogashira-Click and Click-Heck reactions by using Pd-Cu/C as a heterogeneous multi-task catalyst for the synthesis of heterocyclic structures e. g., I. Details of the optimization studies and the substrate scope are discussed. These methodologies allow the preparation of functionalized triazoles in simple exptl. conditions with inexpensive reagents. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Electric Literature of C6H12BrCl).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Electric Literature of C6H12BrCl

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Efficient covalent capping of carbon and gold with TEMPO for catalysis and spin writing was written by Romanovs, Vitalijs;Sidorkin, Valery;Doronina, Evgeniya;Jouikov, Viatcheslav. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2022.Safety of 1-Bromo-6-chlorohexane The following contents are mentioned in the article:

Covalent immobilization of TEMPO at carbon and gold via an aliphatic -(CH₂)₆– linker was achieved via cathodic grafting of a diamagnetic precursor, tetramethylpiperidine, with subsequent >NH to >NO oxidation to give TEMPO-capped paramagnetic interfaces (ΓTEMPO = 5.2 x 10^-10 mol cm^-2); catalytic and spin switching potential of the thus prepared systems was demonstrated. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Safety of 1-Bromo-6-chlorohexane).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Safety of 1-Bromo-6-chlorohexane

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics