Category: 7080-50-4

Chandra published the artcile3-(4-Methoxyphenyl)-5-methylisoxazole-4-carboxylic acid, Recommanded Product: Sodium chloro(tosyl)amide trihydrate, the publication is Acta Crystallographica, Section E: Structure Reports Online (2013), 69(3), o388, database is CAplus and MEDLINE.

In the title compound, C₁₂H₁₁NO₄, the dihedral angle between the benzene and isoxazole rings is 42.52(8)°. The carboxylic acid group is close to being coplanar with the isoxazole ring [dihedral angle = 5.3(2)°]. In the crystal, inversion dimers linked by pairs of O-H···O hydrogen bonds generate R₂²(8) loops.

Acta Crystallographica, Section E: Structure Reports Online published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C7H13ClNNaO5S, Recommanded Product: Sodium chloro(tosyl)amide trihydrate.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Padmavathi, V. published the artcileSynthesis of novel bis heterocycles: bis pyrroles, pyrrolyl pyrazolines and pyrrolyl isoxazolines, Product Details of C7H13ClNNaO5S, the publication is Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry (2008), 47B(11), 1707-1712, database is CAplus.

The Michael acceptors, 1-arylsulfonyl-2-styrylsulfonylethenes were used as synthons to develop bis pyrroles, pyrrolyl pyrazolines and pyrrolyl isoxazolines by 1,3-dipolar cycloaddition of tosylmethyl isocyanide, nitrile imines and nitrile oxides.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C7H13ClNNaO5S, Product Details of C7H13ClNNaO5S.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Zhang, Xiulian published the artcileAryldiazonium ion initiated C-N bond cleavage for the versatile, efficient and regioselective ring opening of aziridines, Name: Sodium chloro(tosyl)amide trihydrate, the publication is Organic Chemistry Frontiers (2019), 6(11), 1832-1836, database is CAplus.

Aryldiazonium salts were proved to initiate the regioselective cleavage of aziridines for the installation of varied functional groups to gave β-substituted aryl sulfonamides I [R¹ = Ph, 4-MeC₆H₄, 4-ClC₆H₄, etc.; R² = H, Me; R³ = OMe, OBn, SPh, etc.]. The ring-opening process was effective and general for a variety of nucleophiles, including [O], [S] and [N] at room temperature This highly regioselective process, which could be performed at the gram scale, enjoys operational simplicity, as well as mild and metal-free conditions. The postulated reaction mechanism involved a single electron transfer from aziridines to aryldiazonium salts, which generates a highly reactive amino radical cation.

Organic Chemistry Frontiers published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C8H10S, Name: Sodium chloro(tosyl)amide trihydrate.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Yakubenko, Artyom A. published the artcileSelf-association of diphenylpnictoginic acids in solution and solid state: covalent vs. hydrogen bonding, Quality Control of 7080-50-4, the publication is Physical Chemistry Chemical Physics (2022), 24(13), 7882-7892, database is CAplus and MEDLINE.

Triphenylpnictogens were oxidized to access diphenylpnictioginic acids Ph₂XOOH (X = P, As, Sb, Bi). Oxidation with chloramine-T does not lead to the cleavage of a C-pnictogen bond. The preliminary reductive cleavage with sodium in liquid ammonia followed by the oxidation with hydrogen peroxide was successfully used for the synthesis of diphenylphosphinic and diphenylarsinic acids. In solid state (by XRD), all diphenylpnictoginic acids form polymeric chains. Diphenylbismuthinic and diphenylantimonic acids form polymeric covalent adducts, while diphenylphosphinic and diphenylarsinic chains are associated through hydrogen bonding. Unlike diphenylphosphinic acid, diphenilarsinic acid forms two polymorphs of hydrogen-bonded infinite chains. In solution in a polar aprotic solvent diphenylarsinic acid, similarly to dimethylarsinic, forms hydrogen-bonded cyclic dimers together with a small amount of cyclic trimers.

Physical Chemistry Chemical Physics published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C9H20Cl2Si, Quality Control of 7080-50-4.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Mal, Sanjib published the artcileFacile one pot synthesis of 8-chloro-[1,2,4]triazolo[4,3-a]pyrazines via oxidative cyclisation using chloramine T, Category: chlorides-buliding-blocks, the publication is Tetrahedron Letters (2015), 56(22), 2896-2901, database is CAplus.

A facile and expedient one pot synthesis of 8-chloro-[1,2,4]triazolo[4,3-a]pyrazine derivatives I [R¹ = H, Cl; R = Ph, 3-MeO-C₆H₄, 4-Br-C₆H₄, etc.] from 2-chloro-3-hydrazinylpyrazine and aldehydes is described using chloramine T trihydrate as a safe and convenient electrocyclisation (oxidising) agent. The presence of the chloro group on pyrazine enabled us to access versatile new synthetic scaffolds II [R¹ = Ph, 2-thiophenyl, 2,4-diCl-C₆H₃] by easy diversification using palladium catalyzed Suzuki-Miyaura and Sonogashira cross coupling reactions. The products are obtained in high yields in short reaction time under mild conditions without the need for chromatog. purification

Tetrahedron Letters published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C7H13ClNNaO5S, Category: chlorides-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Alagiri, Kaliyamoorthy published the artcileCatalyst-Free Regio- and Stereospecific Synthesis of β-Sulfonamido Dithiocarbamates: Efficient Ring-Opening Reactions of N-Tosyl Aziridines by Dialkyldithiocarbamates, COA of Formula: C7H13ClNNaO5S, the publication is Chemistry – A European Journal (2011), 17(25), 6922-6925, S6922/1-S6922/62, database is CAplus and MEDLINE.

We have developed an efficient protocol for the synthesis of β-sulfonamido dithiocarbamates by using a ring-opening strategy of aziridines by thiocarbamates. These methods avoid toxic catalysts and, in most cases, give nearly quant. yields without any byproducts. This strategy provides an elegant method for synthesizing a wide range of β-sulfonamido dithiocarbamates by using inexpensive and readily available starting materials. In addition, a one-pot method has been developed for a facile ring-opening of aziridines by using in situ generated dialkyldithiocarbamate. This methodol. could potentially prove useful for the synthesis of medicinally active and other com. dithiocarbamate derivatives

Chemistry – A European Journal published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C7H13ClNNaO5S, COA of Formula: C7H13ClNNaO5S.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Olmstead, Marilyn M. published the artcileCrystal and molecular structure of chloramine-T trihydrate. Absence of a sodium-nitrogen interaction in the oxidant. N-chloro-N-sodiotoluene-p-sulfonamide, Product Details of C7H13ClNNaO5S, the publication is Inorganic Chemistry (1986), 25(22), 4057-8, database is CAplus.

The title compound is triclinic, space group PT, with a 6.393(1), b 7.510(1)8 c 13.767(2) Å, α 85.33(1), β 83.92(1), and γ 74.11(1)°; Z = 2. Final R = 0.039 for 2366 data. At. coordinates are given. The main feature of the structure involves the lack of the commonly represented interaction between Na and N. Instead, the Na ion is coordinated to one of the sulfonamide oxygens. The rest of the Na coordination sphere involves oxygens (from water of crystallization) and a Cl from a neighboring mol. The structure is the first for an [RSO₂NCl]^– moiety.

Inorganic Chemistry published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C7H13ClNNaO5S, Product Details of C7H13ClNNaO5S.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Gottardi, Waldemar published the artcileThe Integral Method, a new approach to quantify bactericidal activity, Application In Synthesis of 7080-50-4, the publication is Journal of Microbiological Methods (2015), 71-78, database is CAplus and MEDLINE.

The bactericidal activity (BA) of antimicrobial agents is generally derived from the results of killing assays. A reliable quant. characterization and particularly a comparison of these substances, however, are impossible with this information. We here propose a new method that takes into account the course of the complete killing curve for assaying BA and that allows a clear-cut quant. comparison of antimicrobial agents with only one number The new Integral Method, based on the reciprocal area below the killing curve, reliably calculates an average BA [log₁₀ CFU/min] and, by implementation of the agent’s concentration C, the average specific bactericidal activity SBA = BA / C [log₁₀ CFU/min/mM]. Based on exptl. killing data, the pertaining BA and SBA values of exemplary active halogen compounds were established, allowing quant. assertions. N-chlorotaurine (NCT), chloramine T (CAT), monochloramine (NH₂Cl), and iodine (I₂) showed extremely diverging SBA values of 0.0020 ± 0.0005, 1.11 ± 0.15, 3.49 ± 0.22, and 291 ± 137 log₁₀ CFU/min/mM, resp., against Staphylococcus aureus. This immediately demonstrates an approx. 550-fold stronger activity of CAT, 1730-fold of NH₂Cl, and 150,000-fold of I₂ compared to NCT. The inferred quant. assertions and conclusions prove the new method suitable for characterizing bactericidal activity. Its application comprises the effect of defined agents on various bacteria, the consequence of temperature shifts, the influence of varying drug structure, dose-effect relationships, ranking of isosteric agents, comparison of competing com. antimicrobial formulations, and the effect of additives.

Journal of Microbiological Methods published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C7H13ClNNaO5S, Application In Synthesis of 7080-50-4.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Borah, Arun Jyoti published the artcileBromamine-T as an efficient amine source for Sharpless asymmetric aminohydroxylation of olefins, Quality Control of 7080-50-4, the publication is Tetrahedron Letters (2014), 55(3), 713-715, database is CAplus.

Asym. aminohydroxylation of various olefins was carried out using bromamine-T as nitrogen source in the presence of (DHQ)₂PHAL ligand. The new nitrogen source was effective in terms of yield and reaction time. The optical purities of the products could be obtained with ≤99% ee.

Tetrahedron Letters published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C7H13ClNNaO5S, Quality Control of 7080-50-4.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Patil, A. A. published the artcileMeasurement of critical micelle concentration of technical grade non-ionic detergent in presence of chloramine-T using dye solubilization technique, HPLC of Formula: 7080-50-4, the publication is Oriental Journal of Chemistry (2011), 27(2), 753-756, database is CAplus.

Com. available tech. grade non-ionic surfactants usually contain impurities and have a broad distribution of mol. weight owing to degree of ethoxylation. It has shown that the surface tension method (Wilhelmy plate) is very sensitive if impurities are present in the surfactant. Much lower CMC values are obtained for tech. grade surfactants with the surface tension method than with the dye solubilization method. The CMC determined by the dye solubilization technique are in fair agreement with the values obtained by other available methods. The change in CMC of Tween-40 has been studied through the influence of additive Chloramine-T in aqueous medium by measuring the absorbance of the pure surfactant and with Chloramine-T in presence of the water-insoluble dye Orange-OT by using the dye solubilization technique. The absorbance was increased with increasing concentration of pure Tween-40. The absorbance of the mixed systems with Chloramine-T shows the same trend. The CMC of pure surfactant was decreased with increasing concentration of Chloramine-T. The influence of Chloramine-T on the absorbance of Tween-40 is a clear indication that the phenomenon of dye micellization is associated with the different micelles coalescing.

Oriental Journal of Chemistry published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C7H13ClNNaO5S, HPLC of Formula: 7080-50-4.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics