Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 74-11-3, Name is 4-Chlorobenzoic acid, molecular formula is C7H5ClO2. In an article, author is Islam, Md Sayedul,once mentioned of 74-11-3, Quality Control of 4-Chlorobenzoic acid.
A Highly Active Catalyst 2,4,6-Tris (di-4-chlorobenzamido)-1,3,5-triazine Palladium (II) Chloride for the Green Synthesis of Substituted Dihydrobenzo[b]thiophene in Ionic Liquid
The palladium-metallodendrimer (Pd-MD) 2,4,6-tris (di-4-chlorobenzamido)-1,3,5-triazine palladium (II) chloride was synthesized by the reaction of substituted triazine, substituted benzoyl chloride, and (Ph3P)(2)PdCl2 in DMF at 100 degrees C. This Pd-MD was characterized by FTIR, H-1 NMR, C-13 NMR, Scanning Electron Microscopy (SEM), Energy Dispersive X-ray (EDX), mass spectrometry, X-ray photoelectron spectroscopy (XPS), elemental analysis, Thermogravimetric analysis (TGA), and Differential scanning calorimetry (DSC) methods. This catalyst was successfully applied for the green synthesis of different substituted alkyl 2,3-dihydrobenzo[b]thiophene-2-carboxylates in ionic liquid tetra-n-butylammonium bromide (TBAB) solution at 120 degrees C for 2.5 hours with a good to an excellent percentage of yields (75 % to 96 %). Importantly, this homogeneous catalytic system was easily recoverable and reusable at least five times without a significant loss of activity.
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