Category: 75-57-0

A Strained Ion Pair Permits Carbon Dioxide Fixation at Atmospheric Pressure by C-H H-Bonding Organocatalysis was written by Xu, Jiaxi;Xian, Anmei;Li, Zhenjiang;Liu, Jingjing;Zhang, Zhihao;Yan, Rui;Gao, Luoyu;Liu, Bo;Zhao, Lili;Guo, Kai. And the article was included in Journal of Organic Chemistry in 2021.Synthetic Route of C4H12ClN The following contents are mentioned in the article:

The cycloadditions of carbon dioxide into epoxides to afford cyclic carbonates by H-bond donor (HBD) and onium halide (X) cocatalysis have emerged as a key strategy for CO₂ fixation. However, if the HBD is also a halide receptor, the two will quench each other, decreasing the catalytic activity. Here, we propose a strained ion pair tris(alkylamino)cyclopropenium halide (TAC·X), in which TAC repels X. TAC possesses a pos. charged cyclopropenium core that makes the vicinal C-H or N-H a nonclassical HBD. The interionic strain within TAC·X makes TAC a more electrophilic HBD, allowing it to activate the oxygen of the epoxide and making X more nucleophilic and better able to attack the methylene carbon of the epoxide. NMR titration spectra and computational studies were employed to probe the mechanism of the cycloaddition of CO₂ to epoxides reactions under the catalysis of TAC·X. The ¹H and ¹³C{¹H}NMR titration spectra of the catalyst with the epoxide substrate unambiguously confirmed H-bonding between TAC and the epoxide. DFT computational studies identified the transition states in the ring-opening of the epoxide (TS1) and in the ring-closure of the cyclic carbonate (TS2). This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Synthetic Route of C4H12ClN).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Synthetic Route of C4H12ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Screening of Ionic Liquids and Deep Eutectic Solvents for Physical CO₂ Absorption by Soft-SAFT Using Key Performance Indicators was written by Alkhatib, Ismail I. I.;Ferreira, Margarida L.;Alba, Carlos G.;Bahamon, Daniel;Llovell, Felix;Pereiro, Ana B.;Araujo, Joao M. M.;Abu-Zahra, Mohammad R. M.;Vega, Lourdes F.. And the article was included in Journal of Chemical & Engineering Data in 2020.SDS of cas: 75-57-0 The following contents are mentioned in the article:

The efficient screening of solvents for CO₂ capture requires a reliable and robust equation of state to characterize and compare their thermophys. behavior for the desired application. In this work, the potentiality of 14 ionic liquids (ILs) and 7 deep eutectic solvents (DESs) for CO₂ capture was examined using soft-SAFT as a modeling tool for the screening of these solvents based on key process indicators, namely, cyclic working capacity, enthalpy of desorption, and CO₂ diffusion coefficient Once the models were assessed vs. exptl. data, soft-SAFT was used as a predictive tool to calculate the thermophys. properties needed for evaluating their performance. Results demonstrate that under the same operating conditions, ILs have a far superior performance than DESs primarily in terms of amount of CO₂ captured, being at least two-folds more than that captured using DESs. The screening tool revealed that among all the examined solvents and conditions, [C₄ py][NTf₂] is the most promising solvent for phys. CO₂ capture. The collection of the acquired results confirms the reliability of the soft-SAFT EoS as an attractive and valuable screening tool for CO₂ capture and process modeling. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0SDS of cas: 75-57-0).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.SDS of cas: 75-57-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Synthesis optimization of phase-singularized UZM-5 zeolite under hydrothermal conditions: The critical control points of its crystalline phase and crystallinity was written by Yao, Rui;Zhang, Wenhao;Peng, Yuan;Song, Hongling;Zhu, Chenyu;Shu, Lun;Yang, Weishen. And the article was included in Microporous and Mesoporous Materials in 2022.Application of 75-57-0 The following contents are mentioned in the article:

Pure UZM-5 zeolite with either nanosheet or rosette-shaped morphol. have been successfully synthesized by a charge d. mismatch (CDM) method under a corresponding tumbling or static conditions. The synthesis parameters were fully investigated to abstain from commonly accompanying byproducts, including SOD or amorphous phase which greatly interfered with the use of UZM-5. The crystalline phases and relative crystallinity of resultant products were carefully substantiated by using scanning electron microscope and X-ray diffraction. As a result, the molar ratios of water and structure directing agents thereof were deemed to be two vital parameters which had significant effects on the well-defined pure-phase UZM-5 zeolite production Trace ethanol added in the reagent solution was found to play a role in zeolite purification There is an urgent need in electrocatalytic reduction of nitrate to ammonia. In this work, pure UZM-5 zeolite with Lewis acid sites served as catalyst matrix for the application to produce this valuable chem. Excellent ammonia production rate with high faradaic efficiency was achieved by using the obtained novel UZM-5-based catalyst for the reduction reaction, strongly proving the great potential of this young zeolite in catalysis applications. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Application of 75-57-0).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Application of 75-57-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Notched-Polyoxometalate Strategy to Fabricate Atomically Dispersed Ru Catalysts for Biomass Conversion was written by Han, Yunhu;Dai, Jun;Xu, Ruirui;Ai, Wenying;Zheng, Lirong;Wang, Yu;Yan, Wensheng;Chen, Wenxing;Luo, Jun;Liu, Qiang;Wang, Dingsheng;Li, Yadong. And the article was included in ACS Catalysis in 2021.Product Details of 75-57-0 The following contents are mentioned in the article:

The development of the synthesis methods of single-atom catalysts (SACs) is of great significance for the study of the specificity of SACs. Herein, we report a strategy to immobilize Ru atom using notched-polyoxometalate (N-POM) to prevent Ru from aggregation during pyrolysis and obtain a Ru catalyst with atomically dispersed Ru anchored on uniform subsupporter WO_x clusters on carbon-nitrogen (Ru1@WO_x/CN). Interestingly, the as-synthesized Ru1@WO_x/CN catalyst exhibits an outstanding catalytic activity for the hydrogenation of levulinic acid (LA) to γ-valerolactone (GVL) in solvent-free condition (conversion of over 99% and selectivity of ~100%). According to exptl. anal. and d. functional theory (DFT) calculations, both the regulation of the electronic structure of Ru active center through the subsupporter WO_x clusters as well as the CN substrate and the catalysis of the acidifying WO_x in the reaction for the dehydrogenation of 4-hydroxypentanoic acid intermediate are correlated with the enhancement of the enhanced catalytic activity. This N-POM strategy is also demonstrated to be impressive in preparing a series of atomically dispersed noble-metal atoms, which provides an opportunity of discovering SACs. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Product Details of 75-57-0).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Product Details of 75-57-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Ball-like nickel hydroxide nanoparticles: Electro-synthesis, characterization, and application was written by Bagheri, Fathollah;Mosivand, Saba. And the article was included in Materials Today Communications in 2021.Formula: C4H12ClN The following contents are mentioned in the article:

Ball-like nickel hydroxide nanostructures were synthesized using electro-crystallization method. The synthesis was carried out in an electrolytic cell containing two nickel electrodes, and an aqueous solution of C₄H₁₂Cl as supporting electrolyte. The effect of applied voltage on morphol., structure, and magnetic properties of the products were studied using XRD, FT-IR, SEM/EDX, TEM, and VSM. The XRD patterns confirm the formation of hexagonal structure of Ni(OH)₂ without any impurities. Based on FT-IR results the amine mols. present at the surface of particles. The SEM images show that the products have ball-like shape. Each nickel hydroxide ball composed of the small nanoparticles. The mean particle size increases from ∼9 nm to ∼50 nm by increasing the applied voltage from 8 V to 26 V. The ability of electro-synthesized nickel hydroxide nanostructures on removal of cobalt and cadmium from laboratory water and real water of Khorram-rood, Seimareh, and Kashkan rivers in Iran, has been investigated. The AAS data show that the removal efficiency of heavy metals from real water is higher than laboratory water. Based on these results we could successfully remove 100% of cadmium and 85.8% of cobalt from real water samples. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Formula: C4H12ClN).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Formula: C4H12ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Solvated Nickel Complexes as Stoichiometric and Catalytic Perfluoroalkylation Agents was written by Shreiber, Scott T.;Vicic, David A.. And the article was included in Angewandte Chemie, International Edition in 2021.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

The acetonitrile-solvated [(MeCN)Ni(C₂F₅)₃]^– was prepared in order to compare and contrast its reactivity with the known [(MeCN)Ni(CF₃)₃]^– towards organic electrophiles. Both [(MeCN)Ni(CF₃)₃]^– and [(MeCN)Ni(C₂F₅)₃]^– successfully react with aryl iodonium and diazonium salts as well as alkynyl iodonium salts to give fluoroalkylated organic products. Electrochem. anal. of [(MeCN)Ni^II(C₂F₅)₃]^– suggests that, upon electro-oxidation to [(MeCN)_nNi^III(C₂F₅)₃], reductive homolysis of a perfluoroethyl radical occurs, with the concomitant formation of [(MeCN)₂Ni^II(C₂F₅)₂]. Catalytic C-H trifluoromethylations of electron-rich arenes were successfully achieved using either [(MeCN)Ni(CF₃)₃]^– or the related [Ni(CF₃)₄]^2-. Stoichiometric reactions of the solvated nickel complexes reveal that “ligandless” nickel is exceptionally capable of serving as reservoir of CF₃ groups under catalytically relevant conditions. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Category: chlorides-buliding-blocks).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Synthesis, crystal structure and characterization of [N(CH₃)₄]₄[Mo₁₀O₁₈ (OH)₄(O₂)₁₀(O₂)₂]·6H₂O was written by Liu, Xuemei;Li, Huimin;Ding, Liqin;Guo, Kexin;Li, Jinhuan. And the article was included in Hebei Daxue Xuebao, Ziran Kexueban in 2021.Quality Control of Tetramethylammonium chloride The following contents are mentioned in the article:

A new tetra-Me ammonium decamolybdate [N(CH₃)₄]₄[Mo₁₀O₁₈(OH)₄(O₂)₁₀(O₂)₂]·6H₂O with peroxo and superoxo groups was synthesized by reacting of 30% hydrogen peroxide as the oxidant, ammonium molybdate and tetra-Me ammonium chloride in aqueous solution at room temperature The compound was characterized by elemental anal., IR, UV spectroscopy and its structure was determined by single crystal Xray diffraction. The compound belongs to monoclinic system with space group P2₁/c, a = 1.443(16) nm, b = 1.168(12) nm, c = 1.693(17) nm, β = 99.32(3)°, V = 2.814(5) nm³, Z = 2, D_c = 2.441 g/cm³, R₁ = 0.0356, wR₂ = 0.1050 (I > 2, GOF = 1.087. The compound anions exhibit a centrosym. structure containing two superoxo groups with a bond length of 0.1145 nm and ten classical peroxo groups with a bond length range of 0.1435-0.1481nm. The compound is unstable in water, but stable in solid state at room temperature, and can rapidly oxidize I^– into I₂ with the yield of iodine reaching 91.2%, indicating the compound has strong oxidizing properties due to peroxo and superoxo groups in the structure. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Quality Control of Tetramethylammonium chloride).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Quality Control of Tetramethylammonium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Reversible Co-Self-Assembly and Self-Sorting Systems of Polymer Micelles in Water: Polymers Switch Association Partners in Response to Salts was written by Kanno, Rikuto;Tanaka, Kei;Ikami, Takaya;Ouchi, Makoto;Terashima, Takaya. And the article was included in Macromolecules (Washington, DC, United States) in 2022.Synthetic Route of C4H12ClN The following contents are mentioned in the article:

Reversible self-sorting and co-self-assembly systems of amphiphilic synthetic mols. in water would bring innovative methodologies in creating repeatedly transformable multicomponent self-assemblies that are responsive to the outer environment and stimuli. Herein, we report reversible co-self-assembly and self-sorting systems of the binary blends of amphiphilic random copolymers bearing quaternary ammonium cation and dodecyl groups and those carrying poly(ethylene glycol) (PEG) chains and dodecyl groups in water. The cation copolymers co-self-assembled with the PEG copolymers to form cation/PEG-fused micelles in pure water, while the fused micelles self-sorted into discrete cation or PEG micelles in the presence of salts. Importantly, those random copolymers reversibly switch association partners in response to the presence or absence of salts in water. The size of the fused micelles was dependent on their copolymer composition but independent of the mixing ratio of cation and PEG copolymers. The fused micelles thus coexisted with the extra amount of cation or PEG micelles. We further revealed that the co-self-assembly and self-sorting of their copolymers are driven by the exchange of polymer chains between micelles like the exchange of subdomains in protein self-assemblies. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Synthetic Route of C4H12ClN).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Synthetic Route of C4H12ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Synthesis, characterization and photoluminescence properties of an organic-inorganic hybrid monolacunary Keggin-type polyoxotungstate was written by Wang, Ke;Feng, Shuo;Ma, Pengtao. And the article was included in Inorganic Chemistry Communications in 2021.Synthetic Route of C4H12ClN The following contents are mentioned in the article:

An organic-inorganic hybrid lanthanide-based polyoxometalate (Ln-POM) [N(CH₃)₄]₃K₂[Tb(C₇H₅O₃)(H₂O)₂(α-PW₁₁O₃₉)]·10H₂O (1) was synthesized and further characterized by single crystal x-ray diffraction anal., elemental analyses, Inductive Coupled Plasma Emission Spectrometer (ICP), powder x-ray diffraction (PXRD), Fourier transform IR (FTIR) spectroscopy, solid-state UV/vis spectrum and thermogravimetric analyses (TGA). Single-crystal x-ray diffraction analyses indicated that both organic ligand and [α-PW₁₁O₃₉]^7- group directly bind Tb³⁺ center for the formation of polyanion in 1. The photoluminescence property of 1 was investigated at room temperature, and the results showed that compound 1 exhibits lower energy transfer efficiency from POM fragment and organic ligand to Tb³⁺ ion. Furthermore, time-resolved emission spectroscopy indicates that the photoexcitation O → M ligand to metal charge transfer (LMCT) of POM fragments and organic ligand can sensitize the Tb³⁺ ions through intramol. energy transitions in 1. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Synthetic Route of C4H12ClN).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Synthetic Route of C4H12ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Deep desulfurization performance of thiophene with deep eutectic solvents loaded carbon nanotube composites was written by Liu, Yue;Xue, Jiaojiao;Zhou, Xin;Cui, Yingna;Yin, Jingmei. And the article was included in Royal Society Open Science in 2021.Name: Tetramethylammonium chloride The following contents are mentioned in the article:

One source of air pollution is the combustion of sulfur compounds in fuel oil. Reducing sulfur content in fuel oil has become a hot issue demanding timely solutions Using ionic liquids and deep eutectic solvents (DESs) to remove sulfides in fuel oil has achieved good results presently. However, since DESs are liquid and their transportation and separation are inconvenient, a new way is proposed that the DESs are loaded on the carbon nanotubes (CNTs) with large sp. surface area and good chem. stability. A series of composites materials (DESs/CNTs) were prepared Finally, they are applied to the removal of sulfides in fuel oil. This loading method, which imparts introduced unique physico-chem. properties of the DESs to the carrier materials, preserves both advantages while overcoming some of the problems with DESs. The interaction between DESs and CNTs is mutual promotion. Therefore, this study has important theor. significance and industrial application value. Under optimal conditions, when the reagent ChCl/p-TsOH (1 : 2) was loaded on multi-walled CNTs (OD= 30-60 nm) to prepare the composite material (ChCl/p-TsOH)/CNTs, the single desulfurization rate of the composite material was 95.8%. Finally, the catalytic/oxidation mechanism was studied systematically and this work would provide a green route for the desulfurization of fuels. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Name: Tetramethylammonium chloride).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Name: Tetramethylammonium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics