Grob, Jonathan E. published the artcileOne-Pot C-N/C-C Cross-Coupling of Methyliminodiacetic Acid Boronyl Arenes Enabled by Protective Enolization, Recommanded Product: 4-Chloro-2-ethoxycarbonylphenylboronic acid, the publication is Organic Letters (2012), 14(21), 5578-5581, database is CAplus and MEDLINE.
Iterative cross-coupling is a highly efficient and versatile strategy for modular construction in organic synthesis, though this has historically been demonstrated solely in the context of C-C bond formation. A C-N cross-coupling of haloarene methyliminodiacetic acid (MIDA) boronates with a wide range of aromatic and aliphatic amines is reported. Successful cross-coupling of aliphatic amines was realized only through protective enolization of the MIDA group. This reaction paradigm was subsequently utilized to achieve a one-pot C-N/C-C cross-coupling sequence.
Organic Letters published new progress about 850568-61-5. 850568-61-5 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Boronic acid and ester,Benzene,Ester,Boronic Acids,Boronic Acids,Boronic acid and ester,, name is 4-Chloro-2-ethoxycarbonylphenylboronic acid, and the molecular formula is C9H10BClO4, Recommanded Product: 4-Chloro-2-ethoxycarbonylphenylboronic acid.
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