Category: 866-23-9

McKenna, Charles E. published the artcileThe facile dealkylation of phosphonic acid dialkyl esters by bromotrimethylsilane, Application In Synthesis of 866-23-9, the publication is Tetrahedron Letters (1977), 155-8, database is CAplus.

The phosphonates RP(O)(OR1)2 [I; R = CH2:CH, PhCH2, EtO(CH2)2, (EtO)2P(O)CH2, R1 = Et; R = Bz, (MeO)2P(O)CH2, R1 = Me] were dealkylated by treatment with Me3SiBr at 25° for 1-2 h to give quant. RP(O)(OSiMe3)2. Similar dealkylation of I (R = Cl3C, R1 = Et) at 61-9° for 2.7 h gave ≥99% Cl3CP(O)(OSiMe3)2. Dealkylations with Me3SiCl required higher temperatures and gave low yields. The silyl esters may be hydrolyzed to give the parent phosphonic acids.

Tetrahedron Letters published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Application In Synthesis of 866-23-9.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Nakasato, Satoshi published the artcileSynthesis of dialkyl trichloromethylphosphonates and their properties for additives, Computed Properties of 866-23-9, the publication is Journal of the American Oil Chemists’ Society (1970), 47(8), 283-5, database is CAplus.

Nine (C2-18) dialkyl trichloromethylphosphonates (TCMP) were synthesized by the Arbusov reaction from the corresponding trialkyl phosphite and CCl4. The reaction of (EtO)3P and CCl4 using daylight was completed in about 4 hr. However, in the preparation of the higher dialkyl TCMP the mixture of (RO)3P and CCl4 had to be refluxed 8 hr or more. These compounds were effective chelating, antistatic and flame resistant additives in a formulation of poly(vinyl chloride) as well as excellent extreme pressure additives for lubricating oil; especially the dibutyl TCMP which was effective at 0.25%.

Journal of the American Oil Chemists’ Society published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Computed Properties of 866-23-9.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Saito, Tetsuo published the artcileSystemic inseccticidal properties of certain organic phosphorus compounds to the green peach aphid, Myzus persicae, and the tobacco cutworm, Prodenia litura, Name: Diethyltrichloromethylphosphonate, the publication is Bochu Kagaku (1966), 31(2), 77-81, database is CAplus.

Screening tests of insecticidal activity for ∼50 organophosphorus compounds used the sucking insect, green peach aphid, and the chewing insect, tobacco cutworm. The established systemic insecticides were usually highly toxic to the aphid while being less toxic to the cutworm. One of the thiophosphate esters, ((EtO)2P(S)SCH2CO2(CH2)2Cl) was toxic to the cutworm. Five phosphate esters were toxic to both insects. O,O-Di-Me dichlorohydroxyethanephosphonate and its Ac ester, O,O-di-Me trichlorohydroxyethanephosphonate and its Et Me homolog were more toxic to the cutworm than the aphid. The test plant was cabbage and the test chems. were formulated with Me2CO-C6H6-emulsifier 30:30:30% weight/weight Insecticidal activity was indicated by mortality at concentrations of 1000 ppm. or lower.

Bochu Kagaku published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Name: Diethyltrichloromethylphosphonate.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Stutz, Helmut published the artcilePhostones with potential alkylating properties, Recommanded Product: Diethyltrichloromethylphosphonate, the publication is Zeitschrift fuer Chemie (1975), 15(2), 52-4, database is CAplus.

The reaction of (EtO)2PR with HO(CH2)4Cl gave phostones I [n = 2, R = EtO (II), Ph]. The cyclization of XCH2(CH2)nCH2P(O)(OEt)R (X = halo) gave phostones I (n = 1, 2; R = PhO, Cl3C). II was chlorinated with PCl5 to give I (n = 2, R = Cl). Thiourea and 2-mercaptobenzimidazole were S-alkylated and aniline and piperidine were N-alkylated with I.

Zeitschrift fuer Chemie published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C44H28ClFeN4, Recommanded Product: Diethyltrichloromethylphosphonate.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Bailey, William J. published the artcilePyrolysis of esters. XXII. Synthesis of bisdienes from 2-hydroxymethyl-1,3-butadiene, Quality Control of 866-23-9, the publication is Journal of Organic Chemistry (1962), 2732-6, database is CAplus.

cf. CA 57, 4529d. A new synthesis of 2-hydroxymethyl-1,3-butadiene was developed, starting from commercially available 2-amino-2-ethyl-1,3-propanediol and involving a pyrolysis of an amine oxide as well as the pyrolysis of an ester. Hydroxymethylbutadiene treated with vinyl acetate in the presence of a mercuric oxide-boron trifluoride etherate mixture gave 38% bis(2-butadienylmethyl) acetal. Treatment of the hydroxymethylbutadiene with hexamethylene diisocyanate gave 76% solid bis(2-butadienylmethyl) hexamethylenecarbamate, while treatment with m-xylylene diisocyanate gave 91% solid bis(2-butadienylmethyl) m-xylylenecarbamate.

Journal of Organic Chemistry published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Quality Control of 866-23-9.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Albrecht, S. published the artcileReactions of chloro-substituted methanephosphonic acid dialkyl esters with dialkyl phosphites, trialkyl phosphites, or alcohol/sodium alcoholate, Quality Control of 866-23-9, the publication is Zeitschrift fuer Anorganische und Allgemeine Chemie (1986), 207-11, database is CAplus.

(RO)₂P(O)CCl₃ (R = Et, Bu) react with dialkyl phosphites and alc. in the presence of tertiary amines or with trialkyl phosphites and alc. yielding diesters of dichloromethanephosphonic acids and triesters of phosphoric acid. When esters of trichloromethane- or dichloromethanephosphonic acid react with alcs. in the presence of sodium alcoholates, a quant. cleavage of P-C bond occurs, and triesters of phosphoric acid and CHCl₃ or CH₂Cl₂ are formed.

Zeitschrift fuer Anorganische und Allgemeine Chemie published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Quality Control of 866-23-9.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Albrecht, S. published the artcileReaction of the two-component system trialkyl phosphite/carbon tetrachloride with nucleophiles. 3. Reaction in presence of trialkylammonium salts, SDS of cas: 866-23-9, the publication is Zeitschrift fuer Anorganische und Allgemeine Chemie (1987), 132-46, database is CAplus.

Alkali pseudohalides (KSCN, NaN₃, KCN) react with the 2-component system trialkyl phosphite/carbon tetrachloride in the presence of trialkylammonium halides. Isothiocyanates of dialkylphosphoric acid, N-alkyl phosphoric acid diester amides, N-dialkoxyphosphoryl trialkoxyphosphazenes and tricyanophosphine oxide resp., are obtained. In the system (RO)₃P/CCl₄/R₃NHI the dialkoxyphosphoryl chloride is formed.

Zeitschrift fuer Anorganische und Allgemeine Chemie published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, SDS of cas: 866-23-9.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Steinbach, J. published the artcileReaction of the two-component system trialkyl phosphite/carbon tetrachloride with nucleophiles containing hydrogen. 2. Reaction with ammonia and amines, Name: Diethyltrichloromethylphosphonate, the publication is Zeitschrift fuer Anorganische und Allgemeine Chemie (1985), 180-6, database is CAplus.

RNH₂ (R = H, Pr, Bu, PhCH₂, Ph) reacted 1:1 with (R¹O)₃P (R¹ = Et, Bu) and CCl₄ to give (R¹O)₂P(O)NHR. If excess RNH₂ was used, R¹OP(O)(NHR)₂ and OP(NHR)₃ also formed. The reaction of (R¹O)₃P/CCl₄ in the presence of secondary and tertiary amines gave (R¹O)₂P(O)CCl₃, which reacted with the amine to give [Cl₃CP(O)(O^–)(OR¹)][⁺NRR²R³R⁴].

Zeitschrift fuer Anorganische und Allgemeine Chemie published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C14H10O4S2, Name: Diethyltrichloromethylphosphonate.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Albrecht, Steffen published the artcileDirect synthesis of dialkyl N,N-diorganophosphoramidates from trialkyl phosphites, Application In Synthesis of 866-23-9, the publication is Phosphorus, Sulfur and Silicon and the Related Elements (1991), 62(1-4), 189-92, database is CAplus.

Amidation of (RO)₃P (R = Et, Bu) with secondary amines R¹R²NH (R¹ = R² = Bu, Et; R¹ = Ph, R² = Me, Et) in the presence of amine hydrochloride catalysts and CCl₄ in MeCN as solvent gave title compounds, (RO)₂P(O)(NR¹R²). The mechanism is discussed.

Phosphorus, Sulfur and Silicon and the Related Elements published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Application In Synthesis of 866-23-9.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Boutevin, B. published the artcileSynthesis of phosphonic compounds with chlorofluorinated chains. Part I, Formula: C5H10Cl3O3P, the publication is Phosphorus and Sulfur and the Related Elements (1981), 11(3), 373-81, database is CAplus.

The redox catalysis and free-radical telomerizations of di- and trichloromethylphosphonyl dichlorides and their esters with chlorotrifluoroethylene (I) [79-38-9] were studied. Also investigated was phosphonation of telomers of I and CCl₄ using Kinnear-Perren and Michaelis-Arbuzov methods. Phosphonic compounds containing chlorofluorinated blocks are obtained with these two methods. By-products are described and explained using known mechanisms.

Phosphorus and Sulfur and the Related Elements published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Formula: C5H10Cl3O3P.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics