Tag: 0-100

Coumarin as a Surrogate for the Protection-group-free Synthesis of o-Hydroxy Stilbenes: Hydrolysis-Decarboxylation-Heck Coupling Reactions in One Pot was written by Andhare, Nitin H.;Equbal, Danish;Sinha, Arun K.. And the article was included in Chemistry – An Asian Journal in 2022.Safety of Lithium chloride The following contents are mentioned in the article:

Here, a successful attempt is made to develop a one-pot protocol for the synthesis of 2-hydroxystilbene derivatives I (R = Ph, naphthalen-2-yl, thiophen-2-yl, benzo[d][1,3]dioxol-5-yl, etc.; R¹ = H, Me) via hydrolysis of natural coumarins II followed by in situ decarboxylative Heck coupling with haloarenes RX (X = I, Br). Fine tuning of the reaction conditions allowed exclusive formation of 2-hydroxystyrylbenzenes I over other possible side products, i.e., benzofuran/substituted coumarins. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Safety of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Safety of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Electrical and material effects of molten salt and temperature on diamond was written by Lukosi, Eric;Alghamdi, Ahmed;Hamm, Daniel;Launiere, Cari;Milburn, Robert;Pereira, Candido;Vilmercati, Paolo;Weitering, Hanno. And the article was included in Diamond and Related Materials in 2022.Name: Lithium chloride The following contents are mentioned in the article:

An electronic grade single crystal diamond detector was tested for its chem. and electronic stability after a five day exposure to a 450 °C KCl-LiCl molten salt eutectic. After exposure to the salt, time-of-flight secondary ion mass spectrometry confirmed that lithium diffused into the diamond. However, no degradation of the hole and electron transport properties were observed Finally, the spectroscopic performance of a diamond detector was investigated as a function of temperature, and it was found that the spectrum started severely degrading at a temperature of 190 °C, consistent with other reports. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Name: Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Name: Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Photoexcited Direct Amination/Amidation of Inert Csp³-H Bonds via Tungsten-Nickel Catalytic Relay was written by Wang, Qing;Ni, Shengyang;Yu, Lei;Pan, Yi;Wang, Yi. And the article was included in ACS Catalysis in 2022.Application of 7447-41-8 The following contents are mentioned in the article:

Light alkanes are the most abundant resources in nature. It is of great significance to develop convenient methods to realize the conversion of alkanes to high value-added products. However, the examples of aliphatic amines derived from unactivated alkanes remain rare. This work describes a rapid construction of C(sp³)-N bonds from light alkanes with amine/amide electrophile reagents via high-valent tungsten and nickel catalysis in high efficiency. The photoexcited metal relay provides a powerful tool for the activation of inert sp³-hybridized C-H bonds and stabilization of C-Ni(III)-N intermediates. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Application of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Additive effects of lithium halides on the tensile and rheological properties of poly(methyl methacrylate) was written by Ito, Asae;Shin, Arisa;Nitta, Koh-hei. And the article was included in Polymer Journal (Tokyo, Japan) in 2022.Electric Literature of ClLi The following contents are mentioned in the article:

Lithium halides are easily dispersed in poly(Me methacrylate) (PMMA) and lead to strong phys. crosslinking with PMMA. We investigated the addnl. effects of various lithium halides, such as LiCl, LiBr, and LiI salts, on the rheol. and mech. properties of PMMA. The salts were homogeneously dispersed in the PMMA matrix, and the flow zone expanded owing to the pinning effects of the molten PMMA chains as the anion size increased. Furthermore, the brittleness of the PMMA solids doped with LiX (X = Cl, Br, and I) was analyzed using the Griffith theory, which suggested that the stress concentration around the salts in the PMMA matrix leads to the initiation of macroscopic fractures. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Electric Literature of ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Electric Literature of ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Nickel catalyzed multicomponent stereodivergent synthesis of olefins enabled by electrochemistry, photocatalysis and photo-electrochemistry was written by Zhu, Chen;Yue, Huifeng;Rueping, Magnus. And the article was included in Nature Communications in 2022.Computed Properties of ClLi The following contents are mentioned in the article:

A three-component, reductive cascade, cross-coupling reaction for the arylalkylation of alkynes was reported. A wide range of trisubstituted alkenes were obtained in good to high yields with excellent chemo- and stereoselectivity by switching between electrochem. and photocatalysis. The E isomer of the product was obtained exclusively when the reaction was conducted with electricity and nickel, while the Z isomer was generated with high stereoselectivity when photo- and nickel dual catalysts were used. Moreover, photo-assisted electrochem. enabled nickel catalyzed protocol was demonstrated to selectively deliver Z-trisubstituted alkenes without the addition of photocatalysts. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Computed Properties of ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Computed Properties of ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Greening Oxidation Catalysis: Water as a Solvent for Efficient Alkene Epoxidation over a Titanosilicate/H₂O₂ System was written by Yu, Yunkai;Fang, Nan;Chen, Zhen;Liu, Dongxu;Liu, Yueming;He, Mingyuan. And the article was included in ACS Sustainable Chemistry & Engineering in 2022.Recommanded Product: Lithium chloride The following contents are mentioned in the article:

Herein, we disclose the application of water (H₂O) solvent in titanosilicate-catalyzed epoxidation of alkenes. A highly efficient H₂O-solvent propylene epoxidation system (Ti-MWW/H₂O/H₂O₂/propylene/K⁺) was achieved, possessing high activity, selectivity, and stability. Our investigation shows that this excellent catalytic performance is ascribed to the structure variation of H₂O induced by K⁺. The superior H₂O structure is the one that donates two and accepts one hydrogen bond (HB), which is known as the “DDA” H₂O structure. The current report benefits sustainable applications in titanosilicate-catalyzed alkene epoxidation and conforms to the principles of green chem. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Recommanded Product: Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Recommanded Product: Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Lithium intercalation and deintercalation of thermally decomposed LiAl₂-layered double hydroxides was written by Lee, Yongju;Jung, Duk-Young. And the article was included in Applied Clay Science in 2022.Computed Properties of ClLi The following contents are mentioned in the article:

Lithium aluminum layered double hydroxide (LiAl₂-LDH) nanocrystals on aluminum metal substrates were synthesized to adsorb lithium in aqueous solutions and utilized to collect lithium in aqueous media. LiAl₂-LDH is transformed at 300°C into a mixture of LiCl and Li-Al-O-OH; dissolved lithium in deionized water at 25°C reached 85% compared to the intercalated lithium content. Amorphous Li-Al-O-OH residues on the aluminum metal substrate were capable of adsorbing lithium ions back to the lithium rich LiAl₂-LDH phase. Thermal treatment followed by addnl. lithium intercalation suggested a topotactic reaction of lithium ions between amorphous Li-Al-O-OH and LiAl₂-LDH. We also proposed a facile recycling method of lithium ions by peeling off the Li-Al-O-OH layer to save the aluminum metal substrate. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Computed Properties of ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Computed Properties of ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Ionochromism, solvatochromism and effect of dissolved gases on the spectral properties of bromothymol blue was written by Tatini, Duccio;Anselmi, Erasmo;Cabrucci, Giacomo;Acar, Mert;Ninham, Barry W.;Lo Nostro, Pierandrea. And the article was included in Journal of Molecular Liquids in 2022.Product Details of 7447-41-8 The following contents are mentioned in the article:

The color of the pH indicator Bromothymol blue (BTB) changes from yellow to blue with increasing pH. The effect of some electrolytes (LiCl, NaCl, KCl, CsCl, KSCN and KClO3) and of D2O on the spectral properties of dilute solutions of BTB is explored. The results are interpreted in terms of dimerization of the dye mols. and of the different hydration that D2O induces. The effects of dissolved gases on the spectral properties of BTB is studied. Complete removal of dissolved gas is achieved. Surprising effects on the UV-vis spectra emerged. After degassing solutions, gases were re-admitted via bubbling. The gases He, Ar, N2, CO2 and CH4.were studied. The effects can be explained by presence or absence of nano- and microbubbles of gas in the solution These allow formation of dimers and multiple association via adsorption and so affect the spectral properties of the dye mols. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Product Details of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Product Details of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Phase diagram, thermodynamic studies, and ab-initio calculations of the Ge-Li system was written by Gierlotka, W.;Debski, A.;Zabrocki, M.;Goral, A.;Gasior, W.. And the article was included in Journal of Chemical Thermodynamics in 2022.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

The limiting enthalpy of solution of liquid germanium in the liquid tin ΔsolH∞Ge(l) was measured at 927 K and equals 3.24 ± 0.34 kJ/mol at. The standard enthalpy of formation of intermetallic phases from the Ge-Li system were calculated at 747 K with the use of the solution calorimetric method. These alloys and intermetallic phases were prepared from pure, metallic germanium and lithium, which were melted in a glove-box filled with high purity argon with a very low concentration of impurities. The X-ray diffraction measurements were conducted to verify the structure of the prepared alloys. The electromotive force studies were performed at three temperatures: 634 K, 807 K, and 841 K by the titration technique. Based on obtained results and other thermodn. quantities available in the literature the thermodn. properties of phases were optimized, and the Ge-Li phase diagram was determined This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Category: chlorides-buliding-blocks).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Hydration and ion interactions of zwitterionic homopolymers with varying carbon spacer lengths was written by Christiansen, Daniel;Cheng, Gang;Mehraeen, Shafigh. And the article was included in Chemical Engineering Research and Design in 2022.Application In Synthesis of Lithium chloride The following contents are mentioned in the article:

We use mol. dynamics simulations to examine the role of polymerization and changing monomer carbon spacer length on the hydration and ion association properties of carboxybetaine and sulfobetaine zwitterionic homopolymers with LiCl and KCl salts in aqueous solution Our simulation results suggest that polymerization leads to increased water and ion effective residence time compared to previous studies while varying carbon spacer length causes a change in the partial charge of zwitterionic functional groups. This change in partial charge affects the distribution and quality of water and ion interactions. Addnl., investigating the ionic conductivity by use of the Nernst-Einstein equation, we found that KCl had higher conductivity than LiCl for both polymer types, which is explained by the shorter effective residence time of K⁺ ions to the polymer than that of Li⁺. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application In Synthesis of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Application In Synthesis of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics