Tag: M.W=650-700

Chlorinated organic compounds are found in nearly every class of biomolecules. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Alkyl chlorides, as versatile building blocks in organic chemistry, are used in the preparation of alcohols, thioethers, alkenes, alkynes, esters, and Grignard reagents. Product Details of C16H24Cl2Ir2.

Jouffroy, Matthieu;Nguyen, Thi-Mo;Cordier, Marie;Blot, Marielle;Roisnel, Thierry;Gramage-Doria, Rafael research published ã€?Iridium-Catalyzed Direct Reductive Amination of Ketones and Secondary Amines: Breaking the Aliphatic Wallã€? the research content is summarized as follows. Direct reductive amination (DRA) is a ubiquitous reaction in organic chem. This transformation between a carbonyl group and an amine is most often achieved by using a super stoichiometric amount of hazardous hydride reagents, thus being incompatible with many sensitive functional groups. DRA could also be achieved by means of chemo- or biocatalysis, thereby attracting the interest of industry as well as academic laboratories due to the virtually perfect atom economy. Although DRAs are well-established for substrate pairs such as aldehydes with either 1° or 2° amines as well as ketones with 1° amines, the current methodologies are limited in the case of ketones with 2° amines. Herein, a general DRA protocol that overcomes this major limitation by means of iridium catalysis is presented. The applicability of the methodol. is demonstrated by accessing an unprecedented range of biol. relevant tertiary amines starting from both aliphatic ketones and aliphatic amines. The choice of a disphosphane ligand (Josiphos A or Xantphos) is essential for the success of the transformation.

Product Details of C16H24Cl2Ir2, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

The class of organic compounds having covalently a bonded chlorine atom is called organic chlorides. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of named reactions and applications. Reference of 12112-67-3.

Hollenhorst, Helia;McDonald, Robert;Ferguson, Michael;Turculet, Laura research published ã€?Synthesis of Rhodium and Iridium Complexes Supported by Bis(indolylphosphino)silyl Pincer Ligation: Competitive N-H and C-H Bond Activation by an Ir(I) Speciesã€? the research content is summarized as follows. The synthesis of five-coordinate amido hydride PSiP pincer complexes of both Rh^III and Ir^III was pursued. The preparation of such complexes by a salt metathesis route was initially targeted to assess the synthetic viability of such species. Isolable anilido hydride complexes of both Rh and Ir proved accessible, and rare examples of thermally robust Ir alkylamido hydride complexes were found to be viable synthetic targets. The preparation of amido hydride species by N-H oxidative addition was also pursued. Toward this end, the generation of coordinatively unsaturated (ⁱPr-PSiP^Ind)M^I (M = Rh, Ir) species was investigated. Dehydrohalogenation of (ⁱPr-PSiP^Ind)RhH(Cl) (1) under N₂ afforded the isolable complex [(ⁱPr-PSiP^Ind)Rh]₂(μ-N₂) (8a). While the N₂ ligand could be displaced to afford (ⁱPr-PSiP^Ind)RhL (L = PMe₃, DMAP, H₂NPh), such Rh^I species proved unreactive toward N-H oxidative addition of aniline. Dehydrohalogenation of (ⁱPr-PSiP^Ind)IrH(Cl) (2) in benzene solution, resulted in activation of the solvent to afford (ⁱPr-PSiP^Ind)IrH(Ph) (11), which undergoes facile arene exchange with benzene-d₆. In cyclohexane solution, treatment with aniline afforded a mixture of N-H and aniline sp²-C-H bond oxidative addition products, with the latter species being favored. Although the observation of arene exchange involving (ⁱPr-PSiP^Ind)IrH(Ph) suggests that C-H bond oxidative addition is reversible, attempts to drive the reactivity with aniline in the direction of N-H bond oxidative addition were unsuccessful. This reactivity differs significantly from that of previously reported complexes supported by related PSiP ligation. Most notably, it appears that for (ⁱPr-PSiP^Ind)Ir, products resulting from N-H- and C-H-oxidative addition of aniline substrates do not readily interconvert, although both are postulated to share a common intermediate of the type (ⁱPr-PSiP^Ind)Ir(NH₂Ph).

Reference of 12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Chloride substituents modify the physical properties of organic compounds in several ways. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. They are typically denser than water due to the presence of chlorine, which has a high atomic weight. Recommanded Product: Chloro(1,5-cyclooctadiene)iridium(I) dimer.

Hu, Fang;Zhang, Hua;Chu, Yunpeng;Hui, Xin-Ping research published ã€?Efficient enantioselective synthesis of pyrazolines and isoxazolines enabled by an iridium-catalyzed intramolecular allylic substitution reactionã€? the research content is summarized as follows. An efficient Ir-catalyzed enantioselective intramol. allylic substitution reaction of 2-tosylhydrazono or hydroxyimino carbonates for the synthesis of five-, six- and seven-membered heterocycles containing N-N and N-O bonds I [R¹ = Ph, 3-MeC₆H₄, 2-thienyl, etc,; X = NTs, O; n = 1,2,3] was achieved.

12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, Recommanded Product: Chloro(1,5-cyclooctadiene)iridium(I) dimer

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. SDS of cas: 12112-67-3.

Ilyin, I. Yu.;Mirzaeva, I. V.;Sukhikh, T. S.;Bonegardt, D. V.;Basova, T. V. research published ã€?STUDY OF THE CORRELATION BETWEEN THE STRUCTURE OF THE [Ir(cod)Cp] COMPLEX AND ITS THERMAL PROPERTIESã€? the research content is summarized as follows. A volatile iridium(I) complex [Ir(cod)Cp] (cod – 1,5-cyclooctadiene, Cp – cyclopentadienyl) is synthesized and characterized by IR and NMR spectroscopy. The structure of [Ir(cod)Cp] is determined by single crystal X-ray diffraction. The anal. of the Hirshfeld surface along with the electron d. distribution and its topol. based on the AIM theory reveals the presence of many intermol. contacts, with C(Cp)···H(Cp), Ir···H(Cp), H(cod)···H(cod) being the strongest. The presence of these contacts in the crystal structure of the compound leads to higher m.ps. and transition temperatures to the gas phase, as compared to those of a similar complex containing methyl-substituted cyclopentadienyl. Lattice energy calculations and results of the thermogravimetric anal. of the [Ir(cod)Cp] complex are well consistent with the similar data for β-diketonate complexes [Ir(cod)L], which suggests that there may be a correlation between lattice energies and melting and a 50% weight loss temperatures

SDS of cas: 12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

The class of organic compounds having covalently a bonded chlorine atom is called organic chlorides. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of named reactions and applications. Formula: C16H24Cl2Ir2.

Jacko, Jaroslav;Stas, Monika;Rulisek, Lubomir;Cisarova, Ivana;Kotora, Martin research published �Ir-Catalyzed Cycloaddition of Tribenzocyclyne with Biphenylenes� the research content is summarized as follows. Ir-catalyzed C-C bond activation in biphenylenes followed by a reaction with tribenzocyclyne was demonstrated as a suitable method for synthesizing strained and unknown monoadducts with the tetradehydrotetrabenzo[a,c,e,i]cyclododecene scaffold ([12]annulenes). Modification of reaction conditions also furnished [12]annulene products with cis and/or trans double bonds formed by hydrogen transfer. The [9]annulene side product was formed upon the reaction of the benzyl radical with tribenzocyclyne during the Bergman cyclization. All isolated compounds were fully characterized by HRMS, NMR and X-ray diffraction anal.

Formula: C16H24Cl2Ir2, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Organic chlorides are organic molecules with a C-Cl bond, for example chloroform (CH3-Cl) or vinyl chloride(C2H3Cl). 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Organic chlorides can be used in production of: PVC, Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. Application of C16H24Cl2Ir2.

Ho, An T.;Ensign, Seth C.;Vanable, Evan P.;Portillo, David;Humke, Jenna N.;Kortman, Gregory D.;Hull, Kami L. research published 《 Rhodium-/Iridium-Catalyzed Hydroamination for the Synthesis of 1,2-, 1,3-, or 1,4-Diamines》, the research content is summarized as follows. The Ir-catalyzed regioselective hydroamination of allyl amines as well as the catalyst-controlled regiodivergent hydroamination of homoallylic amines with aniline nucleophiles is reported. These directed hydroamination reactions afford a variety of 1,2-, 1,3-, and 1,4-diamines in good to excellent yields and high regio- and chemoselectivities. Mechanistic investigations suggest that the reactions are proceeding through an oxidative addition into the ArHN-H bond and that the observed regioselectivity is due to the selective formation of a five- or six-membered metallacyclic intermediate depending on the catalyst employed.

Application of C16H24Cl2Ir2, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Electric Literature of 12112-67-3.

Ho, Luong Phong;Neitzel, Angelika;Bannenberg, Thomas;Tamm, Matthias research published 《 Rhodium and Iridium Complexes of Anionic Thione and Selone Ligands Derived from Anionic N-Heterocyclic Carbenes》, the research content is summarized as follows. The lithium salts of anionic N-heterocyclic thiones and selones [{(WCA-IDipp)E}Li(toluene)] (1, 2; E = S, Se; WCA = B(C₆F₅)₃, IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene), which contain a weakly coordinating anionic (WCA) borate moiety in the imidazole backbone were reacted with Me₃SiCl, to furnish the silylated adducts (WCA-IDipp)ESiMe₃ (3, 4; E = S, Se). The reaction of the latter with [(η⁵-C₅Me₅)MCl₂]₂ (M = Rh, Ir) afforded the rhodium(III) and iridium(III) half-sandwich complexes [{(WCA-IDipp)E}MCl(η⁵-C₅Me₅)] (5–8). The direct reaction of the lithium salts 1 and 2 with a half or a full equivalent of [M(COD)Cl]₂ (M = Rh, Ir) afforded the monometallic complexes [{(WCA-IDipp)E}M(COD)] (9–12) or the bimetallic complexes [μ₂-{(WCA-IDipp)E}M₂(COD)₂(μ₂-Cl)] (13–16), resp. The bonding situation in these complexes has been investigated by means of d. functional theory (DFT) calculations, revealing thiolate or selenolate ligand character with negligible metal-chalcogen π-interaction.

12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, Electric Literature of 12112-67-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Organic chlorides are organic molecules with a C-Cl bond, for example chloroform (CH3-Cl) or vinyl chloride(C2H3Cl). 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Organic chlorides can be used in production of: PVC, Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. Application In Synthesis of 12112-67-3.

Grimm, Alexandra B.;Wang, Kai;Rheingold, Arnold L.;Moore, Curtis E.;Szieberth, Denes;Nyulaszi, Laszlo;Protasiewicz, John D. research published 《 2-Aryl-1,3-Benzoxaphospholes as Unwilling Participants for Catalytic Suzuki-Miyaura CC Coupling Reactions》, the research content is summarized as follows. Under conditions typically effective to achieve a catalytic aryl-aryl bond during Pd Suzuki-Miyaura (SM) coupling reactions of ArB(OH)₂ and ArBr, reactions of p-tolylboronic acid and 2-(BrC₆H₄)-1,3-benzoxaphosphole (BrC₆H₄-BOP, 1) failed to provide the anticipated product of CC bond coupling, 2-(p-CH₃C₆H₄-C₆H₄)-1,3-benzoxaphosphole. An anal. of reaction mixtures by ¹H and ³¹P{¹H} NMR spectroscopic methods showed numerous broad resonances, suggesting the formation of labile metal complexes with 1. This possibility was confirmed by determinations of the solid-state structures of [(^tBu₃P)(Ph-BOP)M]₂ (M = Pt, 5; M = Pd, 6) from the reaction of Ph-BOP and [M(^tBu₃P)₂] (M = Pt, Pd). The structures of 5 and 6 are isomorphous and reveal unusual bridging μ₂-P-BOP bonding modes. Computational studies have explored the structures and relative energies and indicate that dimeric complexes of this form can dissociate easily. Surprisingly, even when P:C double bonds of Ar-BOPs are sheltered by coordination to W pentacarbonyl, the Ar-BOP units resist yielding products of CC coupling under similar SM conditions but instead yield unusual products whereby CsOH adds across the P:C bonds in [(CO)₅W{2-Ar-BOP}]. Computational studies are consistent with ready addition of hydroxide to the W-protected P:C bond.

Application In Synthesis of 12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Chloride substituents modify the physical properties of organic compounds in several ways. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. They are typically denser than water due to the presence of chlorine, which has a high atomic weight. Category: chlorides-buliding-blocks.

Guerra Faura, Gabriel;Nguyen, Tena;France, Stefan research published 《 Catalyst-Controlled Chemodivergent Reactions of 2-Pyrrolyl-α-diazo-α-ketoesters and Enol Ethers: Synthesis of 1,2-Dihydrofuran Acetals and Highly Substituted Indoles》, the research content is summarized as follows. A catalyst-controlled, chemodivergent reaction of pyrrolyl-α-diazo-α-ketoesters, e.g., I (R = H, Et, Ph, R¹ = Me, Bn, Ts), with enol ethers, e.g., 2-methoxypropene, dihydropyran, and (1-ethoxyvinyl)benzene, is reported. While Cu(II) catalysts selectively promoted a [3+2]-cycloaddition to provide pyrrolyl-substituted 2,3-dihydrofuran (DHF) acetals, e.g., II, dimeric Rh(II) catalysts afforded 6-hydroxyindole-7-carboxylates, e.g., III, via an unreported [4+2]-benzannulation. The choice of enol ether proved to be crucial in determining both regioselectivity and yield of the resp. products (up to 91% yield for Cu(II) and 82% for Rh(II) catalysis). Furthermore, the DHF acetals were shown to serve as precursors to 7-hydroxyindole-6-carboxylates (isomeric to the indoles formed from Rh) and highly substituted furans in the presence of Lewis acids. Thus, from a common pyrrolyl-α-diazo-α-ketoester, up to three unique heterocyclic scaffolds can be achieved based on catalyst selection.

Category: chlorides-buliding-blocks, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Category: chlorides-buliding-blocks.

Guo, Panchi;Zhan, Miao research published 《 Iridium-Catalyzed Enantioconvergent Allylation of a Boron-Stabilized Organozinc Reagent》, the research content is summarized as follows. An Ir-catalyzed enantioconvergent coupling of the versatile B-stabilized organozinc reagent BpinCH₂ZnI with a racemic branched allylic carbonate was developed here, which differs from the authors’ previous work by using 1,1-bisborylmethane through the kinetic resolution process. The reaction has a broad substrate scope, and various chiral homoallylic organoboronic esters could be obtained in good yields with excellent enantioselectivities. The synthetic practicability of the products was demonstrated by their conversion to other useful families of compounds

Category: chlorides-buliding-blocks, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics