Tag: M.W=650-700

The class of organic compounds having covalently a bonded chlorine atom is called organic chlorides. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of named reactions and applications. Name: Chloro(1,5-cyclooctadiene)iridium(I) dimer.

Zhang, Dejin;Yang, Guoqiang;Hu, Xingbang;Zhang, Zhibing research published 《 Utilization of a Methoxy Group in Lignin to Prepare Amides by the Carbonylation of Amines》, the research content is summarized as follows. A new method to synthesize acetanilides RC₆H₄N(C(O)CH₃)(R¹) (R = H, 2-Me, 3-Me, 2-F; R¹ = H, Me, iso-Pr, cyclohexyl, phenyl) by the carbonylation of amines RC₆H₄NHR¹ directly was reported. Lignin was used as a source of Me by cleaving the methoxy group using LiI. Different amines were employed to investigate the amide bond formation. The corresponding acetanilides were obtained with good to excellent yields. Several Me ethers were also used as a Me source. Excellent conversion of RC₆H₄NHR¹ (R = H, R¹ = Me) and selectivity of RC₆H₄N(C(O)CH₃)(R¹) (R = H, R¹ = Me) were obtained. More importantly, lignin monomer compounds and lignin were used as a source of Me. Satisfactory results were received. A possible mechanism based on the controlled experiments was proposed. This method may provide a potential way for the transformation of lignin into valuable chems.

12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, Name: Chloro(1,5-cyclooctadiene)iridium(I) dimer

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Chlorinated organic compounds are found in nearly every class of biomolecules. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Alkyl chlorides, as versatile building blocks in organic chemistry, are used in the preparation of alcohols, thioethers, alkenes, alkynes, esters, and Grignard reagents. Recommanded Product: Chloro(1,5-cyclooctadiene)iridium(I) dimer.

Zhang, Jian;Yang, Wu-Lin;Zheng, Hanliang;Wang, Yi;Deng, Wei-Ping research published 《 Regio- and Enantioselective γ-Allylic Alkylation of In-Situ Generated Free Dienolates via Scandium/Iridium Dual Catalysis》, the research content is summarized as follows. An unprecedented asym. γ-allylic alkylation of free dienolates via Sc/Ir dual catalysis is reported, which affords a range of synthetically versatile γ-allylic crotonaldehydes I (Ar = Ph, 2-MeOC₆H₄, 3,4-Cl₂C₆H₃, 1-naphthyl, 2-thienyl, etc.; R¹ = H, Me, Ph, etc.; R² = H, EtO₂C) in high efficiency with excellent chemo-, regio-, and enantioselectivities. The dienolates bearing no essential auxiliary groups were generated in-situ by scandium triflate-mediated Meinwald rearrangement of vinyloxiranes II atom-economically. With the assistance of computational d. functional theory calculations, a Sc/Ir bimetallic catalytic cycle was proposed to illustrate the reaction mechanism.

Recommanded Product: Chloro(1,5-cyclooctadiene)iridium(I) dimer, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Organic chlorides are organic molecules with a C-Cl bond, for example chloroform (CH3-Cl) or vinyl chloride(C2H3Cl). 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Organic chlorides can be used in production of: PVC, Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. Synthetic Route of 12112-67-3.

Zhang, Lin;Zhang, Ling;Chen, Qian;Li, Linlin;Jiang, Jian;Sun, Hao;Zhao, Chong;Yang, Yuanyong;Li, Chun research published 《 Cinchona-Alkaloid-Derived NNP Ligand for Iridium-Catalyzed Asymmetric Hydrogenation of Ketones》, the research content is summarized as follows. Herein, a series of novel and easily accessed cinchona-alkaloid-based NNP ligands I [R = cyclohexyl, Ph, 2-MeOC₆H₄, etc.; R¹ = H, MeO] was developed in two steps. By combining [Ir(COD)Cl]₂, 39 ketones including aromatic, heteroaryl, and alkyl ketones were hydrogenated, all affording valuable chiral secondary alcs. with 96.0-99.9% ee. A plausible reaction mechanism was discussed by NMR, HRMS, DFT and an activating model involving trihydride was verified.

12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, Synthetic Route of 12112-67-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Organic chlorides are organic molecules with a C-Cl bond, for example chloroform (CH3-Cl) or vinyl chloride(C2H3Cl). 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Organic chlorides can be used in production of: PVC, Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. Safety of Chloro(1,5-cyclooctadiene)iridium(I) dimer.

Yun, Bo-Sun;Kim, So-Yoen;Kim, Jin-Hyoung;Choi, Sunghan;Lee, Sanghun;Son, Ho-Jin;Kang, Sang Ook research published 《 Synthesis and Characterization of Blue Phosphorescent NHC-Ir(III) Complexes with Annulated Heterocyclic 1,2,4-Triazolophenanthridine Derivatives for Highly Efficient PhOLEDs》, the research content is summarized as follows. Efficient tris-bidentate Ir(III) phosphorescent dopants were prepared using 1,2,4-triazolo[4,3-f]phenanthridine (tzp) moieties modified with aryl substituents (Ph, tolyl, and xylenyl) as the main phenylimidazole-based N-heterocyclic carbene (NHC) chelates (CĈ:). According to the degree of the bulkiness of the aryl substituent and the ligation mode, the five prepared Ir(^tzpCĈ:) complexes include four homoleptic NHC-Ir(III) complexes that are referred to as fac-Ir(tzpPh)₃, fac/mer-Ir(tzpTol)₃, and mer-Ir(tzpXyl)₃ and one heteroleptic cis-Ir(tzpPh)₂(tzpPh)’, in which the Ph moiety of one tzpPh ligand is abnormally ligated to the Ir metal center, unlike other tzp ligands. The Ir(III) complexes ligated by carbene ligands (^tzpCĈ:) exhibited highly efficient emissions in solid state (Φ_em = 23.2-54.0%). Electrochem. and theor. studies revealed that the excited-state properties of these NHC-Ir(III) complexes are variable on the extent of planarity and π-conjugation of the ^tzpCĈ: chelating ligand. Due to its enhanced rigidity and low excited-state energy, a result of abnormal tzpPh ligand ligation, the heteroleptic cis-Ir(tzpPh)₂(tzpPh)’ exhibited the most efficient emission properties in solution (Φ_em = 21.3%) and solid (Φ_em = 54.0%) media. Of the devices fabricated with Ir(^tzpCĈ:)₃ complexes as emitters, that doped with cis-Ir(tzpPh)₂(tzpPh)’ exhibited superior electroluminescence efficiencies (external quantum efficiency (EQE) of 16.3%, current efficiency of 27.6 cd A^-1, and power efficiency of 22.1 lm W^1-) and CIE coordinates of [0.17,0.26], which are superior to those of other Ir(^tzpCĈ:)₃ complexes and Ir(dmp)₃ (dmp = 3-(2,6-dimethyl-phenyl)-7-methylimidazo[1,2-f]phenanthridine). This study provides insight into the mol.-level engineering of Ir(III) dopant materials for improving the emission efficiencies of phosphorescent OLEDs.

Safety of Chloro(1,5-cyclooctadiene)iridium(I) dimer, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Chlorinated organic compounds are found in nearly every class of biomolecules. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Alkyl chlorides, as versatile building blocks in organic chemistry, are used in the preparation of alcohols, thioethers, alkenes, alkynes, esters, and Grignard reagents. Name: Chloro(1,5-cyclooctadiene)iridium(I) dimer.

Yang, Wu-Lin;Wang, Yuan-Lin;Li, Wen;Gu, Bu-Ming;Wang, Si-Wen;Luo, Xiaoyan;Tian, Bo-Xue;Deng, Wei-Ping research published 《 Diastereo- and Enantioselective Synthesis of Eight-Membered Heterocycles via an Allylation/Ring Expansion Sequence Enabled by Multiple Catalysis》, the research content is summarized as follows. The present work addresses this issue by designing an asym. allylation/ring expansion reaction of 2-(1-hydroxyallyl)phenols and cyclobutanone carboxamides enabled by sequential iridium/zinc/bifunctional squaramide catalysis, affording a series of 8-membered benzo[b]oxocines in high yields with high diastereo- and enantioselectivities. Mechanistic investigation revealed that the enantioselectivity was controlled by the chiral iridium catalyst, while d. functional theory calculations demonstrate that the diastereoselectivity was controlled by the chiral bifunctional squaramide catalyst. Moreover, the sequential allylation reaction strategy was demonstrated to be also applicable to the synthesis of two types of enantiomerically enriched nitrogen heterocycles, 8-membered benzo[b]azocines and polycyclic cyclobuta[b]quinolines.

Name: Chloro(1,5-cyclooctadiene)iridium(I) dimer, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Chloride substituents modify the physical properties of organic compounds in several ways. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. They are typically denser than water due to the presence of chlorine, which has a high atomic weight. Category: chlorides-buliding-blocks.

Yu, Han;Ma, Lin;Wada, Kenji;Kurihara, Ryohsuke;Feng, Qi;Uemura, Shinobu;Isoda, Kyosuke research published 《 Rapid Multialakylation of Aqueous Ammonia with Alcohols by Heterogeneous Iridium Catalyst under Simple Conditions》, the research content is summarized as follows. This paper reports the synthesis of tertiary and secondary amines from aqueous ammonia and benzylic alcs. by titania-supported iridium catalyst. It is a successful example of heterogeneous systems at moderate temperature without either addnl. solvent or high pressure. The catalytic system showed good tolerance to the atm. condition and performed rapidly to give tribenzylamine a yield of over 99 % within 6 h in argon. The crystal structure of titania supports for iridium catalysts strongly affected their activity. The catalysis smoothly proceeded on larger scales. The catalyst could be easily reused and run at least for 5 cycles without significant loss of activity. The highly-dispersed iridium species of less than 2 nm in diameter would be responsible for the excellent catalytic activity. This catalyst is well applicable in multialkylation of aqueous ammonia with various primary and secondary benzylic alcs.

12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. SDS of cas: 12112-67-3.

Yang, Huaxin;Zhou, Yang;Zhang, Zhihan;Wen, Jialin;Zhang, Xumu research published 《 Iridium-Catalyzed Hydroiodination and Formal Hydroamination of Olefins with N-Iodo Reagents and Molecular Hydrogen: An Umpolung Strategy》, the research content is summarized as follows. Herein reported a convenient method to convert olefins to organic iodides R¹(CH)ICH₂R² [R¹ = Ph, 4-BrC₆H₄, 4-FC₆H₄, etc.; R² = Me, Ph, 3-MeC₆H₄, etc.] and amines I [R¹ = Ph, 4-ClC₆H₄, 4-BrC₆H₄, etc.; R² = Me, n-Pr, n-Bu, etc.] using an Ir/ZhaoPhos catalyst, mol. hydrogen and an electrophilic iodine(I) reagent. High yields and regioselectivities were obtained under mild conditions. In addition, basic workup with potassium carbonate leads to C-N products. Control experiments and DFT calculations tentatively excluded the pathway involving the in situ formation of HI.

SDS of cas: 12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Organic chlorides are organic molecules with a C-Cl bond, for example chloroform (CH3-Cl) or vinyl chloride(C2H3Cl). 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Organic chlorides can be used in production of: PVC, Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. Safety of Chloro(1,5-cyclooctadiene)iridium(I) dimer.

Yang, Jianping;Massaro, Luca;Krajangsri, Suppachai;Singh, Thishana;Su, Hao;Silvi, Emanuele;Ponra, Sudipta;Eriksson, Lars;Ahlquist, Maarten S. G.;Andersson, Pher G. research published 《 Combined Theoretical and Experimental Studies Unravel Multiple Pathways to Convergent Asymmetric Hydrogenation of Enamides》, the research content is summarized as follows. A highly efficient convergent asym. hydrogenation of E/Z mixtures of enamides catalyzed by N,P-iridium complexes supported by mechanistic studies was reported. It was found that reduction of the olefinic isomers (E and Z geometries) produced chiral amides with the same absolute configuration (enantioconvergent hydrogenation). This allowed the hydrogenation of a wide range of E/Z mixtures of trisubstituted enamides with excellent enantioselectivity (up to 99% ee). A detailed mechanistic study using deuterium labeling and kinetic experiments revealed two different pathways for the observed enantioconvergence. For α-aryl enamides, fast isomerization of the double bond took place, and the overall process resulted in kinetic resolution of the two isomers. For α-alkyl enamides, no double bond isomerization was detected, and competition experiments suggested that substrate chelation was responsible for the enantioconvergent stereochem. outcome. DFT calculations were performed to predict the correct absolute configuration of the products and strengthen the proposed mechanism of the iridium-catalyzed isomerization pathway.

Safety of Chloro(1,5-cyclooctadiene)iridium(I) dimer, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Chlorinated organic compounds are found in nearly every class of biomolecules. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Alkyl chlorides, as versatile building blocks in organic chemistry, are used in the preparation of alcohols, thioethers, alkenes, alkynes, esters, and Grignard reagents. Category: chlorides-buliding-blocks.

Xiao, Lu;Wei, Liang;Wang, Chun-Jiang research published 《 Stereodivergent Synthesis of Enantioenriched γ-Butyrolactones Bearing Two Vicinal Stereocenters Enabled by Synergistic Copper and Iridium Catalysis》, the research content is summarized as follows. By virtue of a fundamentally new reaction model of azomethine ylide serving as a two-atom synthon, the first example of stereodivergent preparation of [(3R,4S)/(3S,4R)/(3R,4R)/(3S,4S)]-γ-butyrolactones I (R = Me, benzyl, allyl, 2-ethoxycarbonylethyl, etc.) via synergistic Cu/Ir-catalyzed asym. cascade allylation/lactonization is presented, and all four stereoisomers of I bearing two vicinal stereocenters are accessible with excellent diastereoselective and enantioselective control. The chiral Ir^III– π-allyl intermediate was separated and characterized to understand the origin of the regio- and stereoselectivity of the initial C-C bond formation process. Control experiments shed some light on the catalyst/substrate and catalyst/catalyst interactions in this dual catalytic system to rationalize the related kinetic/dynamic kinetic resolution process with different catalyst combinations. The enantioenriched γ-butyrolactone products I were converted into an array of structurally complex chiral mols. and organocatalysts that were otherwise inaccessible.

Category: chlorides-buliding-blocks, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Chlorinated organic compounds are found in nearly every class of biomolecules. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Alkyl chlorides, as versatile building blocks in organic chemistry, are used in the preparation of alcohols, thioethers, alkenes, alkynes, esters, and Grignard reagents. Formula: C16H24Cl2Ir2.

Xu, Yang;Wang, Hongkai;Yang, Zhuang;Zhou, Yuqiao;Liu, Yangbin;Feng, Xiaoming research published 《 Stereodivergent total synthesis of rocaglaol initiated by synergistic dual-metal-catalyzed asymmetric allylation of benzofuran-3(2H)-one》, the research content is summarized as follows. Herein, a novel stereodivergent allylic alkylation of benzofuran-3(2H)-one that relies on the synergistic catalysis of a chiral N,N’-dioxide-Co(or Ni) complex and a phosphoramidite-Ir catalyst was described. All four possible stereoisomers of the α-allylated product were provided with excellent diastereo- and enantioselectivities by appropriate permutations of the two chiral catalysts. The concise synthesis of the targeted mol. rocaglaol was furnished in a stereodivergent manner, following a uniform synthetic route and using the same set of starting materials. Subsequently, a preliminary study on the anticancer activity for eight stereoisomers of rocaglaol reveals the pronounced influence of stereochem. variations on biol. activity.

Formula: C16H24Cl2Ir2, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics