Chlorinated organic compounds are found in nearly every class of biomolecules. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Alkyl chlorides, as versatile building blocks in organic chemistry, are used in the preparation of alcohols, thioethers, alkenes, alkynes, esters, and Grignard reagents. Computed Properties of 12112-67-3.
Yabe, Ryota;Ebe, Yusuke;Nishimura, Takahiro research published 《 Iridium-Catalyzed Direct C-H Allylation of Ketimines》, the research content is summarized as follows. Aromatic C-H allylation of N-sulfonyl ketimines I (R = Ph, 2-naphthyl, 3-methylphenyl, etc.) with allyl alc. or allyl Ph ether CH2CHCH2OR1 (R1 = H, Me, Ph, Boc) as an allyl source is catalyzed by a cationic iridium complex. The presence of a catalytic amount of a pyridine derivative was found to be essential for the reaction. In contrast, direct C-H allylation of ketimines RC(Me)=N(4-MeOC6H4) derived from benzophenone derivatives and p-methoxyaniline with allyl Ph ether proceeded in the absence of pyridine derivatives
Computed Properties of 12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics